期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 55, 期 8, 页码 1442-1450出版社
WILEY
DOI: 10.1002/pola.28513
关键词
ammonium groups; ion conductive polymers; ion exchangers; membranes; polyaromatics; terpolymers
资金
- CREST JST
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) Japan [26289254, 16K18258]
- Grants-in-Aid for Scientific Research [26289254, 16K18258] Funding Source: KAKEN
Synthesis and properties of a series of ammonium-containing terpolymers (QPAF-3) as anion conductive membranes are reported. The QPAF-3s composed of perfluoroalkylene, alkylene, and ammonium-functionalized phenylene groups without heteroatom linkages in the main chain were synthesized via nickel-mediated polycondensation reaction, followed by chloromethylation, quaternization, and ion exchange reactions. Self-standing, bendable membranes were obtained by solution casting. The QPAF-3 membrane with optimized terpolymer composition and ion exchange capacity (1.46 meq g(-1)) showed high hydroxide ion conductivity (123 mS cm(-1) in water at 80 degrees C). The alkaline stability test in 1 M KOH for 1000 h at 80 degrees C and the posttest analysis with IR spectra and tensile strength suggested that ammoniumgroups were likely to be decomposed while the polymer main chain was chemically more robust. The presence of the alkylene groups in the terpolymers lowered solubility, glass transition temperature, and elongation property of the resulting membranes. (C) 2017 Wiley Periodicals, Inc.
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