期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 24, 页码 8110-8113出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04312
关键词
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资金
- University of Delaware (UD)
- University of Delaware Research Foundation
- Research Corp. Cottrell Scholars Program
- NIH NIGMS [R01 GM102358]
- NSF
- NIH [NSF CHE0421224, CHE0840401, CHE1229234, CHE1048367, NIH S10 0D016267-01, S10 RR026962-01, P20GM104316, P30GM110758]
Enabled by nickel catalysis, a mild and general catalytic method for C-alkylation of nitroalkanes with unactivated alkyl iodides is described. Compatible with primary, secondary, and tertiary alkyl iodides; and tolerant of a wide range of functional groups, this method allows rapid access to diverse nitroalkanes.
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