期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 17, 页码 6234-6241出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01814
关键词
-
资金
- ERC
- NWO
- COST Action [CM1304]
- Marie Curie ITN ResMoSys
- Dutch Ministry of Education, Culture and Science [024.001.035]
With the advent of reversible covalent chemistry the study of the interplay between covalent bond formation and noncovalent interactions has become increasingly relevant. Here we report that the interplay between reversible disulfide chemistry and self-assembly can give rise either to molecular diversity, i.e., the emergence of a unprecedentedly large range of macrocycles or to molecular specificity, i.e., the autocatalytic emergence of a single species. The two phenomena are the result of two different modes of self-assembly, demonstrating that control over self-assembly pathways can enable control over covalent bond formation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据