期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 40, 页码 14005-14008出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b07830
关键词
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资金
- EPSRC [EP/G036764/1]
- Royal Society for a URF
- European Research Council (ERC) [639594 CatHet]
- Engineering and Physical Sciences Research Council [EP/L011999/1, 1652802, EP/K03927X/1] Funding Source: researchfish
- EPSRC [EP/K03927X/1, EP/L011999/1] Funding Source: UKRI
We outline a simple protocol that accesses directly unprotected secondary amines by intramolecular C-N bond forming dearomatization or aryl C-H amination. The method is dependent on the generation of a potent electrophilic aminating agent released by in situ deprotection of O-Ts activated N-Boc hydroxylamines.
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