Review
Chemistry, Inorganic & Nuclear
Antal Udvardy, Ferenc Joo, Agnes Katho
Summary: The compound 1,3,5-Triaza-7-phosphaadamantane (pta, phosphaurotropine) has played a crucial role in the development of aqueous organometallic chemistry and catalysis due to its easy synthesis, oxidation stability, versatile functionalization possibilities, and high solubility in both water and common organic solvents. It has been used to synthesize transition metal complexes and has been employed as catalysts in various important aqueous-phase processes, contributing significantly to the advancement of green chemical processes.
COORDINATION CHEMISTRY REVIEWS
(2021)
Article
Chemistry, Physical
Wei Jiang, Jing-Pei Cao, Chen Zhu, Ming Zhao, Zhong-Hai Ni, Xiao-Yan Zhao, Jin-Xuan Xie, Liang Zhao, Yun-Peng Zhao, Hong-Cun Bai
Summary: This study investigates Ru-based catalysts for the selective hydrogenation of lignin-derived aromatic compounds and finds that Ru/alpha-Al2O3 catalyst exhibits excellent recyclability, air stability, and the highest activity. The mechanism of selective hydrogenation is revealed by experimental and theoretical calculations.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Inorganic & Nuclear
Pragti, Sreshtha Nayek, Satyam Singh, Avinash Sonawane, Ivo Grabchev, Rakesh Ganguly, Suman Mukhopadhyay
Summary: In this study, three Ru(II) arene complexes with a bidentate benzimidazole-based ligand were synthesized and their antitumor activity was studied by varying the co-ligand X. The synthesized compounds showed good interactions with serum albumin proteins, had good drug stability and lipophilic character. They were found to bind with DNA and could induce apoptosis in cancer cells, as well as upregulate cleaved caspase-3 expression and downregulate BCLXL expression. These findings provide a new direction for the investigation of antitumor ruthenium-based metallodrugs using benzimidazole-based ligands.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Feng Chen, Isolda Romero-Canelon, Abraha Habtemariam, Ji-Inn Song, Samya Banerjee, Guy J. Clarkson, Lijiang Song, Ivan Prokes, Peter J. Sadler
Summary: We synthesized a series of novel substituted sulfonyl ethylenediamine (en) Ru-II arene complexes, which showed antiproliferative activity against cancer cells and exhibited catalytic activity in transfer hydrogenation reactions and reactions with thiols.
DALTON TRANSACTIONS
(2022)
Article
Biochemistry & Molecular Biology
Jakob Kljun, Mihaela Rebernik, Lucia M. Balsa, Jerneja Kladnik, Uros Rapus, Tomaz Trobec, Kristina Sepcic, Robert Frangez, Ignacio E. Leon, Iztok Turel
Summary: Organoruthenium pyrithione complexes, such as [(eta(6)-p-cymene)Ru(pyrithionato)(pta)]PF6, show promise as a new class of anticancer drugs. Our study focuses on finding alternatives to the pta ligand and discovering new structural elements to improve the biological properties of ruthenium anticancer drugs. By replacing the pta ligand with different phosphine, phosphite, and arsine ligands, we identified improved inhibitory potency against the enzyme glutathione S-transferase, as well as investigated cytotoxicity in breast, bone, and colon cancers.
Article
Chemistry, Inorganic & Nuclear
Dmitri Gelman, Ilya Kisets, Sofiya Zabelinskaya
Summary: The synthesis and catalytic studies of a prototypical coordinatively rigid carbometalated half-sandwich Ru(II) complex with a rigid polyaromatic tether were described. Despite its coordinatively and electronically saturated nature, the complex demonstrated the ability to activate and transfer hydrogen to polar and nonpolar double bonds. The catalytic activity was benchmarked in the Ru-catalyzed chemoselective hydrogenation of alpha,beta-unsaturated ketones, with initial mechanistic studies suggesting an inner-sphere mechanism via dihydride intermediates.
