Article
Polymer Science
Mohd Adib Tajuddin Ahmad, Norizah Abdul Rahman
Summary: In this study, lignin was used as a soft template to mix with PAN and produce porous nanofibers following selective chemical dissolution. The removal of lignin significantly increased the specific surface area of the PAN/lignin nanofibers, showing potential for the production of highly porous carbon nanofibers.
Article
Environmental Sciences
Pooja P. Sarngan, Agasthiyaraj Lakshmanan, Debabrata Sarkar
Summary: Designing one-dimensional mixed-phase TiO2 with defects near the valence band, experimental results revealed that band alignment between two phases, up-shift of band edge, and optimum anatase percentage play a crucial role in enhancing photocatalytic activity. We predicted shifts in band edge induced by surface electric dipole layer from defects.
Article
Materials Science, Multidisciplinary
R. Pramanik, A. Arockiarajan
Summary: Soft hydrophilic composites are promising materials for biomedical applications due to their ability to promote cell growth and proliferation. This study focuses on the development of soft biomimetic scaffolds using a mixture of silk fibroin and nanocellulose fibres with varying mass ratios. The results show that a specific combination of these materials leads to optimal mechanical properties, including stiffness, strength, and elongation-at-break point (EOB). The internal architecture, rate-dependent viscoelastic characterization, and FTIR spectra are also analyzed.
Article
Chemistry, Multidisciplinary
Mengjie Chen, Si-Min Lu, Hao-Wei Wang, Yi-Tao Long
Summary: By statistically analyzing time-resolved current transients, we can quantitatively determine the dynamic chemical potential difference and interparticle communication between populations of large and small Ag NPs, enabling in situ investigation of chemical communication-dependent transformation kinetics of NPs in the photochemical process with the high sensitivity of stochastic collision electrochemistry, shedding light on designing nanomaterials.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Environmental Sciences
N. Ndwandwa, F. Ayaa, S. A. Iwarere, M. O. Daramola, J. B. Kirabira
Summary: In this study, cellulose nanofibers (CNFs) were successfully extracted from Hyparrhenia filipendula waste straws, and their structure and properties were reported for the first time in the open literature. Due to the structure and properties of the produced CNFs, they have potential applications such as polymer matrices, films, and membranes, enabling efficient utilization of agricultural waste.
WASTE AND BIOMASS VALORIZATION
(2023)
Article
Engineering, Environmental
Qiaorong Guo, Dongbin Wei, Chuanfang Zhao, Cuiping Wang, Haijun Ma, Yuguo Du
Summary: This study found that the physical UV-blocker CG-TiO2 could break the organic coatings and promote the chemical reactions of chemical sunscreen BP-1, leading to the formation of highly toxic products during UV irradiation. A total of 24 transformation products were identified, including hydroxyl BPs, hydroxyl dibenzo-p-dioxins, and hydroxyl benzoyl benzoquinones. This study highlights the role of CG-TiO2 in promoting the transformation of chemical sunscreens and generating higher toxicity during UV irradiation, providing scientific data for evaluating the fate and potential risk of sunscreens in the environment.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Environmental Sciences
Nohhyeon Kwak, Haebum Lee, Hyunok Maeng, Arom Seo, Kwangyul Lee, Seojeong Kim, Meehye Lee, Joo Wan Cha, Beomcheol Shin, Kihong Park
Summary: This study conducted shipborne measurements of fine particulate matter over the Yellow Sea and classified the particles into seven types based on morphology and composition. The results showed variations in particle concentrations and dominant types based on location and airflow conditions.
