期刊
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
卷 28, 期 12, 页码 8596-8600出版社
SPRINGER
DOI: 10.1007/s10854-017-6583-5
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资金
- NSFC [21407025]
- National Science Foundation of Fujian Province [2016J01047]
- National Program for the Fujian Provincial Science and Technology
- Provincial Financial Department [2013H6007]
- Outstanding Youth Research Training Program of University of Fujian Province
The color-tunable fluorescent LaOCl:Eu3+, Ce4+ nanofibers were successfully fabricated via an electrospinning combined with calcination route, in which PVA was employed as a template. XRD, TG-DTG results show that the heat-treatment of the nanofibers at 750 degrees C is enough to obtain highly crystallized LaOCl:Eu3+, Ce4+ samples. Scanning electron microscopy analysis indicates that LaOCl: Eu3+, Ce4+ nanofibers are composed of wafer nanograins with mean diameter of similar to 30 nm. Photoluminescence analysis shows that the luminescence intensity has changed with the varying Ce4+ doping content in LaOCl:Eu3+ nanofibers. Additionally, CIE chromaticity coordinates of LaOCl:5% Eu3+, x% Ce4+ nanofibers change from orange light region of (0.4997, 0.4828) and (0.5232, 0.4627) at x = 5.0 and 2.5 to red light region of (0.5661, 0.4251) at x = 1.7, then to orange light region of (0.5590, 0.4318) at x = 1.0, respectively. Hence the fluorescence color of LaOCl:Eu3+, Ce4+ nanofibers can be tuned by simply adjusting the Eu/Ce ratio, which is a promising candidate for application in LEDs.
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