期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 13, 页码 7040-7044出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01003
关键词
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Conditions have been developed for the palladium-catalyzed cyanation of aryl bromides utilizing the air-stable XantPhos-PdCl2 precatalyst. By employing a trialkylamine as a reducing agent, the active Pd(0) species is generated in situ, alleviating the need to employ the air-sensitive Pd-2(dba)(3). Twenty-two substituted benzonitriles have been synthesized using this method.
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