期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 788, 期 -, 页码 137-143出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2017.02.010
关键词
Thin film; Photoelectrochemical cell; Cadmium selenide; Electrochemical impedance spectroscopy; Indium doping; Band diagram
Present investigation describes the photoelectrochemical studies of electrosynthesized CdSe and indium doped CdSe (In:CdSe) thin films deposited on stainless steel (SS) substrates. The photoelectrochemical (PEC) studies of both films are carried out with CdSe and In:CdSe(SS)/1 M Polysulfide/C cell. It is observed that indium doping in CdSe enhances the fill factor from 0.56 to 0.63 and photo-conversion efficiency from 0.80% to 2.01%. In order to study the consequence of doping, undoped and indium doped CdSe thin films are further characterized by capacitance-voltage, electrochemical impedance spectroscopy (EIS), spectral response, transient responsb, speed of response characterization techniques. By using capacitance-voltage measurement, various physical parameters are estimated and accordingly energy band diagrams have been constructed. (C) 2017 Elsevier B.V. All rights reserved.
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