期刊
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
卷 82, 期 7-8, 页码 825-839出版社
SERBIAN CHEMICAL SOC
DOI: 10.2298/JSC170412062D
关键词
X-ray crystal structure; cobalt(III); Schiff base; antioxidant activity; DFT; Fukui
资金
- Ministry of Education, Science and Technological Development of the Republic of Serbia [172035, 172055]
Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated.
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