Article
Environmental Sciences
Guoyang Zhang, Zhichao Yang, Qing Teng, Yingqi Han, Suhong Zhang, Shengyu Liu
Summary: Green and efficient separation adsorbents are highly sought after for the treatment of heavy metal ions wastewater. In this study, xanthan gum (XG) supported by fly ash magnetic beads (FAMB) was used to create adsorbent XG@FAMB. The effects of XG@FAMB dosage, solution pH, adsorption time, and initial concentration of Pb (II) and Cu (II) on the adsorption performance were investigated, and the maximum adsorption capacity of XG@FAMB for Pb (II) and Cu (II) was found to be 14.93 mg/g and 14.88 mg/g, respectively. XG@FAMB exhibited a monolayer adsorption mechanism controlled by chemical action, where Pb (II) and Cu (II) were coordinated with oxygen-containing functional groups on the XG@FAMB surface and accompanied by electrostatic adsorption. XG@FAMB combines the environmental protection advantages of XG and the easy solid-liquid separation properties of FAMB, showing good removal efficiency for Pb (II) and Cu (II).
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Environmental Sciences
Seung-Hee Hong, Myung-Chul Shin, Jechan Lee, Chang-Gu Lee, Dae-Sung Song, Byung-Hwan Um, Seong-Jik Park
Summary: The study investigated the use of bottom ash generated from the combustion of cattle manure as an adsorbent for the removal of heavy metals from aqueous solutions. The results showed that the adsorption of Cd(II), Cu(II), Pb(II), and Ni(II) onto the bottom ash followed the pseudo-second-order kinetic model and was well-described by the Freundlich isotherm model. Thermodynamic analysis revealed that the adsorption onto the bottom ash was endothermic, and the presence of cations such as Na+, Ca2+, and Al3+ reduced the amount of metals adsorbed onto the BA-CCM.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Environmental Sciences
Zhen Zhang, Tao Wang, Huixue Zhang, Yonghong Liu, Baoshan Xing
Summary: Magnetized activated carbons (MAC) prepared from rape straw powder showed high adsorption capacities for Pb(II) and Cd(II) due to surface active points, with adsorption behavior conforming to the Freundlich model and pseudo-second-order kinetic model. Thermodynamic parameters indicated spontaneous and endothermic reactions. Adjusting the pH of the solution could enhance adsorption capacity, but competitive adsorption occurred in the presence of high-valent ions. Adsorption mechanisms included electrostatic attraction, surface complexation, and co-precipitation. The MAC material showed potential for heavy metal ion removal from aqueous solutions.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Agricultural Engineering
Yue Zhang, Yongshan Wan, Yulin Zheng, Yicheng Yang, Jinsheng Huang, Hao Chen, Guixiang Quan, Bin Gao
Summary: Hydrochars derived from hydrothermal carbonization of hickory wood, bamboo, and wheat straw were modified with potassium permanganate for effective sorption of heavy metals. The modified wheat straw hydrochar (WSHyC-0.2KMnO(4)) exhibited the highest adsorption capacity, attributed to its large specific surface area, abundant surface oxygenic functional groups, and significant presence of MnOx microparticles. Batch adsorption experiments demonstrated that WSHyC-0.2KMnO(4) had a faster adsorption rate and much higher adsorption capacity (12-17 times) for Pb(II), Cd(II), and Cu(II) compared to WSHyC, due to increased OCFG and MnOx microparticles on its surface facilitating ion exchange, electrostatic interactions, and complexation mechanisms.
BIORESOURCE TECHNOLOGY
(2023)
Article
Polymer Science
Huda Alsaeedi, Hilal Ahmad, Malak Faisal Altowairqi, Afnan Abdullah Alhamed, Ali Alsalme
Summary: Cellulose nanoparticles were synthesized and covalently functionalized with multi-functional group for their excellent application in environmental remediation technology. The hybrid material demonstrated excellent adsorption properties for simultaneous extraction of multiple metal ions. The sorbent exhibited a sorption capacity in the range of 1.8-2.2 mmol/g. The method was successfully employed for simultaneous extraction and determination of Pb(II), Cd(II) and Cu(II) from real-world samples, with a preconcentration limit of 0.7 ppb and a detection limit of 0.4 ppb.
