期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 12, 页码 4574-4581出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01851
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [26106507, 15K14119, 16H02393]
- Kanagawa Academy of Science and Technology
- Tokyo Tech World Research Hub Initiative (WRHI) Program of Institute of Innovative Research
- Tokyo Institute of Technology
- Helmholtz Association, Germany [VI-I-NG-409]
- 973 Project of the Ministry of Science and Technology of China [2014CB921500]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB07030300]
- NSFC [11574378]
- NSF
- MOST
- Grants-in-Aid for Scientific Research [16H02393, 16H00883, 15K14119] Funding Source: KAKEN
Perovskite PbCoO3 synthesized at 12 GPa was found to have an unusual charge distribution of Pb(2+)Pb(3)(4+)Co(2+)2Co(2)(3+)O(12) with charge orderings in both the A and B sites of perovskite ABO(3). Comprehensive studies using density functional theory (DFT) calculation, electron diffraction (ED), synchrotron X-ray diffraction (SXRD), neutron powder diffraction (NPD), hard X-ray photoemission spectroscopy (HAXPES), soft X-ray absorption spectroscopy (XAS), and measurements of specific heat as well as magnetic and electrical properties provide evidence of lead ion and cobalt ion charge ordering leading to Pb2+Pb34+Co22+Co23+O12 quadruple perovskite structure. It is shown that the average valence distribution of Pb3.5+Co2.5+O3 between Pb3+Cr3+O3 and Pb4+Ni2+O3 can be stabilized by tuning the energy levels of Pb 6s and transition metal 3d orbitals.
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