Article
Engineering, Chemical
Zhijia Zhu, Chenmiao Zhu, Ruiying Yang, Lingfeng Yan, Chunyan Hu, Baojiang Liu
Summary: The study successfully prepared Bi5O7I/BiOIO3 composite materials with excellent degradation efficiency and stability in photocatalysis. Through investigation of electron migration and photocatalytic mechanism, it elucidated the active species and heterojunction structure contributing to the improved photocatalytic activity.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Environmental Sciences
Jialun Huang, Jingtao Shen, Ganwei Zhang, Yongfu Guo, Xinyu Zheng
Summary: A 3D microsphere of Bi5O7I/BiOCl heterojunction catalyst was synthetised in this study, significantly enhancing the transfer rate and separation efficiency of carriers through synergy, and heightening light absorption capacity.
Article
Environmental Sciences
Zhanwei Qiao, Weiqun Chu, Hao Zhou, Cheng Peng, Zhenzhen Guan, Jiang Wu, Sorachon Yoriya, Ping He, Hai Zhang, Yongfeng Qi
Summary: In this study, an S-doped g-C3N4/Bi5O7I heterojunction was designed to enhance the absorption of visible light and the separation efficiency of photogenerated carriers, leading to improved photocatalytic reaction rates. This work provides a promising strategy for the development of non-metal doping combined with heterojunction photocatalytic systems.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Engineering, Environmental
Yiqiong Yang, Wenqing Ji, Xingyu Li, Zenghui Zheng, Fukun Bi, Minhui Yang, Jingcheng Xu, Xiaodong Zhang
Summary: The Bi5O2I/ZnO n-n heterojunction microspheres showed excellent photocatalytic performance in degrading PFOA, with photoproduction holes attacking the carboxylic groups of PFOA and transforming it into shorter chain perfluorocarboxylic acids. This photocatalyst has the potential to be an effective treatment for PFOA contamination.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Qi Li, Yi -lei Li, Bo Li, Ying-juan Hao, Xiao-jing Wang, Rui-hong Liu, Yuan Ling, Xinying Liu, Fa-tang Li
Summary: This study investigated the role of the main {314} facet of Bi5O7I, finding that increasing the {008} facet proportion did not effectively improve its activity, while controllable oxygen vacancy concentration could be achieved by constructing a reduction atmosphere. The results showed that the synergistic effect of facet ratio and oxygen vacancies led to an enhancement in charge carrier performance.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Biochemistry & Molecular Biology
Zhanqiang Ma, Wei Guo, Kaiyue Zhang, Nan Wang, Ziyue Li, Juan Li
Summary: In this paper, a novel S-scheme CuS/Bi5O7I heterojunction with increased visible light harvesting and high-efficiency separation of photogenerated electrons and holes was successfully constructed using a two-step approach. The 3%-CuS/Bi5O7I composite demonstrated the best antibacterial activity, completely inactivating E. coli in 180 minutes of visible light irradiation. The bacterial inactivation process involved the protection system initiated by SOD and CAT, followed by cell membrane destruction and leakage of intracellular components resulting in the death of E. coli.
Article
Nanoscience & Nanotechnology
Haonan Zhang, Xin Zhang, Zhaoze Zhang, Xiaoming Ma, Yuanna Zhu, Miaojuan Ren, Yongqiang Cao, Ping Yang
Summary: Ultrahigh charge separation and transfer characteristics were achieved in Bi4O5I2/Bi5O7I 2D/1D hierarchical structures by growing 2D nanoplates on the electron-accumulating facet of 1D nanobelts. The synergistic effect of two types of heterojunctions in the hierarchical structures significantly enhanced charge transfer and photocatalytic performance compared to control samples. This study provides a new strategy for the exploration of highly active heterostructure nanomaterials in various applications.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Meina Huang, Ju Li, Yongcheng Huang, Xuan Zhou, Zuzeng Qin, Zhangfa Tong, Minguang Fan, Bin Li, Lihui Dong
Summary: Designing and synthesizing g-C3N4@TiO2-SnO2 nanocomposites can lead to highly efficient photocatalysts for pollutant removal and H-2 evolution. The improved photoactivity of the composite is mainly attributed to enhanced electron-hole separation and apt modulation of thermodynamic properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Chemical