Article
Chemistry, Multidisciplinary
George S. Biggs, Oskar James Klein, Sarah L. Maslen, J. Mark Skehel, Trevor J. Rutherford, Stefan M. V. Freund, Florian Hollfelder, Sally R. Boss, Paul D. Barker
Summary: The study focuses on generating artificial metalloenzymes through ligand exchange, with a fast and robust procedure developed using Ru-II(eta(6)-arene)(bipyridine) complexes. By successfully introducing metal cofactors into proteins to generate catalysts, the research demonstrates a significant increase in catalytic activity.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Applied
Lilia Longo, Somayeh Taghavi, Margherita Riello, Elena Ghedini, Federica Menegazzo, Alessandro Di Michele, Giuseppe Cruciani, Michela Signoretto
Summary: The optimization of innovative and sustainable catalysts using Pd supported on activated biochars was conducted in this study. Four different waste biomasses from vegetal and animal origin were pyrolyzed and physically activated, and a commercial activated carbon was used as the reference support. The catalysts were impregnated with 0.6 wt% Pd and characterized and tested for benzaldehyde hydrogenation. Results showed that Pd/A-RH and Pd/A-HS exhibited the highest activity (benzaldehyde conversion of 99%) and selectivity towards toluene (97% and 78%), respectively. Characterizations confirmed that the physicochemical properties of the activated biochars, influenced by the origin of initial biomasses, significantly affected the final efficiency of the catalysts.
Review
Chemistry, Multidisciplinary
Lukas Lueckemeier, Marco Pierau, Frank Glorius
Summary: This review aims to present the state-of-the-art in transition-metal catalysed asymmetric hydrogenation of (hetero)arenes, highlighting recent advances and important trends, and providing a broad overview for the reader.
CHEMICAL SOCIETY REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Srividya Swaminathan, Jebiti Haribabu, Naveen Kumar Kalagatur, Maroli Nikhil, Nithya Balakrishnan, Nattamai S. P. Bhuvanesh, Krishna Kadirvelu, Ponmalai Kolandaivel, Ramasamy Karvembu
Summary: The synthesis of fourteen new Ru-II-arene complexes were characterized and found to exhibit high toxicity towards IMR-32 cancer cells, with two complexes showing the highest activity and the ability to induce apoptosis and cell cycle arrest. These complexes also demonstrated good binding affinity with receptors commonly overexpressed in cancer cells.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Qi-Yuan Yang, Rui Ma, Yun-Qiong Gu, Xiao-Fang Xu, Zhen-Feng Chen, Hong Liang
Summary: Targeting metabolic reprogramming to treat cancer, by using arene-ruthenium(II)/osmium(II) complexes to potentiate the anticancer effect of metformin (Met.) via glucose metabolism reprogramming, could increase overall survival and reduce side effects.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Biochemistry & Molecular Biology
Emanuele Zanda, Natalia Busto, Lorenzo Biancalana, Stefano Zacchini, Tarita Biver, Begona Garcia, Fabio Marchetti
Summary: The study found that certain ruthenium complexes exhibited remarkable stability in water and cell culture medium, showing strong cytotoxicity against cancer cell lines, with RUCYN being the most promising one with significant selectivity compared to non-cancerous cells. The variability of affinity of the complexes for BSA and DNA binding was determined, with certain complexes showing enhanced cell internalization and cytotoxicity at the expense of selectivity.
CHEMICO-BIOLOGICAL INTERACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Tobias Biberger, Stephan N. Hess, Markus Leutzsch, Alois Fuerstner
Summary: In this study, a new hydrogenation reaction transformation was reported, where propargyl alcohol derivatives were converted to cyclopentene products using [(CpRu)-Ru-X(MeCN)(3)]PF6 as catalyst. It was also discovered that rearrangements leading to other organic compounds could occur when the transient carbene carried appropriate substituents.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Hiroyuki Miyamura, Shu Kobayashi
Summary: This paper describes the development of cooperative and synergistic catalyst systems of heterogeneous Rh-Pt bimetallic nanoparticle catalysts, Rh-Pt/DMPSi-Al2O3, and Sc(OTf)(3) in the liquid phase for the hydrogenation of arenes under very mild conditions. The cooperative activation achieved significant rate acceleration and successful hydrogenation of challenging substrates with strong electron-donating groups and sterically hindered substituents was demonstrated.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Inorganic & Nuclear
Shinya Okazoe, Lena Staiger, Mirza Cokoja, Kohei Kusada, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Hiroshi Kitagawa, Roland A. Fischer
Summary: The study reports the hydrogenation catalytic activity application of molybdenum-ruthenium (MoRu) solid-solution alloy nanoparticles (NPs) for the hydrogenation of 1-octene and 1-octyne. The solid-solution structure of MoRu NPs enhances the catalytic activity of Ru by inducing a charge transfer from Mo to Ru, as observed through X-ray photoelectron spectroscopy.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Sivasankar Kulandaivel, Chia-Her Lin, Yi-Chun Yeh
