4.6 Article

Mechanical properties of carbon fiber reinforced bisphenol A dicyanate ester composites modified with multiwalled carbon nanotubes

期刊

JOURNAL OF APPLIED POLYMER SCIENCE
卷 134, 期 29, 页码 -

出版社

WILEY
DOI: 10.1002/app.45100

关键词

composites; fullerenes; graphene; mechanical properties; nanotubes

资金

  1. Natural Science Foundation of China [51272210, 50902112, 51221001]
  2. Program for New Century Excellent Talents in University [NCET-13-0474]
  3. Foreign Talents Introduction and Academic Exchange Program of China [B08040]
  4. Scientific Research Fund of Jilin Provincial Education Department [2015437]

向作者/读者索取更多资源

A novel electrophoretic deposition (EPD) method was employed for grafting multiwalled carbon nanotubes (MWCNTs) on carbon fibers, which, after impregnation with bisphenol A dicyanate ester (BADCy), synergistically reinforced BADCy matrix composites (CNT-C/BADCy). The effect of MWCNT presence on the mechanical properties of the composites was investigated. Composite tensile strength increased by 45.2% for an EPD duration of 2 min, while flexural strength exhibited a decreasing trend with EPD duration. Optical microscopy revealed that the existence of MWCNTs enhanced the fiber-matrix interface while a large number of CNTs were observed to have pulled-out from the matrix, a finding which explained the observed tensile strength increase in terms of energy dissipation by the specific toughening mechanism. The flexural strength decrease of the composites with CNTs as compared to specimens without nanotubes was found linked to the increased stress concentration in the BADCy matrix due to tube presence which weakens the adhesion between carbon fabrics. In a word, carbon nanotubes will enhance the micro interface and weaken the macro interface of the composites. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45100.

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