ENVIRONMENTAL POLLUTION
(2022)
Article
Chemistry, Multidisciplinary
Wenkai Liu, Ao Wang, Ruibo Yang, Hecheng Wu, Shuren Shao, Jinlin Chen, Yan Ma, Zhen Li, Yanchao Wang, Xueling He, Jiehua Li, Hong Tan, Qiang Fu
Summary: This article introduces a new method to achieve a soft-to-stiff transition in shape-memory polyurethane by incorporating the principle of phase-transition-induced stiffening. By triggering segmental rearrangement and transformation of hard domains through water, the material achieves improved stress transfer and shape recovery.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Wanlin Fu, Qi Zhan, Ying Yu, Xiangyu Meng, Mingyu Tang, Yunpeng Wang, Yueming Sun, Yunqian Dai
Summary: In this study, a green and facile approach was used to fabricate highly efficient adsorbent and photocatalyst with two-dimensional transition metal oxide nanostructures. Ultrathin and microporous AlOOH/Al2O3 nanosheets were topologically grown on the surface of TiO2-based nanofibers, leading to high adsorption capacity and significant photodegradation for RhB dye.
Article
Chemistry, Physical
Hai Qiu, Ying Li, Tianfu Guo, Shan Tang, Zhaoqian Xie, Xu Guo
Summary: The study investigates the mechanical behaviors of porous soft solids under biaxial loads, revealing new pattern transformations under biaxial compression for soft solids with oblique lattices of circular voids. Introducing tensile deformation in one direction can inhibit this pattern transformation, while the number of voids in square lattices of voids affects the deformation behaviors quantitatively rather than qualitatively. The results suggest that void morphology and biaxial loading can be utilized to tune the pattern transformations of porous soft solids under large deformation, providing new possibilities for controlling their deformation patterns under specific biaxial stress-states.
Article
Chemistry, Applied
O. Secundino-Sanchez, J. Diaz-Reyes, J. F. Sanchez-Ramirez, J. S. Arias-Ceron, M. Galvan-Arellano, O. Vazquez-Cuchillo
Summary: This study reports the synthesis of monocrystalline TiO2 nanofibers with high specific surface area using the electrospinning technique. The nanofibers were annealed at different temperatures to achieve crystalline phase transformation. The chemical stoichiometry, crystalline phase transformation, and optical properties were characterized. The photocatalytic activity of the annealed TiO2 nanofibers was also evaluated.
Article
Chemistry, Physical
Shijie Wu, Yan Song, Chunxiang Lu, Tao Yang, Shuxia Yuan, Xiaodong Tian, Zhanjun Liu
Summary: The morphology of soft carbons can be regulated by using pitches with different chemical structures, leading to the formation of lamellar structures. These lamellar structures have more exposed defect-edge sites and larger active surface, which contribute to the adsorption of potassium ions and improved reaction kinetics.
Article
Plant Sciences
Yu Liu, Yanan He, Fang Wang, Runchun Xu, Ming Yang, Zhimin Ci, Zhenfeng Wu, Dingkun Zhang, Junzhi Lin
Summary: Artemisia argyi, known as the longevity grass in eastern countries, has been used for over two thousand years for its warm effect in curing cold diseases. The Artemisia argyi essential oil has been recognized for its medicinal properties and developed into various health products, showing potential in disease resistance, anti-inflammatory, analgesic, and anti-cancer effects. The plant has demonstrated remarkable efficacy in traditional medicine, but further research is needed to fully understand its toxicity and mechanism of action.
JOURNAL OF ETHNOPHARMACOLOGY
(2021)
Article
Multidisciplinary Sciences
Wenxiong Zhang, Eiji Hosono, Daisuke Asakura, Hayato Yuzawa, Takuji Ohigashi, Masaki Kobayashi, Hisao Kiuchi, Yoshihisa Harada
Summary: In this study, the spatial distributions of chemical states in LiCoO2 cathode particles were investigated using scanning transmission X-ray microscopy, revealing heterogeneous reactions within individual particles after charging to 4.5 V. The results also showed the existence of non-active particles, indicating the importance of understanding local reactions in battery materials for improved performance.
SCIENTIFIC REPORTS
(2023)
Review
Chemistry, Physical
Diana Jesus, Ana R. Pinho, Maria C. Gomes, Claudia S. Oliveira, Joao F. Mano
Summary: Bone tissue engineering aims to recreate the bone microenvironment for bone regeneration by guiding cell fate towards the osteogenic lineage. It is important to consider the synergistic effect of biochemical/physical cues, as cells in their native microenvironment are stimulated by multiple signals simultaneously. Therefore, combined modifications are crucial for developing innovative bone regenerative therapies.
