Article
Chemistry, Inorganic & Nuclear
Filippo Peru, Seyedhosein Payandeh, Torben R. Jensen, Georgia Charalambopoulou, Theodore Steriotis
Summary: A composite material of 0.71 LiBH4-0.29 NaBH4 and CMK-3 carbon with nanopores was successfully synthesized, showing improved hydrogen absorption-desorption kinetics. After five cycles, the composite maintained a consistent uptake of about 3.5 wt.% H-2. The enhanced kinetics were attributed to carbon-hydride surface interactions and the heat transfer capability of the carbon support. The nanopore confinement may also contribute to the improved reversibility.
Review
Chemistry, Physical
Thi Thu Le, Claudio Pistidda, Van Huy Nguyen, Pardeep Singh, Pankaj Raizada, Thomas Klassen, Martin Dornheim
Summary: This review discusses the progress in using metal hydrides and complex metal hydrides as solid-state hydrogen storage materials, as well as improving their performance through nanoconfinement. Researchers believe that magnesium hydride and lithium borohydride are promising solid-state hydrogen storage materials, but issues of thermodynamic stability and kinetics need to be addressed.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Chaochao Dun, Sohee Jeong, Yi-Sheng Liu, Noemi Leick, Tracy M. Mattox, Jinghua Guo, Joo-Won Lee, Thomas Gennett, Vitalie Stavila, Jeffrey J. Urban
Summary: Designing interfaces with thermodynamic and kinetic specificity is crucial for hydrogen storage. The addition of a thin layer of MgCl2 on a porous Mg(BH4)(2)-based framework has been shown to significantly improve hydrogen desorption performance, reduce decomposition temperature and activation barrier, and prevent oxidation of the decomposed system.
Article
Engineering, Environmental
Shun Wang, Mingxia Gao, Zhihao Yao, Yushan Liu, Meihong Wu, Zhenglong Li, Yongfeng Liu, Wenping Sun, Hongge Pan
Summary: A novel structural LiBH4 system has been developed using nanoconfinement technique and in-situ introduced catalysts, which significantly improve its hydrogen storage properties, exhibiting advantages such as low temperature dehydrogenation initiation and rapid desorption.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Jiaguang Zheng, Zhendong Yao, Xuezhang Xiao, Xuancheng Wang, Jiahuan He, Man Chen, Hao Cheng, Liuting Zhang, Lixin Chen
Summary: The study revealed that the LMBH@HCNS composites exhibit significantly improved dehydrogenation properties, with high actual dehydrogenation amounts and fast hydrogen desorption rates. After three cycles, the reversible hydrogen storage capacity increased without obvious degradation.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Green & Sustainable Science & Technology
R. -F. Guo, C. -Y. Hsu, N. Kostoglou, S. Hinder, M. Baker, C. Mitterer, C. Rebholz, C. -Y. Wang
Summary: In this study, the effect of LiBH4@FLG nanoconfinement on the dehydrogenation properties was investigated by loading lithium borohydride into plasma-activated nanoporous few-layer graphene powders with different specific surface areas and functional groups. The results showed that nanoconfinement could significantly decrease the dehydrogenation temperature, and LiBH4@FLG with 400 m2/g surface area and amine groups exhibited the highest dehydrogenation yield.
MATERIALS TODAY SUSTAINABILITY
(2023)
Article
Chemistry, Physical
Jikai Ye, Guanglin Xia, Xuebin Yu
Summary: By reacting graphene-wrapped Al with LiBH4, this study achieved the destabilization of LiBH4, improving the reaction efficiency between LiBH4 and Al and demonstrating complete dehydrogenation and hydrogenation of LiBH4.
