期刊
DALTON TRANSACTIONS
卷 44, 期 44, 页码 19056-19058出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt02972d
关键词
-
资金
- JSPS KAKENHI Grant [26286001, 26620042]
A polyoxometalate-silver ethynide composite cluster, [Ag-42(CO3)-{ C = CC(CH3)(3)}(27)(alpha-A-SiW9Nb3O40)(2)](-) (1), demonstrates that we can select the binding site of a polyoxometalate to the silver alkynide cluster by tuning the surface charge of the precursor polyoxometalate. Multidimensional and multinuclear NMR spectra revealed that 1 maintains its precise atomic connectivity in the solution.
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