Article
Biotechnology & Applied Microbiology
Jyotsna Thayath, Keechilat Pavithran, Shantikumar Nair, Manzoor Koyakutty
Summary: The study team developed a method to convert total blood serum into chemo drug-loaded nanoparticles and demonstrated its significant antitumor efficacy in vitro and in vivo.
Article
Chemistry, Multidisciplinary
Binitha Gangaja, Shantikumar Nair, Dhamodaran Santhanagopalan
Summary: Rechargeable lithium-ion batteries dominate the energy storage market with a market value of $50 billion. The study demonstrates the possibility of reusing spent LiFePO4 cathodes for new lithium-ion batteries and investigating their use in sodium-ion storage.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Materials Science, Multidisciplinary
Rosebin Babu, C. R. Reshmi, John Joseph, Binulal N. Sathy, Shantikumar Nair, Praveen Kerala Varma, Deepthy Menon
Summary: This study demonstrates the design and fabrication of woven electrospun nanotextile vascular patches with biodegradable polymers, meeting mechanical and biological requirements for vascular applications. The unique nanofibrous architecture of the nanotextile allows for exceptional anisotropic mechanical behavior and good biocompatibility. The integration of electrospinning and weaving techniques results in a novel biodegradable material suitable for vascular patch applications.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2021)
Article
Materials Science, Biomaterials
Aarya G. Krishnan, John Joseph, C. R. Reshmi, Shantikumar Nair, Manitha Nair, Deepthy Menon
Summary: In this study, the technique of cylindrical weaving was combined with electrospinning to fabricate a seamless bilayered conduit with improved mechanical properties and cellular response. The results showed that this bilayered construct could potentially be a suitable candidate for small diameter vascular prosthesis.
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS AND POLYMERIC BIOMATERIALS
(2023)
Article
Materials Science, Biomaterials
P. S. Unnikrishnan, Subramania Iyer, V. Manju, C. R. Reshmi, Deepthy Menon, Shantikumar V. Nair, Manitha Nair
Summary: This study investigated the bone formation potential of a nanocomposite fibrous scaffold in mandible defects and compared it with autograft. The results showed that the scaffold promoted quality bone formation and demonstrated better osseointegration after dental implant placement.
BIOMATERIALS ADVANCES
(2022)
Review
Nanoscience & Nanotechnology
Prashant Sadanandan, Natalie L. Payne, Guizhi Sun, Anusha Ashokan, Siddaramana G. Gowd, Arsha Lal, Madathiparambil Kumaran Satheesh Kumar, Sreeranjini Pulakkat, Shantikumar Nair, Krishnakumar N. Menon, Claude C. A. Bernard, Manzoor Koyakutty
Summary: Targeting nano-conjugated autoantigens to tissue-resident macrophages in lymphoid organs can effectively suppress autoimmunity and restore self-tolerance.
NANOMEDICINE-NANOTECHNOLOGY BIOLOGY AND MEDICINE
(2022)
Article
Biotechnology & Applied Microbiology
John Joseph, Vito Domenico Bruno, Nadiah Sulaiman, Alexander Ward, Thomas W. Johnson, Helna Mary Baby, Shantikumar Nair, Deepthy Menon, Sarah Jane George, Raimondo Ascione
Summary: The study successfully engineered a highly flexible and mechanically robust nanotextile-based vascular graft (NanoGraft) and demonstrated its potential superiority over the commercial ePTFE in an animal model, suggesting promising clinical applications.
