期刊
JOURNAL OF POWER SOURCES
卷 341, 期 -, 页码 404-410出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2016.12.015
关键词
Sodium-ion hybrid electrolyte battery; Nickel hexacyanoferrate; Seawater; Replaceable cathode; Energy storage
资金
- UNIST [1.160004.01]
- National Research Foundation of Korea [NRF-2014R1A2A1A11052110]
- Korea Research Fellowship Program - Ministry of Science, ICT and Future Planning through the National Research Foundation of Korea [2016H1D3A1909680]
- Ministry of Science & ICT (MSIT), Republic of Korea [2017미래선도형] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2016H1D3A1909680, 2014R1A2A1A11052110] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Sustainable, safe, and low-cost energy storage systems are essential for large-scale electrical energy storage. Herein, we report a sodium (Na)-ion hybrid electrolyte battery with a replaceable cathode system, which is separated from the Na metal anode by a Na superionic conducting ceramic. By using a fast Na-ion-intercalating nickel hexacyanoferrate (NiHCF) cathode along with an eco-friendly seawater catholyte, we demonstrate good cycling performance with an average discharge voltage of 3.4 V and capacity retention >80% over '100 cycles and >60% over 200 cycle. Remarkably, such high capacity retention is observed for both the initial as well as replaced cathodes. Moreover, a Na-metal-free hybrid electrolyte battery containing hard carbon as the anode exhibits an energy density of similar to 146 Wh kg(-1) at a current density of 10 mA g(-1), which is comparable to that of lead-acid batteries and much higher than that of conventional aqueous Na-ion batteries, These results pave the way for further advances in sustainable energy storage technology. (C) 2016 Elsevier B.V. All rights reserved.
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