4.6 Article

Removal of Hg0 from Flue Gas Using Two Homogeneous Photo-Fenton-Like Reactions

期刊

AICHE JOURNAL
卷 61, 期 4, 页码 1322-1333

出版社

WILEY
DOI: 10.1002/aic.14727

关键词

Hg-0 removal; photo-Fenton-like reactions; flue gas; simultaneous removal of Hg-0, NO, and SO2

资金

  1. National Natural Science Foundation of China [51206067]
  2. National Key Basic Research Program 973 Project of China [2013CB228504]
  3. Open Research Fund Program of Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education (Southeast University)
  4. Key Laboratory of Efficient & Clean Energy Utilization, College of Hunan Province (Changsha University of Science Technology)
  5. Training Project of Jiangsu University Youth Backbone Teacher

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Removal of Hg-0 using two homogeneous Photo-Fenton-Like reactions was first investigated in a photochemical reactor. Effects of process parameters on Hg-0 removal were studied. Free radical and reaction products were analyzed. Removal pathways of Hg-0 were discussed. Simultaneous removal of Hg-0, NO, and SO2 is also studied briefly. The results show that UV power, wavelength, H2O2 concentration, and solution pH have great effects on Hg-0 removal. Hg-0, and SO2 concentrations, solution temperature, Fe3+, Cu2+, CO32-, and HCO3- concentrations also have significant effects on Hg-0 removal. However, concentrations of CO2, NO, O-2, Cl-, NO3-, SO42-, SiO2, Al2O3, and Fe2O3 only have slight effects on Hg-0 removal. Hg-0/NO/SO2 can be simultaneously removed by Photo-Fenton-Like reactions. center dot OH was captured, and SO42-/NO3-/Hg2+ were also detected. Removals of Hg-0 by photochemical oxidation and center dot OH oxidation play a major role, and removal of Hg-0 by H2O2 oxidation only plays a secondary role in removal of Hg-0. (C) 2015 American Institute of Chemical Engineers

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