4.7 Article

Laser controlled charge-transfer reaction at low temperatures

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JOURNAL OF CHEMICAL PHYSICS
卷 146, 期 8, 页码 -

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AMER INST PHYSICS
DOI: 10.1063/1.4976972

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  1. Grants of the ARO-MURI [W911NF-14-1-0378, W911NF-12-1-0476]
  2. NSF [PHY-1619788]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Physics [1619788] Funding Source: National Science Foundation

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We study the low-temperature charge transfer reaction between a neutral atom and an ion under the influence of near-resonant laser light. By setting up a multi-channel model with field-dressed states, we demonstrate that the reaction rate coefficient can be enhanced by several orders of magnitude with laser intensities of 106 W/cm(2) or larger. In addition, depending on laser frequency, one can induce a significant enhancement or suppression of the charge-exchange rate coefficient. For our intensities, multi-photon processes are not important. Published by AIP Publishing.

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