期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 787, 期 -, 页码 110-117出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2017.01.051
关键词
Poly(3,4-ethylenedioxythiophene); Au; Nanosphere; Dopamine; Uric acid
资金
- National Natural Science Foundation of China [21564014]
Poly(3,4-ethylenedioxythiophene)/Gold (PEDOT/Au) hollow nanospheres with the ratio of EDOT and HAuCl4 from 2:1 to 1:2 were synthesized by in-situ polymerization method. The synergism between the PEDOT and Au explored for detection of Dopamine (DA) and Uric acid (UA) in neutral phosphate buffer solutions (PBS 7.0). It was found that the monodispersed PEDOT and PEDOT/Au hollow nanospheres had been successfully prepared. Electrochemical experiments showed that the PEDOT/Au(1:1) modified electrode revealed excellent electrocatalytic activity with faster electron charge transfer kinetics. The results from differential pulse voltammetry (DPV) experiments revealed that the PEDOT/Au(1:1) electrode has excellent linear response with 0.15 mu mu-330 mu M and 1.5 mu M-150 mu M for the determination of DA and UA, respectively. The detection limits(S/N = 3) were found to be 0.07 mu M and 0.08 mu M for determination of DA and UA, respectively. The PEDOT/Au(1:1) modified electrode also had good reproducibility, repeatability and excellent stability. (C) 2017 Elsevier B.V. All rights reserved.
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