MATERIALS TODAY ENERGY
(2021)
Article
Materials Science, Ceramics
Xin Li, Yunzhuo Zhang, Yue Cheng, Xujun Chen, Wenhu Tan
Summary: The MOF-derived ZnCo2O4 with hierarchical microflower structure was synthesized by an easy solvothermal process and annealing, exhibiting excellent gas sensing performance.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Minjie Li, Wenya Xu, Rui Jiang, Mengying Du, Lifang Zhang, Siyuan Yang, Shuangming Wang, Jing Cao
Summary: Hollow porous tube assembled ZnCo2O4 hierarchical porous architectures (HPA) were prepared by a solvothermal strategy and subsequent annealing treatment. The ZnCo2O4 HPA sensor showed enhanced response, fast response/recovery speed, and good repeatability and stability towards xylene gas, indicating its potential application in xylene gas detection.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Chemistry, Physical
J. R. Tena-Garcia, A. Casillas-Ramirez, K. Suarez-Alcantara
Summary: Mixtures of LiAlH4/FeCl2 and LiBH4/FeCl2 were prepared under cryogenic conditions using ball milling, with the optimal production conditions being milling for 30 minutes at -196 degrees C and 15 Hz oscillation frequency. Hydrogen release in LiAlH4/FeCl2 mixtures starts at around 60 degrees C, while LiBH4/FeCl2 mixtures exhibit dehydrogenation starting at 40 degrees C and finishing at about 300 degrees C. The formation of LiCl is considered the driving force behind the decomposition reactions in these reactive mixtures. Cryogenic ball-milling has a positive effect on production and low-temperature dehydrogenation of the studied samples.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Nanoscience & Nanotechnology
Yong Zhang, Yang Xia, Linxi Wang, Bei Cheng, Jiaguo Yu
Summary: In this study, flower-like hierarchical ZnO microspheres were prepared by hydrothermal method followed by calcination at different temperatures, and their performance in H2O2 production was examined under simulated sunlight irradiation. The ZnO calcined at 300 degrees C exhibited the highest activity and optimal stability. Additionally, cycling experiments indicated good stability and long-term performance of the prepared ZnO samples.
Article
Chemistry, Physical
Baole Li, Ke Zhang, Shaopeng Qi, Yanmei Guo, Jinxi Chen, Yongbing Lou
Summary: This study successfully improves the cyclic stability of pseudocapacitive materials by constructing a hierarchical ZnCo2O4-ZnO/ZnCo2O4 core-shell microarchitecture composite. The material exhibits high specific capacity, ultra-high rate capability, significant pseudocapacitance contribution, and ultra-long cycle stability.
APPLIED SURFACE SCIENCE
(2022)
Article
Engineering, Environmental
Li Ren, Wen Zhu, Qiuyu Zhang, Chong Lu, Fengzhan Sun, Xi Lin, Jianxin Zou
Summary: In this study, a novel hierarchically porous carbon nanofiber was synthesized and used as a support for magnesium hydride/nickel nanoparticles, resulting in improved hydrogen desorption performance. The nanocomposites exhibited faster desorption kinetics, lower onset desorption temperature, and higher hydrogen absorption capacity at a lower temperature.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Physics, Applied
You Zhou, Yong Sun, Juan Feng, Xinghua Li
Summary: A flower-like ZnO/SnS2 heterojunction was constructed as a photocatalyst, which showed improved efficiency in the degradation of organic dye and hydrogen evolution. This enhancement was attributed to the special hierarchical structure and synergetic effect of the ZnO/SnS2 heterojunction, which increased the specific surface area and promoted the separation of photogenerated electron-hole pairs.
APPLIED PHYSICS EXPRESS
(2022)
Article
Chemistry, Physical
J. R. Tena-Garcia, M. Osorio-Garcia, K. Suarez-Alcantara
Summary: Mixtures of LiBH4/VCl3 and LiAlH4/VCl3 with different stoichiometries were prepared and tested for hydrogen release. The mixtures showed diverse hydrogen release levels and exhibited a change in reaction pathway at low temperatures.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Materials Science, Multidisciplinary
Yao Wang, Yukun Liu, Pingge He, Junteng Jin, Xudong Zhao, Qiuyu Shen, Jie Li, Xuanhui Qu, Yongchang Liu, Lifang Jiao
Summary: Researchers successfully enhanced the structural stability and battery performance of sodium-ion battery cathode materials by selectively substituting the chromium element. The newly developed material, Na3.9MnCr0.9Zr0.1(PO4)(3)/C, exhibited a high capacity retention of 85.94% over 500 cycles at high charge rates, and an ultra-high capacity of 156.4 mAh/g at low charge rates, enabling stable energy output as high as 555.2 Wh/kg. This study provides new opportunities for designing high-energy and high-stability NASICON cathodes through ion doping.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hongye Qin, Yukun Ye, Jinhong Li, Wenqi Jia, Siyu Zheng, Xuejie Cao, Guangliang Lin, Lifang Jiao
Summary: Nickel hydroxide has been identified as a promising electrocatalyst for urea oxidation reaction. By doping vanadium and creating oxygen vacancies, the catalyst's activity is enhanced by increasing the number of active sites and lowering the energy barrier for the reaction.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Qiuyu Shen, Yongchang Liu, Xudong Zhao, Junteng Jin, Xiaobai Song, Yao Wang, Xuanhui Qu, Lifang Jiao
Summary: Initiating anionic redox chemistry in layered sodium oxide cathodes is a prevalent method to break the capacity limit set by traditional transition metal redox. This study uncovers a Mn activation mechanism in a novel P2-Na0.80Li0.08Ni0.22Mn0.67O2 cathode, which achieves high discharge capacity and long cycling life by triggering anionic redox and reducing Mn through oxygen loss. The work elucidates the charge compensation mechanism and expands the horizons of oxygen redox chemistry for high-performance layered oxide cathode materials in sodium-ion batteries.