Rong Yan, Hao Huang, Shuo Chu, Wen-Feng Jiang
Summary: Novel Bi6O5(OH)3(NO3)5·3H2O/Bi5O7I (BBN/BOI) Z-scheme binary heterojunction composites were successfully prepared via a facile in-situ growth method, exhibiting enhanced photocatalytic performance for degrading organic pollutants.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Physical
Zaid H. Jabbar, Bassim H. Graimed, Ayah A. Okab, Maye M. Alsunbuli, Rasha A. Al-husseiny
Summary: Promoting the separation activity of photo-induced carriers via the design of heterostructure photocatalysts remains a vital challenge. In this study, a multistep strategy was developed to construct a Bi5O7I/Bi/Bi2WO6/NiFe2O4 heterojunction using in situ growth of Bi/Bi2WO6 and NiFe2O4 species on the surface of Bi5O7I microspheres, leading to a superior photodegradation activity of levofloxacin.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Cailian Xia, Ruixin Lu, Qiaofeng Han
Summary: Bismuth-rich oxyiodides with a layered structure and tunable band potentials have great potential as photocatalysts. This study successfully prepared Bi4O5I2/Bi5O7I heterojunction photocatalysts with enhanced photocatalytic performance using thiourea as an additive. The addition of thiourea not only reduced the pH value, promoting the formation of the heterojunction, but also improved the photocatalytic activity. The as-prepared Bi4O5I2/Bi5O7I (pH 6) heterojunction exhibited superior photocatalytic activity for the degradation of organic dyes and antibiotics.
Article
Engineering, Environmental
Jinhai Li, Chenyu Wang, Jianhai Zhou, Zhang Ping, Guopei Huang, Yuanhui Wu, Shuxing Luo, Dongmei Bao, Zhu Wen, Pili Lu
Summary: In this study, a novel Bi2O2(OH)NO3-BiVO4 heterogeneous composite was successfully constructed and synthesized by a mild and convenient hydrothermal method. The as-synthesized composite exhibited good surface properties and catalytic stability, and significantly enhanced the photocatalytic degradation capacity.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Polymer Science
Ruibo Guo, Liming Bai, Guohua Dong, Dongfeng Chai, Kun Lang, Zhonghua Mou, Ming Zhao
Summary: Rational design of nano-heterojunction catalysts, such as ZnO/AgSiW and ZnO/CsPW, can effectively solve dye pollution. This study synthesized and characterized these two catalysts, and conducted photocatalytic experiments and electrochemical tests. The results showed that the degradation rates of Rhodamine B by these catalysts were significantly higher than that by pure zinc oxide, and they maintained excellent performance after repeated use. The active substances and photocatalytic degradation pathways were determined through free radical capture experiments and liquid chromatography/mass spectrometry analysis.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2022)
Article
Chemistry, Applied
Xuemei Jia, Zichen Shen, Qiaofeng Han, Huiping Bi
Summary: A Bi4O5I2/Bi4O5Br2 heterojunction with rich oxygen vacancies was successfully synthesized through a simple method, and it exhibited excellent photocatalytic performance in the degradation of antibiotics and dyes under visible light.
CHINESE JOURNAL OF CATALYSIS
(2022)
Article
Nanoscience & Nanotechnology
Yu Zhu, Chuwen Li, Dongmei Hou, Guicheng Gao, Weiqi Luo, Zhengzhou Duan, Tang Zhang, Qinyun Xv, Yujia Wang, Jijun Tang
Summary: In this paper, a high-performance BiFeO3@Bi5O7I composite material is synthesized, which forms an n-n heterojunction improving charge transfer efficiency and promoting enhanced photocatalytic efficiency and stability.
Review
Chemistry, Multidisciplinary
Shuchen Tu, Yuxi Guo, Yihe Zhang, Cheng Hu, Tierui Zhang, Tionyi Ma, Hongwei Huang
ADVANCED FUNCTIONAL MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Liqi Bai, Hongwei Huang, Songge Zhang, Lin Hao, Zhili Zhang, Hongfen Li, Li Sun, Lina Guo, Haitao Huang, Yihe Zhang
Review
Energy & Fuels
Lizhen Liu, Yihe Zhang, Hongwei Huang
Summary: Artificial photosynthesis of clean fuels has potential for solving the energy crisis and environmental pollution, and junction engineering plays a key role in enhancing the efficiency, selectivity, and stability of solar-driven CO2 reduction.
