期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 490, 期 -, 页码 59-63出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2016.11.040
关键词
Adsorption; D-A equation; Isosteric heat of adsorption; Adsorbed phase volume
Accurate estimation of the isosteric heat of adsorption is mandatory for a good modeling of adsorption processes. In this paper a thermodynamic formalism on adsorbed phase volume which is a function of adsorption pressure and temperature has been proposed for the precise estimation of the isosteric heat of adsorption. The estimated isosteric heat of adsorption using the new correlation has been compared with measured values of prudently selected several adsorbent-refrigerant pairs from open literature. Results showed that the proposed isosteric heat of adsorption correlation fits the experimentally measured values better than the Clausius-Clapeyron equation. (C) 2016 Elsevier Inc. All rights reserved.
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