ADVANCED ENERGY MATERIALS
(2023)
Review
Chemistry, Physical
Kunjie Zhu, Zhiqin Sun, Zhaopeng Li, Pei Liu, Haixia Li, Lifang Jiao
Summary: Due to the higher freezing point of conventional aqueous electrolytes, the development and practical applications of aqueous rechargeable energy storage (ARES) at low temperature are limited. In this paper, the design principles for low-temperature ARES with excellent performance are discussed, especially in terms of electrode modification and electrolyte regulation. The related studies on low-temperature ARES are comprehensively summarized, and suggestions for addressing the current challenges are provided.
ADVANCED ENERGY MATERIALS
(2023)
Review
Electrochemistry
Zelin Wang, Chunwen Sun, Liang Lu, Lifang Jiao
Summary: Solid state Na-CO2 batteries are a promising energy storage system that utilizes excess CO2 for electrochemical energy storage. Despite their high theoretical energy densities, the practical application of Na-CO2 battery technology faces challenges such as short cycle life, high charging potential, poor rate performance, and lower specific full discharge capacity.
Article
Chemistry, Multidisciplinary
Xiayan Jian, Qiuyu Shen, Xudong Zhao, Junteng Jin, Yao Wang, Shengwei Li, Xuanhui Qu, Lifang Jiao, Yongchang Liu
Summary: This study reports a new type of ultrathin VOPO4 nanosheets as cathodes for sodium-ion batteries, achieving higher capacity and rate performance through redox reactions and ClO4- insertion/extraction. The mechanism of anionic redox reactions is elucidated, opening up a new avenue for high-energy phosphate cathodes for SIBs.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Zhaopeng Li, Hongye Qin, Wenyue Tian, Licheng Miao, Kangzhe Cao, Yuchang Si, Haixia Li, Qinglun Wang, Lifang Jiao
Summary: A flexible 3D hollow porous carbon nanofiber framework embedded with Sb nanoparticles (Sb@HPCNF) is reported to enhance the safety and stability of sodium metal batteries (SMBs). The framework enables highly reversible Na plating-stripping cycles for over 550 hours at 5 mA cm(-2) and exhibits excellent high-rate performance. This study provides new insights for constructing functionalized 3D composite frameworks for next-generation high-safety and high-energy SMBs.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Junteng Jin, Yongchang Liu, Xudong Zhao, Hui Liu, Shiqing Deng, Qiuyu Shen, Ying Hou, He Qi, Xianran Xing, Lifang Jiao, Jun Chen
Summary: Annealing in argon is a universal strategy to upgrade the Na-storage performance of Mn-based oxide cathodes by introducing bulk oxygen vacancies, reducing Mn valence, lowering Mn 3d-orbital energy level, and forming new-concept Mn domains. This method increases the energy density and promotes cycling stability, providing a new avenue towards high-performance Mn-based oxide cathodes for sodium-ion batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Pei Liu, Licheng Miao, Zhiqin Sun, Xuchun Chen, Yuchang Si, Qinglun Wang, Lifang Jiao
Summary: This study proposes an integrated multifunctional solid electrolyte interphase (SEI) with inorganic/organic hybrid construction to enhance the durability of sodium metal anode. The inorganic components improve ionic conduction efficiency and inhibit dendrite formation, while the organic component forms a dense and elastic membrane structure to prevent fracture and delamination issues. Experimental results show that the proposed SEI can achieve stable cycling over 2000 hours at a high current density, with a very low voltage hysteresis.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Pei Liu, Tiantian Zhan, Xuchun Chen, Haixia Li, Qinglun Wang, Wenbo Lu, Lifang Jiao
Summary: O3-type layered oxides have great potential as cathode materials for sodium-ion batteries, but their practical applications are hindered by structural instability and irreversible phase transitions. This study demonstrates a feasible strategy to construct stabilized O3-type layered oxides by doping with a transition metal ion (Zn2+), which improves capacity retention and lifespan, offering a promising approach for high-performance sodium-ion batteries.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Yao Wang, Xudong Zhao, Junteng Jin, Qiuyu Shen, Yang Hu, Xiaobai Song, Han Li, Xuanhui Qu, Lifang Jiao, Yongchang Liu
