Article
Chemistry, Multidisciplinary
Jili Xu, Heng Wang, Ting He, Xiao Yan, Jia Yu, Jingkun Bi, Daixin Ye, Wenli Yao, Ya Tang, Hongbin Zhao, Jiujun Zhang
Summary: Modifying sulfur cathodes with Chevrel phase Mo6S8 nanosheets can effectively address the challenging problems in Li-S batteries. Unlike previous inactive hosts, the Mo6S8 reaction is intercalative and can dynamically enhance the adsorbability for LiPSs and ionic conductivity through reversible electrochemical lithiation. As a result, Mo6S8 nanosheets act as a dynamic-phase promoter and exhibit superior cycling stability, high-rate capability, and low-temperature performance in Li-S batteries. This study opens a new avenue for the development of high-performance Li-S batteries with dynamic regulation activity.
Article
Chemistry, Multidisciplinary
Liping Wang, Piotr Jankowski, Christian Njel, Werner Bauer, Zhenyou Li, Zhen Meng, Bosubabu Dasari, Tejs Vegge, Juan Maria Garcia Lastra, Zhirong Zhao-Karger, Maximilian Fichtner
Summary: A functional Mo6S8 modified separator is designed to address the challenges in magnesium-sulfur batteries, resulting in improved performance and cycling stability.
Article
Chemistry, Physical
Yuxin Tong, Ang Gao, Qinghua Zhang, Tao Gao, Jinming Yue, Fanqi Meng, Yue Gong, Shibo Xi, Zejing Lin, Minglei Mao, Siyuan Peng, Xuefeng Wang, Dongdong Xiao, Dong Su, Yanhong Luo, Hong Li, Liquan Chen, Liumin Suo, Lin Gu
Summary: The study demonstrates how cation-synergy stabilization can enable anion redox of Chevrel phase Mo6S8 in aluminum ion batteries, with atomic-resolved imaging revealing the crucial role of Mo-Mo bond contraction and elongation in maintaining structural stability.
ENERGY STORAGE MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Zhenyou Li, Thomas Diemant, Zhen Meng, Yanlei Xiu, Adam Reupert, Liping Wang, Maximilian Fichtner, Zhirong Zhao-Karger
Summary: The study demonstrates that introducing Mg(BH4)(2) additive improves the performance of the anode-electrolyte interface in magnesium batteries, promoting the formation of a stable solid electrolyte interphase layer and enhancing the cycling and rate capabilities of the battery.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Chemistry, Physical
Kok Long Ng, Brohath Amrithraj, Gisele Azimi
Summary: This review focuses on summarizing reported cathode materials and their charge storage mechanisms in nonaqueous rechargeable Al batteries (RABs). It critically discusses the implications of overall cell chemistries on actual battery performance metrics, outlines the fundamental and practical limitations of existing RAB chemistries, and emphasizes the importance of accurately elucidating the underlying charge storage mechanism. The ion migration kinetics in existing electrodes are discussed, and design guidelines for enhancing their performance are provided.
Article
Electrochemistry
Katharina Helmbrecht, Holger Euchner, Axel Gross
Summary: This study investigates the impact of dispersion forces on MO6S8 chevrel phase intercalation compounds. Dispersion forces have only a slight effect on the lattice spacing of the chevrel phase, but have a significant impact on the insertion voltage and charge carrier mobility. Additionally, the diffusion barriers of charge carriers in the chevrel phase scale linearly with ion size, regardless of the ion charge.
BATTERIES & SUPERCAPS
(2022)
Article
Electrochemistry
Ben Dlugatch, Janina Drews, Ran Attias, Bar Gavriel, Adar Ambar, Timo Danner, Arnulf Latz, Doron Aurbach
Summary: This study examines the effect of adding chlorides to the state-of-the-art electrolyte solution, and finds that the presence of chlorides facilitates reversible magnesium deposition and ion intercalation.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Engineering, Environmental
Zhaojian Sun, Hong Miao, Muhammad Khurram, Ziming Zhang, Yongfa Zhu, Qingfeng Yan
Summary: A mild bottom-up approach was used to prepare quasi-monolayer black phosphorus (BP) from precursor red phosphorus, unlocking new opportunities for photocatalytic H-2 evolution. The intercalation of diamine compounds improved the stability and significantly enhanced the photocatalytic activity of quasi-monolayer BP.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Amr Elgendy, Athanasios A. Papaderakis, Conor Byrne, Zhaozong Sun, Jeppe Lauritsen, Elliot P. C. Higgins, Andinet Ejigu, Robert Cernik, Alex S. Walton, David J. Lewis, Robert A. W. Dryfe
Summary: This study presents a simple and efficient method for synthesizing nanoparticulate ternary Chevrel phases without using hydrogen gas as a reducing agent. The successful formation of Cu2Mo6S8 CP with homogeneous nanoscale structure was confirmed through various analyses. The synthesized CP exhibited promising electrocatalytic activity for hydrogen evolution reaction in acidic media, showing potential for applications in electrocatalysis.
