期刊
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
卷 110, 期 -, 页码 173-179出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2017.06.013
关键词
Gold nanoparticles; Direct reduction; Regenerable sorbent; Mercury capture
资金
- Spanish Ministry of Science and Innovation [JAEPre076]
- European Regional Developments Funds [ENE2011-23412]
- CSIC
- European Regional Developments Funds
A sorbent based on gold nanoparticles deposited by direct reduction of a gold salt on a structured carbon surface has been prepared to be used in the mercury capture at low concentrations. A total of 13 samples have been obtained varying preparation conditions (stirring rate, gold salt concentration and contact time). A kinetic study of the gold reduction on the carbon surface has been carried out, indicating that the calculated reaction rate constant corresponds to the diffusion rate equation. The study of the influence of gold salt concentration on the reduction potential of the gold showed that the use of a high concentration gold salt solution shifts the reduction reaction to gold reduction. Mercury capture capacity cannot be directly related with either gold content or average particle size or average crystal size, but the study of the grain size distribution can explain the mercury capture performance of the samples.
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