Article
Chemistry, Physical
Chao Zeng, Qing Zeng, Chunhui Dai, Likai Zhang, Yingmo Hu
Summary: The carbon-modified MgIn2S4 photocatalysts showed significantly enhanced catalytic activity for converting inert CO2 into chemical fuel, with the carbon-coating and doping strategy exhibiting the best performance in increasing CO evolution rate. The synergistic effect of surface coated and bulk doped carbon could maximize the photocatalysis efficiency.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Wenhong Yang, Yujing Dong, Zhipeng Wang, Yuqin Li, Chunhui Dai, Dongwei Ma, Yu Jia, Zhen Yang, Chao Zeng
Summary: The Sn2+ doped MgIn2S4 photocatalysts show significantly enhanced photocatalytic CO2 reduction activity compared to pristine MgIn2S4, with the highest yield achieved at a specific doping level. The theoretical results indicate that Sn doping alters the band structure, reduces band gap, extends light absorption range, and promotes migration of photoinduced carriers, while the experimental results demonstrate the positive role of Sn dopant in enhancing charge separation and transportation, as well as improving CO2 adsorption ability.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Chemical
Chao Zeng, Haojia Ding, Linping Bao, Yujing Su, Zhipeng Wang
Summary: The study successfully developed highly efficient AgIO3@X heterojunction photocatalysts via a simple in situ reduction method, showing great photocatalytic activity under visible light and efficient degradation of toxic organic pollutants in wastewater.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Chemistry, Inorganic & Nuclear
Linping Bao, Yujing Dong, Chunhui Dai, Guodong Xu, Yong Yang, Xin Liu, Dongwei Ma, Yu Jia, Chao Zeng
Summary: The study demonstrates that surface Co-doping significantly enhances the activity and electronic structure of ZnS photocatalysts, improving the efficiency of hydrogen evolution and facilitating carrier migration.
INORGANIC CHEMISTRY
(2021)
Article
Environmental Sciences
Haojia Ding, Linping Bao, Yao Su, Yuqin Li, Guodong Xu, Chunhui Dai, Chao Zeng
Summary: A core-shell structured Ag2S-AgIO3 Z-scheme heterostructure photocatalyst has been designed and developed, extending the UV absorption of AgIO3 to the Vis-NIR region and enhancing the photocatalytic activity. The composite catalyst shows effective MO degradation under natural sunlight.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2022)
Article
Environmental Sciences
Yujing Su, Yujing Dong, Linping Bao, Chunhui Dai, Xin Liu, Chengyin Liu, Dongwei Ma, Yushuai Jia, Yu Jia, Chao Zeng
Summary: In this study, Ag clusters supported on In2O3 plasmonic photocatalysts were synthesized, showing remarkably enhanced photocatalytic activity for CO2 conversion to CO. Ag clusters act as electron donors to In2O3, accelerating the photocatalytic reaction and promoting visible-light absorption, resulting in the activity enhancement of Ag-In2O3 compounds.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2022)
Article
Chemistry, Multidisciplinary
Yao Su, Haojia Ding, Miaofei Sun, Xin Liu, Chunhui Dai, Yuqin Li, Guodong Xu, Chao Zeng
Summary: Efficient removal of persistent organic pollutants (POPs) in natural waters is crucial for human survival and sustainable development. In this study, a direct Z-scheme BiOIO3/AgIO3 hybrid photocatalyst was developed, and it showed high photoactivity for the degradation of various pollutants. The Bi@Ag-5 photocatalyst exhibited significantly higher efficiency compared to TiO2 (P25) in the treatment of mixed pollutant solutions under natural sunlight irradiation.
Article
Chemistry, Multidisciplinary
Wei Wu, Chunyuan Feng, Mantao Chen, Qin Tan, Yue Deng, Chao Zeng, Lixiang Zhong, Chunhui Dai
Summary: In this study, two new benzimidazole-linked conjugated microporous polymers were synthesized and one of them showed excellent selectivity and high productivity in the photocatalytic reduction of low-content CO2.
Article
Polymer Science
Wei Wu, Mantao Chen, Yue Deng, Qin Tan, Zucheng Dong, Junyu Wang, Chao Zeng, Chunhui Dai
Summary: Porous organic polymers with nanotube structures were prepared and studied as photocatalysts for CO2 conversion. The unique nanotube structure provides a larger surface area for active site exposure and CO2 adsorption. By replacing specific units, the photocatalytic performance was further enhanced. The nanotube catalysts showed higher CO formation rates.