Summary: The study reported a bi-metal organic framework, MOF-919 (Fe-Cu), capable of bifunctional-enzyme mimicking activity with oxidase- and peroxidase-like activities. A simple epinephrine colorimetric biosensor was developed based on this MOF, with a broad linear range and low detection limit, demonstrating its potential application as new nanosensors.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Ling- Hung, Dai-Yi Hsieh, Tsung-Hsiu Hsieh, Pei-Lin Chen, Chia-Her Lin, Sue-Lein Wang
Summary: In this study, three new trivalent titanium phosphorus oxides were synthesized using a simple strategy, each showing proton-coupled electron transfer (PCET) reactivity in a solid state. These compounds exhibit different structures and behaviors, providing new insights into the pathways of solid-state PCET reactions.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Chen-Yen Tsai, Yi-Hsuan Chen, Szetsen Lee, Chia-Her Lin, Chu-Han Chang, Wan-Ting Dai, Wan-Ling Liu
Summary: A SiO2@MOF core-shell microsphere was synthesized for environmentally friendly applications, showing high catalytic activity in the cycloaddition reaction of epoxides. Specifically, SiO2@ZIF-67 achieved a maximum conversion of 97% and could be used for multiple reaction cycles.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Vijayanath Elakkat, Eskedar Tessema, Chia-Her Lin, Xiaoping Wang, Huan-Cheng Chang, You-Ning Zheng, Yu-Cheng Huang, Zhong-Yun Gurumallappa, Zhong-Yun Zhang, Ka Long A. Chan, Hening A. S. Rahayu, Joseph S. Francisco, Norman Lu
Summary: To understand the effect of non-covalent weak interactions on molecules, we investigated different types of weak interactions in fluorinated chiral zinc complexes, including improper H-bonding, tetrel bonds, and halogen bonds. High resolution neutron diffraction studies revealed elongation and shortening of the methylene carbon-hydrogen bond due to tetrel bonds and improper H-bond interactions, respectively. We demonstrated how multiple weak interactions can cumulatively affect the C-H bond and offset its elongation through formation of an improper H-bond. Non-covalent interaction and electrostatic potential analysis investigations confirmed the nature of these interactions using density functional theory (DFT) and related calculations.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Ekta Roy, Souvik Pal, Chung-Wei Kung, Sheng-Sheng Yu, Achala Nagar, Chia-Her Lin
Summary: In this study, a conducting electrochemical sensing probe material, Cr-BDC-NH2@PANI, was successfully synthesized by polymerization of conducting polyaniline (PANI) around the Cr-BDC-NH2 material. The synthesized composite material was drop-casted on a cheap pencil graphite electrode (PGE) to detect trace levels of cadmium ions. The sensor exhibited high selectivity and affinity towards cadmium ions, and was capable of measuring the ions in various water samples and human blood with a low detection limit.
Article
Chemistry, Multidisciplinary
Po-Hsiang Tang, Pamela Berilyn So, Zi-Jing Lin, Chia-Chun Hsieh, Lee-Jene Lai, Chia-Her Lin
Summary: This paper mainly discusses the applicability of using soft x-ray tomography technology to examine the multidimensional structure of metal-organic frameworks, such as their core-shell and hollow framework. By visually observing their corresponding images in different energy bands by different excitation energies for different elements, the researchers can effectively observe the distribution of metals in the structure and the type of hollow pores the metal-organic framework possesses. This pioneering evaluation of MOFs via SXT shows excellent performance in the structure identification of multidimensional metal-organic frameworks.
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
(2023)
Article
Biochemistry & Molecular Biology
Manivannan Govindaraj, Shih-Ying Zhong, Chia-Her Lin, Jhy-Der Chen
Summary: Eight coordination polymers constructed from divalent metal salts, N,N-'-bis(pyridin-3-ylmethyl)terephthalamide (L), and various dicarboxylic acids were reported. The structural types of these compounds are subject to the metal and ligand identities, showing different 2D and 3D structures. The investigation on the photodegradation of methylene blue by using complexes 1-3 reveals that the degradation efficiency may increase with increasing surface areas.
Article
Biochemistry & Molecular Biology
Ya-Fen Hsu, Fan-Lu Kung, Tzu-En Huang, Yi-Ning Deng, Jih-Hwa Guh, Paolo Marchetti, Elena Marchesi, Daniela Perrone, Maria Luisa Navacchia, Lih-Ching Hsu
Summary: A bile acid-dihydroartemisinin hybrid, UDCMe-Z-DHA, exhibits stronger anticancer activity than dihydroartemisinin in hepatocellular carcinoma cells. UDCMe-Z-DHA is more stable and induces cell cycle arrest, reactive oxygen species production, mitochondrial membrane potential loss, and autophagy, leading to apoptosis in liver cancer cells. Compared to dihydroartemisinin, UDCMe-Z-DHA shows lower cytotoxicity towards normal cells and may be a potential drug candidate for hepatocellular carcinoma.
