期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 8, 页码 2960-2963出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01114
关键词
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资金
- Petroleum Research Fund [PRF#54688-DNI1]
- University of Michigan Office of Research
- NIH/National Institute of General Medical Sciences [GM118644]
- David and Lucile Packard Foundation
- Eli Lilly
Polycyclic aromatic hydrocarbons are important structural motifs in organic chemistry, pharmaceutical chemistry, and materials science. The development of a new synthetic strategy toward these compounds is described based on the design principle of iron(III)-catalyzed carbonyl-olefin metathesis reactions. This approach is characterized by its operational simplicity, high functional group compatibility, and regioselectivity while relying on FeCl3 as an environmentally benign,, earth-abundant metal catalyst. Experimental evidence for oxetanes as reactive intermediates in the catalytic carbonyl-olefin ring-closing metathesis has been obtained.
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