4.7 Article

An aggregation-induced emission (AIE) active probe for multiple targets: a fluorescent sensor for Zn2+ and Al3+ & a colorimetric sensor for Cu2+ and F-

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DALTON TRANSACTIONS
卷 44, 期 43, 页码 18902-18910

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03186a

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  1. CSIR [01/2727/13/EMR-II]
  2. Science & Engineering Research Board, India [SR/S1/OC-62/2011]
  3. IIT Guwahati

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A rationally designed probe L, which consists of both cation and anion binding sites, is capable of displaying interesting aggregation induced emission (AIE) properties. L not only can sense Al3+ and Zn2+ through selective turn-on fluorescence responses in 9 : 1 methanol-HEPES buffer (5 mM, pH 7.3; 9 : 1, v/v) medium due to metal ion triggered AIE activity, but also can distinguish them through individual emission signals. L can also detect Cu2+ in mixed buffer medium and F-in acetonitrile through sharp colorimetric responses. All the sensing processes are conspicuous through the naked eye. A theoretical study strongly backed the proposed sensing mechanisms.

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