期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 35, 页码 12109-12112出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b05458
关键词
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资金
- Gobierno de Espana MINECO [CTQ2014-56295-R, 2014-2018 SEV-2013-031]
- FEDER funds [CTQ2014-56295-R]
- CERCA Programme/Generalitat de Catalunya
We report the design, synthesis and characterization of a new RIP metallocavitand that is catalytically active in alkene epoxidation reactions. The elaboration of the resorcin[4]arene's aromatic cavity produced a self-folding, deep hexaamide cavitand featuring a single diverging terpyridine (tpy) group installed at its upper rim. The construction of the metallocavitand involved the initial chelation of a Rum chloride complex by the tpy ligand followed by the incorporation of 2-(phenylazo)pyridine (azpy) as an ancillary ligand. The resulting Ru-II chloro complex was converted into the catalytically active aqua counterpart by a ligand exchange process.
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