Article
Engineering, Environmental
Yanlin Ma, Zhaoping Deng, Zepeng Li, Quanzhi Lin, Yuhang Wu, Weisha Dou
Summary: This study reported the excellent performance of potassium titanate whiskers in adsorbing heavy metals in wastewater, with a focus on the adsorption kinetics and mechanism for various ions. The whiskers demonstrated good recyclability, maintaining over 70% adsorption capacity after five cycles.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Maria Visa, Alexandru Enesca
Summary: This study developed two zeolite structures by recycling PV glass and coal fly ash for the removal of cadmium, copper, and lead from synthetic solutions. The materials were characterized and the adsorption conditions were optimized for enhanced removal efficiency. The zeolite adsorption equilibrium data were described using Langmuir and Freundlich models, and the highest adsorption capacities were determined. This research highlights the potential of waste recycling in removing toxic heavy metals from wastewater.
Article
Green & Sustainable Science & Technology
Yaoyao Zhang, Kangze Yuan, Luca Magagnin, Xishe Wu, Zhenyi Jiang, Wei Wang
Summary: Mercapto-functionalized aerogels (MA-X) were synthesized using MPTMS to remove Pb(II) and Cu(II) from wastewater. MA2 exhibited high adsorption capacities for Pb(II) and Cu(II), with Cu(II) being more readily adsorbed. The adsorption process followed pseudo-second order and Langmuir models, and the main mechanism was coordination chelation between -SH groups and Pb(II) and Cu(II). Life cycle assessment was conducted to evaluate the environmental impact of MA2 production.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Environmental Sciences
Yuyan Zhao, Hanwen Luan, Binghan Yang, Zhenghe Li, Meitong Song, Bing Li, Xiaodan Tang
Summary: In this study, coal fly ash (CFA) and red mud (RM) were combined to synthesize efficient heavy metal adsorbents, providing a new way of resource recycling. The modified composite materials showed larger specific surface area, superior adsorption capacity, and magnetic characteristics compared to CFA and RM. In both single and ternary systems, the modified composite materials demonstrated higher adsorption capacity for Pb, Cu, and Cd, with the preferential adsorption order of Pb > Cu > Cd.
Article
Engineering, Environmental
Piotr Gutwinski, Grzegorz Cema, Aleksandra Ziembinska-Buczynska, Karolina Wyszynska, Joanna Surmacz-Gorska
Summary: The study found that in anaerobic ammonia oxidation process, zinc is the main metal responsible for inhibition, and removing zinc from incoming sewage can restore the efficiency of the process.
JOURNAL OF WATER PROCESS ENGINEERING
(2021)
Article
Chemistry, Analytical
Sadin Ozdemir, Ersin Kilinc, Omer Acer, Mustafa Soylak
Summary: In this study, E. profundum loaded onto Amberlite XAD-4 resin was used for solid-phase extraction of Cu(II), Ni(II), and Pb(II). Various conditions of the SPE procedure and the effects of interfering ions were discussed. The biosorption capacities of E. profundum for Pb(II), Cu(II), and Ni(II) were determined, with LOD values and linear ranges calculated for each metal. Metal ion concentrations in water and food samples were measured using ICP-OES.
MICROCHEMICAL JOURNAL
(2021)
Article
Environmental Sciences
Qian Li, Limin Wang, Rui Xu, Yongbin Yang, Huaqun Yin, Shengming Jin, Tao Jiang
Summary: Heavy metal pollution is a critical global issue, and bioremediation is considered a promising approach. This study investigated the biosorption characteristics of Cd(II), Pb(II), Cu(II), and Zn(II) from aqueous solutions using three phosphorus-accumulating organisms (PAOs) biomasses. The results showed that the biosorption capacity of the biosorbents to heavy metal ions was affected by the solution pH and increased with higher pH values. The experimental data of biosorption were well fitted with the Pseudo-second-order, Redlich-Peterson, and Temkin models, suggesting a hybrid chemical reaction-biosorption process.
Article
Environmental Sciences
Gang Zhou, Shuailong Li, Chenxi Niu, Qi Wang, Xinyuan Zhang, Qunzhi Meng, Lin Li
Summary: The main sources of heavy metal pollution are industrial wastewater and waste residues, which have serious detrimental effects on water and soil environments as well as human health. In this study, a gel adsorbent (AA-SW-AMPS) was prepared using microwave-assisted chemical cross-linking with fir sawdust as the raw material, following the principle of waste utilization. The microstructure, reaction mechanism, and water absorption performance of AA-SW-AMPS were investigated using SEM, FTIR, XRD, and swelling dynamic experiments. The results showed that AA-SW-AMPS had a porous structure with a specific surface area of 240.75 cm²/g, enabling excellent sorption of heavy metals.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Multidisciplinary Sciences
Li Tian, Kai-bin Fu, Shu Chen, Jun Yao, Liang Bian
Summary: In this research, the adsorption of copper, lead, and zinc ions on kaolinite was investigated through experiments and calculations. The results showed that kaolinite has a strong adsorption capacity for these ions. The adsorption process was characterized using various techniques. This study is important for understanding the adsorption properties of kaolinite and optimizing adsorbent materials for water treatment and soil remediation.