Article
Chemistry, Multidisciplinary
Linping Bao, Xiaohui Ren, Chengyin Liu, Xin Liu, Chunhui Dai, Yong Yang, Mohamed Bououdina, Sajjad Ali, Chao Zeng
Summary: Transition metal ion surface doping greatly enhances the activity of ZnS catalysts for H2 evolution and CO2 reduction, with the doping state playing a crucial role in affecting their photo-absorption and reaction kinetics. This research provides insights for the future design and fabrication of high-performance photocatalysts.
CHEMICAL COMMUNICATIONS
(2023)
Article
Construction & Building Technology
Xinke Wang, Na Zhang, Yihe Zhang, Jingang Liu, Chengshan Wang, Paul K. Chu
CONSTRUCTION AND BUILDING MATERIALS
(2020)
Article
Chemistry, Inorganic & Nuclear
Chao Zeng, Qing Zeng, Chunhui Dai, Yingmo Hu
DALTON TRANSACTIONS
(2020)
Article
Chemistry, Physical
Panpan Zhang, Xu Wang, Yangyang Yang, Haifeng Yang, Chunsheng Lu, Mingru Su, Yu Zhou, Aichun Dou, Xiaowei Li, Xiaochuan Hou, Yunjian Liu
Summary: In this study, the influence of transition metal doping on the electronic and mechanical properties and electrochemical performance of 2HMoS2/NC was investigated using Cobalt (Co) as an example. Co doping was found to effectively improve the electronic conductivity and active site areas of 2H-MoS2/NC at different positions, optimizing the adsorption and diffusion capability of potassium ions. Furthermore, the study revealed the optimal roles of different types of nitrogen atoms in kinetic adsorption, diffusion, and interfacial stability of potassium ions. These findings provide guidance for the experimental design of high rate 2H-MoS2/NC electrode materials and the optimal design of other functional composite materials.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zeeshan Ajmal, Mahmood Ul Haq, Shahid Zaman, M. K. Al-Muhanna, Anuj Kumar, Mohammed M. Fadhali, Siwar Ben Hadj Hassine, Muhammas Qasim, K. F. Alshammari, Ghulam Abbas Ashraf, Abdul Qadeer, Adil Murtaza, Sulaiman Al-Sulaimi, Huaqiang Zeng
Summary: This study presents a novel heterojunction structure (SrTiO3/CN-TAL10.0) for enhanced photocatalytic water splitting (PWS). The incorporation of thiophenedicarboxaldehyde (TAL) through copolymerization significantly improves the photocatalytic activity of carbon nitride (CN) while maintaining its photostability performance. The optimized composition allows efficient isolation of photoinduced charge carriers and enhanced charge transport, resulting in a remarkable increase in overall photocatalytic efficiency.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Angela Arnosa-Prieto, Patricia Diaz-Rodriguez, Manuel A. Gonzalez-Gomez, Pelayo Garcia-Acevedo, Lisandra de Castro-Alves, Yolanda Pineiro, Jose Rivas
Summary: Macrophages can exhibit different phenotypes depending on the microenvironment and the characteristics of magnetic iron oxide nanoparticles (MNPs). This study demonstrates that the concentration and morphology of MNPs can influence the polarization of macrophages. The findings have implications for therapeutics targeting tissue regeneration and tumor progression.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yu Fang, Cheng-Ye Zhu, Hao-Cheng Yang, Chao Zhang, Zhi-Kang Xu
Summary: This study demonstrates the advantages of vacuum-assisted interfacial polymerization (VAIP) in fabricating polyimide nanofiltration membranes. By using vacuum filtration, aqueous solutions of PIP can be evenly distributed on different microfiltration substrates, leading to the fabrication of uniform and ultra-thin polyamide layers with excellent performance. The membranes exhibit high rejection rates and water permeance, as well as satisfactory long-term stability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Isaac J. Gresham, Edwin C. Johnson, Hayden Robertson, Joshua D. Willott, Grant B. Webber, Erica J. Wanless, Andrew R. J. Nelson, Stuart W. Prescott
Summary: Understanding the interactions between polymers and surfactants is crucial for optimizing commercial systems. This study tested the behavior of polymer-surfactant systems, revealing that they do not behave like polyelectrolytes in the presence of salt. Additionally, the structure of polymer-surfactant complexes under confinement differs from that of polyelectrolytes.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yunxiao Xie, Cui Liu, Jie Zhang, Yan Li, Bin Li, Shilin Liu
Summary: This study aimed to improve the microstructure and rheological properties of W/W Pickering emulsions by crosslinking sodium alginate at the water-water interface, thereby enhancing the activity of encapsulated probiotics in simulated gastrointestinal digestion.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Sang Ho Lee, Yige Sun, Patrick S. Grant