ACS APPLIED ENERGY MATERIALS
(2021)
Review
Electrochemistry
Ran Attias, Daniel Sharon, Yosef Goffer, Doron Aurbach
Summary: This review summarizes recent progress in understanding cathodes/electrolyte solutions interfaces in non-aqueous Mg systems, describing the sequential steps taking place in the electrochemical intercalation reactions and discussing how the chemical characteristics of electrolyte solutions impact each step of the intercalation process.
Article
Nanoscience & Nanotechnology
Tjasa Pavcnik, Matic Lozinsek, Klemen Pirnat, Alen Vizintin, Toshihiko Mandai, Doron Aurbach, Robert Dominko, Jan Bitenc
Summary: High-performance electrolytes are crucial for the development of magnesium batteries. This study provides a comprehensive characterization of the novel Mg[Al(hfip)(4)](2) salt in various glyme-based electrolytes, emphasizing the influence of water content and additives. The results highlight the high tolerance of Mg[Al(hfip)(4)](2)-based electrolytes to water and the beneficial effect of additives under challenging cycling conditions. A comparison with the state-of-the-art Mg[B(hfip)(4)](2) salt demonstrates the improved performance of electrolytes containing Mg[Al(hfip)(4)](2) and establishes it as a new standard salt for future magnesium battery research.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Pengfei Yu, Yujian Xia, Xuefei Feng, Shun Zheng, Guoxi Ren, Nian Zhang, Xiaosong Liu, Cheng Chen, Xiangxin Guo
Summary: The reaction mechanism of Li+ intercalation into Mo6S8 was studied using in-situ tender X-ray absorption spectroscopy in the viewpoint of local structure. It was found that the discharge and charge processes exhibit asymmetry in the reaction path, and the regions of two-phase transition reactions were identified. These results provide insights into the phase transitions of Mo6S8. Additionally, itXAS is demonstrated as a powerful tool for studying the reaction mechanism of Mo6S8.
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Netanel Shpigel, Arup Chakraborty, Fyodor Malchik, Gil Bergman, Amey Nimkar, Bar Gavriel, Meital Turgeman, Chulgi Nathan Hong, Maria R. Lukatskaya, Mikhael D. Levi, Yury Gogotsi, Dan T. Major, Doron Aurbach
Summary: Despite significant progress in the development of Ti3C2Tx (MXene) electrodes for high-power batteries and supercapacitors, the role of anions in electrochemical energy storage and their ability to intercalate between MXene sheets remains unclear. It has been demonstrated that the insertion of anionic species into MXene within the potential range of interest for capacitive energy storage is unlikely, possibly due to the strong negative charge on Ti3C2Tx sheets terminated by functional groups.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Cristina Madrona, Maria Vila, Freddy E. Oropeza, Victor A. de la Pena O'Shea, Juan J. Vilatela
Summary: This study demonstrates the intercalation of FeCl3 into fibers made up of collapsed carbon nanotubes, showing increased stability and conductivity of the intercalated system. Substantial electron transfer from the carbon nanotubes to FeCl3 was observed, resulting in a significant increase in conductivity and charge carrier concentration in the system.
Review
Chemistry, Multidisciplinary
Tianming Liu, Guocheng Lv, Meng Liu, Changchun Zhao, Libing Liao, Hao Liu, Jiayan Shi, Jian Zhang, Juchen Guo
Summary: This critical review discusses the current research on cation-intercalation and conversion-type cathode materials for rechargeable aluminum batteries (RABs), focusing on the understanding of reaction mechanisms in different materials. The unique reversible oxidation mechanisms of sulfur and selenium enabled by chloroaluminate ionic liquid electrolytes are highlighted, along with discussions on organic cathode materials.