SCIENTIFIC REPORTS
(2022)
Article
Green & Sustainable Science & Technology
Carla Cilliers, Olga Neveling, Shepherd M. Tichapondwa, Evans M. N. Chirwa, Hendrik G. Brink
Summary: This research aimed to improve the scalability and cleaner production of a lead bioremediation process by gaining a better understanding of its dominant mechanisms. The study found that the presence of different lead concentrations and complementary anions had significant effects on the composition and structure of the resulting precipitate.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Materials Science, Multidisciplinary
Asim Jilani, Syed Zajif Hussain, Mohammad Omaish Ansari, Rajeev Kumar, Mohsin Raza Dustgeer, Mohd Hafiz Dzarfan Othman, M. A. Barakat, Ammar A. Melaibari
Summary: The novel ternary nanocomposite Ag-rGO@ZnONR demonstrated excellent photocatalytic performance in the degradation of 2-chlorophenol under solar light irradiation, possibly due to the engineered reduced bandgap and the Schottky barrier at the metal-semiconductor interface facilitating charge separation, as well as the generation of superoxide anions center dot O-2(-) and hydroxyl radicals center dot OH. These interactions, along with pi-pi stacking with the aromatic ring of 2-CP, contributed to the 100% degradation efficiency.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Engineering, Chemical
M. A. Barakat, Rajeev Kumar, Eder C. Lima, Moaaz K. Seliem
Summary: The discharge of organic pollutants, including dyes, into aquatic systems is a major source of environmental contamination. The use of Fe3O4@MUS composite for dye adsorption and Fenton-like degradation has shown effective purification of contaminated water bodies. Experimental results demonstrated high adsorption and removal efficiency of Fe3O4@MUS for methyl orange, along with its good stability for repeated use.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2021)
Article
Green & Sustainable Science & Technology
M. A. Barakat, Rajeev Kumar, Talal Almeelbi, Bandar A. Al-Mur, Jamiu O. Eniola
Summary: In this study, a WO3/WS2/PANI nanohybrid photocatalyst was fabricated for the decomposition of 2-CP in water. The photocatalytic degradation of 2-CP was found to be dependent on irradiation time, pH, and 2-CP concentration. The WO3/WS2/PANI catalyst exhibited excellent catalytic activity and reusability, offering a sustainable technology for water remediation.
JOURNAL OF CLEANER PRODUCTION
(2022)
Review
Green & Sustainable Science & Technology
Jamiu O. Eniola, Rajeev Kumar, M. A. Barakat, Jamshaid Rashid
Summary: The review highlights the need for innovative approaches to tackle pharmaceutical pollutants in drinking water and wastewater. Conventional treatment methods are limited in their efficiency for removing pharmaceutical pollutants, necessitating the development of new and advanced treatment technologies. Hybrid technology and membrane bioreactors show promise in enhancing the removal efficacy of pharmaceutical pollutants. Future research should focus on the integration of multiple technologies to achieve better removal of pharmaceuticals.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Environmental Sciences
Mohamed A. Barakat, Rajeev Kumar, Riyadh F. Halawani, Bandar A. Al-Mur, Moaaz K. Seliem
Summary: This study developed a composite material using magnetite nanoparticles synthesized from altered basalt, H2O2-activated bentonite, and fibrous sawdust for the removal of methylene blue. The characterization and analysis of the composite revealed its effective adsorption capacity and stability. The study also provided insights into the adsorption mechanism at both the molecular scale and energetic level.
Article
Chemistry, Multidisciplinary
Misfer Al Hawash, Rajeev Kumar, Mohamed A. Barakat
Summary: In this study, polyaniline and graphene oxide nanosheet immobilized granular tea waste (PANI/GO@GTW) were synthesized for the removal of anionic and cationic contaminants from groundwater. The results showed that PANI/GO@GTW exhibited high adsorption capacity and efficient removal of bromide ions.