JOURNAL OF NANOBIOTECHNOLOGY
(2022)
Article
Nanoscience & Nanotechnology
Silpasree S. Jayasree, Shantikumar Nair, Dhamodaran Santhanagopalan
Summary: This study investigates the effect of nanoscale engineering of LiCoO2 (LCO) along with coating chemistry and thickness on its electrochemical performance at higher voltages and wide operating temperatures. The results show that LCO coated with 5 wt% Al2O3 exhibits improved reversible capacity, high rate capability, and better stability at various temperatures. The enhanced performance is attributed to the lower charge transfer resistance and structural stability derived from the stable solid solution formation on the interface.
Correction
Biotechnology & Applied Microbiology
John Joseph, Vito Domenico Bruno, Nadiah Sulaiman, Alexander Ward, Thomas W. Johnson, Helna Mary Baby, Shantikumar V. Nair, Deepthy Menon, Sarah Jane George, Raimondo Ascione, Praveen Kerala Varma, Rajesh Jose
JOURNAL OF NANOBIOTECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Minu Anoop, Aswathy R. Nambiar, Shantikumar Nair, Manzoor Koyakutty, Anusha Ashokan
Summary: Zoledronic acid is a potent drug used in cancer immunotherapy to activate gamma delta T cells and deplete tumor-associated macrophages. By optimizing zoledronic acid-conjugated calcium phosphate nanoparticles, in vitro expansion of gamma delta T cells can be improved, leading to enhanced toxicity to macrophages for better depletion of tumor-associated macrophages. The development of this nanoconjugate has great potential in enhancing the clinical efficacy of bisphosphonate-mediated cancer immunotherapy.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Dona Susan Baji, Shantikumar Nair, Dhamodaran Santhanagopalan
Summary: A facile process for the preparation of alkali ion containing Prussian blue cathodes by chemical reduction is reported. The chemical sodiation into Fe[Fe(CN6)] is found to be more efficient than lithiation. The sodiated cathode showed a capacity retention of about 70% after 500 cycles for sodium ion battery applications, while the lithiated cathode showed a better capacity retention of 92% after 300 cycles for lithium ion battery applications.
SUSTAINABLE ENERGY & FUELS
(2022)
Article
Nanoscience & Nanotechnology
Vinod Paul, Sreelakshmi Krishnakumar, Genekehal Siddaramana Gowd, Shantikumar Nair, Manzoor Koyakutty, Bindhu Paul-Prasanth
Summary: This study found that the toxic effects of nZnO on the reproductive system were mainly caused by ROS induction, while zinc ions were predominantly responsible for the adverse impact of ZnSO4. Exposure to nZnO in males affected sexual behavior and fertility, while in females it caused ovarian issues and changes in sex steroid levels.
ACS APPLIED BIO MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Arya Vasanth, Shantikumar Nair, Mariyappan Shanmugam
Summary: Temperature-dependent changes in the structural, nanomorphological, and optical characteristics of 2D layered molybdenum diselenide processed by electrophoretic coating method were investigated. Post-annealing treatments at different temperatures affected the surface morphology, optical absorption, and film compactness of the MoSe2. The study confirmed that electrophoretic coating yielded high-quality MoSe2 films suitable for functional devices.
JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES
(2021)
Article
Electrochemistry
Aswathy S. Murali, Dona Susan Baji, Shantikumar Nair, Dhamodaran Santhanagopalan
Summary: A simple vapor-phase conversion method was used to convert metal oxalates into metal phosphide nanostructures, which showed good performance in various alkali ion batteries with reversible specific capacity under different cycling conditions.
ELECTROCHIMICA ACTA
(2021)
Article
Nanoscience & Nanotechnology
Badrinathan Sridharan, Naveen Devarajan, Rupal Jobanputra, Genekehal Siddaramana Gowd, Ida Mulayirikkal Anna, Anusha Ashokan, Shantikumar Nair, Manzoor Koyakutty
Summary: A biomineral nanocontrast agent based on iron-doped nanocalcium phosphate was developed for early detection of liver cirrhotic and hepatocellular carcinoma nodules. The optimized nanocontrast agent showed promising results in detecting liver tumor lesions as small as 0.25 cm and was eliminated through hepatobiliary clearance within 72 hours.
ACS APPLIED BIO MATERIALS
(2021)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)