4.6 Article

Forest-based resources as fillers in biobased polyurethane foams

期刊

JOURNAL OF APPLIED POLYMER SCIENCE
卷 135, 期 3, 页码 -

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WILEY
DOI: 10.1002/app.45684

关键词

cellulose and other wood products; composites; thermosets

资金

  1. Brazilian National Council for Scientific and Technological Development (CNPq)

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Six fillers from forestry wastes (wood, bark, cones and needles from young pine trees, kraft lignin, and recycled paper sludge from industry wastes) were incorporated into polyurethane (PU)-based foams prepared via free-rise pouring method. Variable filler contents (1, 5, and 10 wt %) and NCO/OH ratios (0.6, 0.9, and 1.2) were investigated. A simple mixture (1:3) of castor oil and crude glycerin (byproduct from biodiesel production) was used as biobased polyol. The foam composites were investigated through spectroscopy, morphological, mechanical, and hygroscopic analyses. The addition of fillers decreased water uptake and yielded rigid PU systems with more homogenous cell structure. The 1% and 5% reinforcement wood were the most effective among the studied compositions, with better mechanical and hygroscopic performance, probably due the higher compatibility of the wood with the PU system, which promote urethanic bonds between filler and isocyanate, as indicated by wet chemical results and micrographs. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 45684.

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