Review
Biochemistry & Molecular Biology
Muzammil Anjum, Mobeena Anees, Samia Qadeer, Azeem Khalid, Rajeev Kumar, Mohamed. A. Barakat
Summary: Landfill leachate (LFL) treatment is challenging due to its complex pollutants, but anaerobic digestion with pretreatment methods shows promise in producing renewable energy and valuable chemicals from leachate. Various pretreatment techniques, such as electrochemical, ultrasonic, alkaline, coagulation, nanofiltration, air stripping, adsorption, and photocatalysis, are summarized in this review. The incorporation of pretreatment and anaerobic digestion offers a high economic viability through bioenergy production and cost savings in sustainable leachate management.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Physical
Rajeev Kumar, Mohammad Omaish Ansari, Md Abu Taleb, Mohammad Oves, Mohamed A. Barakat, Mansour A. Alghamdi, Naief H. Al Makishah
Summary: In this study, an integrated adsorption-photocatalysis process was used to effectively remove oxytetracycline from aqueous solution by fabricating an adsorbent-photocatalyst integrated material. The results demonstrated that the combination of adsorption and photocatalysis can significantly improve the removal efficiency, and the material showed sustained efficacy even after multiple cycles of use.
Article
Chemistry, Physical
Rajeev Kumar, Md. Abu Taleb, Mohamed A. Barakat, Bandar Al-Mur
Summary: This article reports a facile fabrication of tungsten oxide (WO3)/bismuth oxychloride (BiOCl) immobilized on polyaniline (PAn) (BiOCl/WO3@PAn) heterojunction nanocomposite photocatalyst. The synthesized BiOCl/WO3@PAn nanocomposite showed higher visible light absorption behavior and bandgap energy reduction than the WO3 and BiOCl. The study is important as it presents an advanced photocatalyst that can utilize solar energy for water purification applications.
Article
Multidisciplinary Sciences
M. A. Barakat, Abd-Allah Hyder, Areej A. Almoneef
Summary: This article presents a new mathematical fractional model for examining HIV transmission. The model is built using recently developed fractional differential and integral operators. The existence and uniqueness of the model are investigated using Leray-Schauder nonlinear alternative and Banach's fixed point theorems. Additionally, various types of Ulam stability are established for the fractional HIV model. It is evident that the obtained findings can be reduced to many previous results in the literature.
SCIENTIFIC REPORTS
(2023)
Correction
Environmental Sciences
Mohamed A. A. Barakat, Rajeev Kumar, Riyadh F. F. Halawani, Bandar A. A. Al-Mur, Moaaz K. K. Seliem
Article
Chemistry, Multidisciplinary
Ahmed N. N. Doyo, Rajeev Kumar, Mohamed A. A. Barakat
Summary: A facile one-step in situ oxidative polymerization synthesis method was used to fabricate polyaniline@waste cellulosic nanocomposite adsorbent to remove copper(II) and phenol from aqueous solution. The structural and surface properties of the synthesized material were examined and the adsorption behavior of Cu(II) and phenol onto the material was investigated. The PANI@WTP adsorbent showed high adsorption capacity for Cu(II) and phenol, and the efficiency remained excellent even after multiple cycles of regeneration.
Article
Energy & Fuels
Jamshaid Rashid, Talha Tufail Bhatti, Muhammad Hassan, M. A. Barakat, Rajeev Kumar, Ming Xu
Summary: Production of biogas from crop wastes via the biological route is a promising technology for sustainable development. A study investigated the use of photocatalytic pretreatment to enhance the anaerobic process efficiency. Rice husk was pretreated using Indium Vanadate decorated Titania nanocomposite, leading to higher biodegradability and biogas production. The results showed that photocatalytic pretreatment significantly increased the cumulative biogas production compared to raw or untreated rice husk.
Review
Engineering, Chemical
Ahmed N. Doyo, Rajeev Kumar, M. A. Barakat
Summary: This review discusses the applications of modified biopolymers for decontaminating heavy metals in wastewater. It highlights the preparation, alteration, and applications of chemically modified or synthesized composites based on chitosan, cellulose, and alginate biopolymers. The review also presents the adsorption behavior of heavy metals onto modified biopolymeric adsorbents and suggests potential future research directions.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Biochemistry & Molecular Biology
Md. Abu Taleb, Rajeev Kumar, M. A. Barakat
Summary: In this study, a multifunctional thin film was synthesized and utilized for the adsorptive scavenging of antibiotics and metal ions from contaminated wastewater. The results showed that the hybrid thin film had higher adsorption capacity and could be reused multiple times.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)