期刊
JOURNAL OF NATURAL PRODUCTS
卷 80, 期 10, 页码 2850-2854出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jnatprod.7b00714
关键词
-
资金
- TASCMAR project
- European Union [634674]
- IRD
Two sporothriolide-related compounds were obtained from an extract of the fungus Hypoxylon monticulosum CLL-205, isolated from a Sphaerocladina sponge collected from the Tahiti coast. Compound 2 is a deoxy analogue of sporothric acid (4). Compound 3 is a newly reported unusual scaffold combining sporothriolide (1) and trienylfuranol A (5) moieties, through a Diels-Alderase-type reaction. Various experimental and analytical arguments supported the biocatalytic origin of compound 3. The structures of the isolated compounds were elucidated using 1D and 2D NMR, HRMS, and IR data. The structure and the absolute configuration of 3 were unambiguously confirmed by a single-crystal X-ray diffraction analysis.
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