期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 164, 期 12, 页码 E287-E294出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0321712jes
关键词
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资金
- German Federal Ministry of Education and Research [03XP0034G, 03X4631P]
In this paper we introduce a pseudo two-dimensional (P2D) model for a common lithium-nickel-cobalt-manganese-oxide versus graphite (NCM/graphite) cell with solid electrolyte interphase (SEI) growth as the dominating capacity fade mechanism on the anode and active material dissolution as the main aging mechanism on the cathode. The SEI implementation considers a growth due to non-ideal insulation properties during calendar as well as cyclic aging and a re-formation after cyclic cracking of the layer during graphite expansion. Additionally, our approach distinguishes between an electronic (sigma(SEI)) and an ionic (kappa(SEI)) conductivity of the SEI. This approach introduces the possibility to adapt the model to capacity as well as power fade. Simulation data show good agreement with an experimental aging study for NCM/graphite cells at different temperatures introduced in literature. (C) The Author(s) 2017. Published by ECS. All rights reserved.
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