Summary: This research developed an effective approach to enhance the charging rates of lithium ion batteries (LIBs) by strategically incorporating carbon nanotube (CNT) conductivity boosters into Li4Ti5O12 (LTO) electrodes. Multi-layer architectures comprising CNT-rich and CNT-free LTO electrode layers were manufactured using a layer-by-layer spray coating method to promote charge transfer kinetics of high mass loading electrodes. The best performing multi-layer was paired with a spray-coated LiFePO4 (LFP) positive electrode, resulting in attractive power performance that outperformed conventional LTO || LFP combinations.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jingwei Liang, Shaobin Li, Fengbo Li, Li Zhang, Yufeng Jiang, Huiyuan Ma, Kun Cheng, Liang Qing
Summary: A molybdenum-regulated self-supporting electrode material with rich vacancy defects has been successfully synthesized and shows exceptional catalytic activities and stability for electrocatalytic overall water splitting. This study provides a new perspective for the design and synthesis of non-precious metal bifunctional electrocatalysts.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jonas Blahnik, Jennifer Schuster, Rainer Mueller, Eva Mueller, Werner Kunz
Summary: This study investigates the relationship between the morphology of PMMA monopolymers and PMMA-PHEMA copolymers with the expected nature of surfactant-free microemulsions (SFMEs) before polymerization. It is found that previously mesostructured, surfactant-free mixtures can produce porous polymers of different morphologies, while unstructured, oil-rich regions lead to solid, transparent polymers without nanostructured morphologies. Additionally, a surfactant-based reference system shows similar phase behavior and polymer morphologies as the comparable surfactant-free system, indicating the importance of the hydrotropic behavior of HEMA in this system.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zheng-Fen Pu, Wen-Zhi She, Rong Sheng Li, Qiu-Lin Wen, Bi-Chao Wu, Chun-Hua Li, Jian Ling, Qiue Cao
Summary: This study synthesized two framework-isomeric covalent organic frameworks (COFs) and discovered that the light scattering signal of COFs can be used for the analytical detection of lead ions. By controlling synthesis conditions and introducing regulators, the morphology of COFs could be controlled and framework-isomeric COFs could be precisely synthesized.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yuchen Weng, Ying Hong, Jingyu Deng, Sicheng Cao, Li-Juan Fan
Summary: This paper reports the preparation of dynamic color-changing fluorescent polymer nanoparticles (PNPs) by constructing a fluorescence resonance energy transfer (FRET) pair. The PNPs show excellent anti-counterfeiting effects and reproducibility. The study demonstrates a promising encryption strategy that can achieve multiple outputs with simple operation.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Guodong Liu, Zijian Wang, Jianing Wang, Hanbin Liu, Zhijian Li
Summary: This study investigates the combination of multicolor switchable polyaniline (PANI) electrode and 1-methyl-4,4'-bipyridyl iodide (MBI), which demonstrates superior optical properties in visible and near-infrared light modulation, as well as excellent electrochemical performances. This combination can be used to develop novel electrochromic devices for applications in smart packaging, smart labels, and flexible smart windows.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Huying Yan, Yang Guo, Xingzhi Bai, Jiawei Qi, Haipeng Lu
Summary: By modifying Ti3C2Tx through heterogeneous interface engineering, optimized impedance matching is achieved, leading to enhanced electromagnetic wave absorption performance.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Kehu Zhang, Yang Zhou, Silvia Moreno, Simona Schwarz, Susanne Boye, Brigitte Voit, Dietmar Appelhans
Summary: This article presents an advanced crosslinking strategy to fabricate clustered polymersomes using host-guest interactions. By controlling the input of crosslinker and environmental conditions, reversible aggregation and disassembly of these polymersomes can be achieved. The size and structure of these clustered polymersomes can be regulated and visualized through a fluorescent enzymatic cascade reaction.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Junjie Xu, Weixiong Huang, Ruiling Li, Li Li, Jinjin Ma, Jiaou Qi, Haiyan Ma, Min Ruan, Lilin Lu
Summary: In this study, a potassium doped palladium catalyst was developed for acetylene hydrogenation, showing excellent catalytic performance and durability. The doping of potassium effectively weakened the adsorption of ethylene, improved ethylene selectivity, and lowered the barriers of hydrogen activation and transfer reactions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)