期刊
AICHE JOURNAL
卷 61, 期 10, 页码 3459-3469出版社
WILEY-BLACKWELL
DOI: 10.1002/aic.14924
关键词
hollow fiber; MFI zeolite membrane; membrane reactor; water gas shift reaction
资金
- National Natural Science Foundation of China [21490585, 21222602, 21176117]
- Key Project of Chinese Ministry of Education [212060]
- Outstanding Young Fund of Jiangsu Province [BK2012040]
- Six Top Talents of Jiangsu Province
- 333 Talent Project of Jiangsu Province
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [09KJA530002]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Hollow fiber MFI zeolite membranes were modified by catalytic cracking deposition of methyldiethoxysilane to enhance their H-2/CO2 separation performance and further used in high temperature water gas shift membrane reactor. Steam was used as the sweep gas in the MR for the production of pure H-2. Extensive investigations were conducted on MR performance by variations of temperature, feed pressure, sweep steam flow rate, and steam-to-CO ratio. CO conversion was obviously enhanced in the MR as compared with conventional packed-bed reactor (PBR) due to the coupled effects of H-2 removal as well as counter-diffusion of sweep steam. Significant increment in CO conversion for MR vs. PBR was obtained at relatively low temperature and steam-to-CO ratio. A high H-2 permeate purity of 98.2% could be achieved in the MR swept by steam. Moreover, the MR exhibited an excellent long-term operating stability for 100 h in despite of the membrane quality. (c) 2015 American Institute of Chemical Engineers AIChE J, 61: 3459-3469, 2015
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