Summary: This study unravels the reductive coupling mechanism (RCM) in a novel P2-Na0.8Cu0.22Li0.08Mn0.67O2 cathode, which boosts the reversibility and kinetics of anionic redox reactions. The formation of strong covalent Cu-(O-O) bonding effectively suppresses excessive oxygen oxidation and irreversible cation migration, resulting in a cathode with remarkable rate capability and long-term cycling stability.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Tao Zhang, Ji Kong, Chao Shen, Shengjie Cui, Zezhou Lin, Yuyu Deng, Minghao Song, Lifang Jiao, Haitao Huang, Ting Jin, Keyu Xie
Summary: This study introduces acetic acid in layered cathode materials to form sodium acetate and successfully achieves efficient sodium compensation. Based on sodium compensation, the capacity retention and energy density of the battery have been significantly improved.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Physical
Han Li, Yao Wang, Xudong Zhao, Junteng Jin, Qiuyu Shen, Jie Li, Yukun Liu, Xuanhui Qu, Lifang Jiao, Yongchang Liu
Summary: Natriumsuperionic conductor (NASICON)-type phosphates with 3D open frameworks have attracted attention as cathodes for sodium-ion batteries. However, they suffer from mediocre energy density and rapid capacity decay. In this study, a multielectron reaction and low-strain Na(3.5)Fe(0.5)V-Cr-0.5(PO4)(3)/C cathode material was designed, which exhibited high working voltage, high reversible capacity, and high cycling stability.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Physical
Tongzhou Wang, Licheng Miao, Siyu Zheng, Hongye Qin, Xuejie Cao, Lei Yang, Lifang Jiao
Summary: In this study, a simple synthesis of Ni3N/Mo2N heterostructure was reported, and urea-assisted electrolytic hydrogen production was systematically investigated. It was found that the -NH2 and C=O groups of the urea molecule were more easily adsorbed on Ni3N and Mo2N, respectively. The Ni3N/Mo2N heterostructure optimized the adsorption of urea and improved the hydrogen evolution reaction performance, leading to a much lower voltage (1.36 V @ 10 mA cm-2) and a 7 times higher hydrogen production rate in the urea-assisted water electrolyzer.
Article
Chemistry, Multidisciplinary
Chen Chen, Tianhao Wang, Xudong Zhao, Aiduo Wu, Shengwei Li, Ning Zhang, Xuanhui Qu, Lifang Jiao, Yongchang Liu
Summary: The study demonstrates the fabrication of OH-termination-rich V₂CTx material with interlayer K+-pillars (alk-V₂CTx) using a one-step alkalization method. The alk-V₂CTx cathode exhibits excellent reversibility and rapid Li+/Zn2+ co-insertion/extraction electrochemistry, along with superior rate performance and exceptional cycling life. The study also investigates the hybrid-ion storage mechanisms and presents flexible quasi-solid-state rechargeable Zn batteries with inspiring energy output even under severe deformation conditions and low temperatures.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu
Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen
Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu
Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing
Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen
Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang
Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo
Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu
Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas
Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov
Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei
Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur
Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea
Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang
Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu
Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.
JOURNAL OF POWER SOURCES
(2024)
