期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 25, 页码 8448-8451出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b05273
关键词
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资金
- European Research Council [ERC-337776]
- MINECO [CTQ2016-78779-R]
- UAM
We have developed a copper-catalyzed substitution reaction of propargylic ammonium salts with aryl Grignard reagents. The reaction is stereospecific and alpha-regioselective and proceeds with exceptional functional group tolerance. Conveniently, a stable, inexpensive, and commercially available copper salt is used and no added ligand is required.
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