期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 37, 页码 12891-12894出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b05427
关键词
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A rhodium-catalyzed intermolecular hydroacylation reaction of vinyl cyclobutanols with non-chelating aldehydes has been developed. This reaction offers a new and atom-economical approach for the selective preparation of 1,5-diketones in high yields. Experimental data suggest a sequential ring-opening, transfer hydrogenation, and hydroacylation mechanism. We propose that aldehyde decarbonylation is avoided by the formation of a novel rhodium enolate species that also accounts for the compatibility of a broad range of aldehydes and its anti-Markovnikov selectivity.
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