期刊
DALTON TRANSACTIONS
卷 44, 期 48, 页码 21131-21140出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03636d
关键词
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资金
- National Natural Science Foundation of China [21171035, 51302035, 51472049, 11204030]
- Key Grant Project of Chinese Ministry of Education [313015]
- Ph.D. Programs Foundation of the Ministry of Education of China [20110075110008, 20130075120001]
- China Postdoctoral Science Foundation [2014M550203]
- Science and Technology Commission of Shanghai Municipality [13ZR1451200]
- Program Innovative Research Team in University [IRT1221]
- Shanghai Leading Academic Discipline Project [B603]
- Program of Introducing Talents of Discipline to Universities [111-2-04]
- Fundamental Research Funds for the Central Universities
- Foundation of Shanghai University of Engineering Science [E1-0501-15-0105]
- Project of Shanghai universities young teacher training scheme [ZZGCD15037]
The design and fabrication of high performance supercapacitors with a high specific capacitance and a long lifespan still remain a challenge. We present two hydrothermal and two annealing processes for the fabrication of hierarchical heterostructures of NiO@MMoO4 (M = Co, Ni) nanosheet arrays on Ni foam. In this hierarchical structure, numerous MMoO4 nanoflakes grow on a NiO nanosheet and the integration of MMoO4 can improve the whole electrode's conductivity, leading to an ideal pathway for electron and ion transport. The hierarchical NiO@MMoO4 (M = Co, Ni) heterostructure electrode demonstrated remarkable electrochemical performance with a high specific capacitance and predominant cycling stability, making it one of the prospective electrode materials for high performance supercapacitors.
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