MATERIALS CHEMISTRY FRONTIERS
(2022)
Article
Agricultural Engineering
Carolina del Mar Saavedra Rios, Virginie Simone, Loic Simonin, Sebastien Martinet, Capucine Dupont
BIOMASS & BIOENERGY
(2018)
Article
Chemistry, Physical
David Peralta, Jeremie Salomon, Jean-Francois Colin, Adrien Boulineau, Frederic Fabre, Carole Bourbon, Benjamin Amestoy, Elise Gutel, Didier Bloch, Sebastien Patoux
JOURNAL OF POWER SOURCES
(2018)
Article
Chemistry, Physical
Linda Ager-Wick Ellingsen, Alex Holland, Jean-Francois Drillet, Willi Peters, Martin Eckert, Carlos Concepcion, Oscar Ruiz, Jean-Francois Colin, Etienne Knipping, Qiaoyan Pan, Richard G. A. Wills, Guillaume Majeau-Bettez
Article
Chemistry, Physical
Camelia Matei Ghimbeu, Joanna Gorka, Virgine Simone, Loic Simonin, Sebastien Martinet, Cathie Vix-Guterl
Article
Multidisciplinary Sciences
Guillaume Tonin, Gavin Vaughan, Renaud Bouchet, Fannie Alloin, Marco Di Michiel, Laura Boutafa, Jean-Francois Colin, Celine Barchasz
SCIENTIFIC REPORTS
(2017)
Article
Chemistry, Physical
Ida Kallquist, Jean-Frederic Martin, Andrew J. Naylor, Christian Baur, Maximilian Fichtner, Jean-Francois Colin, Daniel Brandell, Kristina Edstrom, Maria Hahlin
JOURNAL OF PHYSICAL CHEMISTRY C
(2020)
Article
Chemistry, Physical
Andrew J. Naylor, Ida Kallquist, David Peralta, Jean-Frederic Martin, Adrien Boulineau, Jean-Francois Colin, Christian Baur, Johann Chable, Maximilian Fichtner, Kristina Edstrom, Maria Hahlin, Daniel Brandell
ACS APPLIED ENERGY MATERIALS
(2020)
Article
Chemistry, Physical
Youcef Kerdja, Marion Chandesris, Sebastien Martinet
Summary: This study investigates the influence of different transport and insertion kinetics parameters on battery performances through numerical simulations, focusing on the electrode's microstructure level. It shows that interfacial insertion kinetics have the most significant impact on discharge capacity, followed by lithium liquid and solid diffusions. Additionally, a statistical analysis on the parameters' influence on particles lithiation heterogeneities is presented for the first time in this paper.
JOURNAL OF POWER SOURCES
(2021)
Article
Electrochemistry
David Peralta, Jeremie Salomon, Yvan Reynier, Jean-Frederic Martin, Eric De Vito, Jean-Francois Colin, Adrien Boulineau, Carole Bourbon, Benjamin Amestoy, Celine Tisseraud, Roger Pellenc, Jean-Louis Ferrandis, Didier Bloch, Sebastien Patoux
Summary: DMD process is common in high manganese spinel cathode materials, with coating or doping as the main approach to address it; this study reveals the DMD phenomenon in silicon-graphite/lithium rich layered oxide systems, and the AlF3 coating can improve electrochemical performance but cannot completely prevent transition metal ions dissolution.
ELECTROCHIMICA ACTA
(2021)
Article
Engineering, Chemical
David Peralta, Anna -Caroline Lavergne-Bril, Emmanuel Billy, Jean-Francois Colin, Didier Bloch, Sebastien Patoux
Summary: The demand for cobalt is expected to sharply increase due to the intensive development of Li-ion batteries for transportation applications, while more than half of cobalt production is concentrated in the Democratic Republic of the Congo, making recycling and reusing cobalt from used batteries crucial to limit imports.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Physical
Yagmur Celasun, Jean-Francois Colin, Sebastien Martinet, Anass Benayad, David Peralta
Summary: Lithium-rich disordered rocksalt Li2TiS3 is a promising cathode material for high-energy lithium-ion batteries due to its large discharge capacity. However, the quick fading of specific capacity results in poor cycle life. Our study discovered new high-energy selenium-substituted materials (Li2TiSexS3-x) with improved cycling stability and large reversible capacities.
Article
Chemistry, Physical
Samuel Tardif, Nicolas Dufour, Jean-Francois Colin, Gerard Gebel, Manfred Burghammer, Andreas Johannes, Sandrine Lyonnard, Marion Chandesris
Summary: This study investigates the distribution of lithium ions within graphite electrodes in lithium-ion batteries, revealing different patterns at different lithiation stages. By combining experimental and modeling approaches, it is shown that the kinetics of lithium intercalation is reduced during certain phase transitions, leading to imbalanced competing forces within the graphite electrodes.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Electrochemistry
A. Iturrondobeitia, A. Kvasha, J-M. Lopez del Amo, J. F. Colin, D. Sotta, I. Urdampilleta, M. Casas-Cabanas
ELECTROCHIMICA ACTA
(2017)
Proceedings Paper
Electrochemistry
G. Lefevre, J. B. Ducros, M. Nestoridi, F. Renard, J. F. Colin, D. Peralta, M. Chakir, M. Chapuis, S. Martinet
11TH EUROPEAN SPACE POWER CONFERENCE
(2017)