Article
Chemistry, Analytical
Sivasankar Kulandaivel, Chia-Her Lin, Yi-Chun Yeh
Summary: In this study, copper-based coordination polymer (Cu-CP) nanozymes were successfully synthesized to accelerate the oxidation of epinephrine (Epi) with high specificity. The Cu-CP nanozymes showed a wide linear range for Epi detection and excellent stability and recyclability. Moreover, colorimetric and fluorescence signals were used for sequential detection of the coexistence of Epi and norepinephrine (NE), making it possible to track the treatment outcomes of patients with pheochromocytoma. Experiments using artificial urine confirmed the efficacy of the proposed system.
Article
Biochemical Research Methods
Tarik Abdelkareem Mostafa Amer, Sathyadevi Palanisamy, Pamela Berilyn So, Priya Vijayaraghavan, Shey-Cherng Tzou, Tsai-Te Lu, Chia-Her Lin, Yun-Ming Wang
Summary: The use of MOF-based nanomaterials in bioapplications has increased due to their biocompatibility, drug degradation, tunable porosity, and intrinsic biodegradability. Bimetallic MOFs embedded with and without folic acid were synthesized and used for tissue sealing and repairing incisional wound sites in mice models. These materials displayed antibacterial properties and enhanced wound healing rates, and also showed potential for cell migration and angiogenesis.
BIOCONJUGATE CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Chen-Yen Tsai, Chin-Hung Liao, Mei-Ling Lin, Chia-Her Lin
Summary: The objective of this research is to create monolithic heterogeneous catalysts (cordierite@MOFs) through the application of metal-organic framework (MOF) materials onto honeycomb cordierite for CO2 cycloaddition. By employing monolithic catalysts instead of powdered catalysts, the recycling and reusability of catalysts during post-reaction treatment can be significantly improved. The cordierite@ZIF-67 catalyst, known for its high activity, stability, and easy recyclability, offers significant advantages in terms of practicality and efficiency. It not only improves the overall efficiency of the catalytic process but also contributes to the sustainability and environmental friendliness of the production process by minimizing waste and resource consumption.
INORGANIC CHEMISTRY
(2023)
Article
Materials Science, Biomaterials
Sivasankar Kulandaivel, Hsin-Tsung Chen, Chia-Her Lin, Yi-Chun Yeh
Summary: Finding materials that balance enzyme-like reactivity, stability, and affordability is crucial for future biosensing. Iron-based metal-organic frameworks (MOFs) with peroxidase properties offer potential solutions due to their variable pore size, surface area, and Lewis acid active sites. This study demonstrates the enhanced peroxidase catalytic activity of MIL-88B(Fe) (1,4-NDC) MOF and explores the sequential application of Fe-MOF and enzyme-encapsulating ZIF-90 PVP MOF for glucose detection. It highlights the potential of nanozymes as alternatives to natural enzymes in biosensing.
JOURNAL OF MATERIALS CHEMISTRY B
(2023)
Article
Chemistry, Multidisciplinary
Venkatesan Lakshmanan, Chia-Yi Lee, Yu-Wen Tseng, Yu-Hsiang Liu, Chia-Her Lin, Jhy-Der Chen
Summary: In this study, six coordination polymers with different topological structures and adsorption properties were synthesized through hydro(solvo)thermal reactions. Two of the polymers exhibited high selectivity for the detection of pesticides and good recyclability. Moreover, the effect of surface modification on the wettability of the materials was investigated.
Article
Biochemistry & Molecular Biology
Manivannan Govindaraj, Wei-Chun Huang, Chia-Yi Lee, Venkatesan Lakshmanan, Yu-Hsiang Liu, Pamela Berilyn So, Chia-Her Lin, Jhy-Der Chen
Summary: This study reports the synthesis and structural characterization of various Hg(II) halide complexes using single-crystal X-ray diffraction analyses. The ligand type and halide anion were found to play important roles in determining the structural diversity of the complexes. The luminescent properties and stability of selected complexes were also evaluated.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Materials Science, Multidisciplinary
Pamela Berilyn So, Chen-Yu Liu, Yu-Lun Lai, Cheng-Shiuan Lee, Chia-Her Lin
Summary: This work explores the capacity of metal-organic framework-polyvinyl alcohol composites in adsorbing volatile organic compounds. The experiment shows that these composites have higher adsorption capacity than commercially available adsorbents. Among them, MIL-68@PVA beads exhibit the best static adsorption capacity, while HKUST-1@PVA beads show the best adsorption capacity for low concentration toluene.
MATERIALS ADVANCES
(2022)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)