期刊
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
卷 21, 期 8, 页码 2415-2423出版社
SPRINGER
DOI: 10.1007/s10008-017-3591-6
关键词
Nickel compound; Metal-organic framework; Supercapacitor; Li-ion battery; Electrochemical property
资金
- National Natural Science Foundation of China [20971060]
- Advanced Catalysis and Green Manufacturing Collaborative Innovation Center
- Natural Science Research Key Project of Jiangsu Colleges and Universities [16KJA430005]
- Natural Science Foundation of State Key Laboratory of Coordination Chemistry
Nickel-based metal-organic framework ([Ni(4,4'-bpy)(tfbdc)(H2O)(2)], Ni-MOF) nanoparticles with the size of 45-250 nm were synthesized by a facile hydrothermal route in combination with a grinding treatment (4,4'-bpy = 4,4'-bipyridine, H(2)tfbdc = tetrafluoroterephthalic acid). The materials were characterized by elemental analysis, IR spectrum, thermogravimetric analysis, powder X-ray diffraction, X-ray photoelectron spectrum (XPS), transmission electron microscope (TEM), scanning electron microscope (SEM), and the Brunauer-Emmett-Teller (BET) surface. As electrode materials for supercapacitors, the Ni-MOF nanoparticles delivered a high specific capacitance of 2548 F g(-1) in 1 M KOH solution at a current density of 1 A g(-1). When applied as anode materials of Li-ion batteries, the Ni-MOF nanoparticles displayed a higher reversible capacity, a better cyclic stability, and a higher rate performance, which still maintained 406 mAh g(-1) after 50 cycles at a current density of 50 mA g(-1). The better electrochemical performances may be attributed to the unique structure feature, and short route for electrolyte/Li-ions diffusion in nanosized Ni-MOF.
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