4.7 Article

Microstructure and mechanical properties of Mg-4Zn-0.5Ca alloy fabricated by the combination of forging, homogenization and extrusion process

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 720, 期 -, 页码 196-206

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.05.232

关键词

Mg-4Zn-0.5Ca alloy; Extrusion; Homogenization treatment; Microstructure; Mechanical properties

资金

  1. National Natural Science Foundation of China [51201112, 51401144]
  2. Natural Science Foundation of Shanxi [201601D011034, 2015021067]

向作者/读者索取更多资源

The Mg-4Zn-0.5Ca alloy was processed by the combination of forging, homogenization and extrusion in present study. The results showed that homogenization treatment between forging and extrusion process can release stored energy and diminish precipitated MgZn2 phase, both of which result in the finer size and low volume fraction of dynamic recrystallized (DRXed) grains, as well as strong basal plane texture in the as-extruded alloy (FD-H-ED). As compared with the as-extruded alloy without homogenization treatment (FD-ED), the FD-H-ED alloy exhibited high yield strength which is thought to originate from the dislocation strengthening and texture strengthening. Only stage III and stage IV appeared in the theta vs. (sigma , sigma(0.2)) curves of FD-ED and FD-H-ED alloys. Large amount of fine DRXed grains in FD-ED alloy led to the high dynamic recovery rate at stage III. However, the unDRXed regions in FD-H-ED alloy resulted in its unobvious starting point and promote the decrease of theta value at Stage IV. (C) 2017 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Nanoscience & Nanotechnology

Work hardening and softening behavior of Mg-Zn-Ca alloy influenced by deformable Ti particles

Yi-dan Fan, Kun-kun Deng, Cui-ju Wang, Kai-bo Nie, Quan-xin Shi

Summary: Pure titanium particles reinforced Mg-6Zn-0.2Ca magnesium matrix composites were successfully fabricated and their mechanical properties were studied. The results showed that the titanium particles promoted dynamic recrystallization of the matrix alloy, refining the size of MgZn2 phases and resulting in high yield strength and ultimate tensile strength in the composite. However, the work hardening rate of the composite decreased during plastic deformation.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2022)

Article Nanoscience & Nanotechnology

Effect of Nd on the microstructure and mechanical properties of Mg-3Zn-0.5Zr alloy

J. H. Zhang, K. B. Nie, K. K. Deng, X. Z. Han, Z. D. Wang

Summary: The effect of adding trace elements of Nd to Mg-3Zn-0.5Zr alloy was studied. It was found that Nd content significantly influenced the composition and distribution of the second phase in the alloy. The introduction of Nd resulted in a decrease in grain size and grain boundary strengthening, as well as an increase in texture intensity. High strength alloys with low alloying content and traditional extrusion processes were obtained.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2022)

Article Nanoscience & Nanotechnology

Effects of precipitates and solute atoms on the work hardening and softening behavior of Zn-rich aluminum alloy

Ren Jie Dai, Kun Kun Deng, Cui Ju Wang, Kai Bo Nie, Guo Wei Zhang, Wei Liang

Summary: AE alloy and AS alloy were obtained by extrusion and solution treatment of Zn-rich aluminum alloy. AE alloy has fine grains and high precipitate content, while AS alloy has increased grain size and dissolved precipitates. Both alloys show improved mechanical properties, but AE alloy has higher work hardening capacity.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2022)

Article Materials Science, Multidisciplinary

Effect of hot extrusion on the microstructure and mechanical properties of SiCNWs/Mg-2Zn-0.1Y composite

Wei Li, Kaibo Nie, Zhilong Liu, Kunkun Deng, Yanan Li, Xili Tong

Summary: The addition of SiC nanowires affected the microstructure and mechanical properties of Mg-2Zn-0.1Y matrix composites under different hot extrusion parameters. Stengthening mechanism was analyzed and the results showed significant changes in grain size and volume fraction with variations in extrusion temperature and speed.

MATERIALS CHARACTERIZATION (2022)

Article Materials Science, Multidisciplinary

The corrosion properties of AZ91 alloy improved by the addition of trace submicron SiCp

Xin Lv, Kun-Kun Deng, Cui-Ju Wang, Kai-Bo Nie, Quan-Xin Shi, Wei Liang

Summary: The addition of trace submicron SiC particles can promote the formation of lamellar (α+β) structure and improve the corrosion resistance of the alloy. However, the precipitation of granular β-Mg17Al12 phase with increased SiCp content leads to a gradual decrease in corrosion resistance.

MATERIALS CHEMISTRY AND PHYSICS (2022)

Article Materials Science, Multidisciplinary

Effect of extrusion on the microstructure and mechanical properties of a low-alloyed Mg-2Zn-0.8Sr-0.2Ca matrix composite reinforced by TiC nano-particles

Zedong Wang, Kaibo Nie, Kunkun Deng, Jungang Han

Summary: A low-alloyed Mg-2Zn-0.8Sr-0.2Ca matrix composite reinforced by TiC nano-particles was successfully prepared by semi-solid stirring under the assistance of ultrasonic, and then the as-cast composite was hot extruded. The finest grain size of similar to 0.30 mu m is obtained in the sample extruded at 200 degrees C and 0.1 mm/s. The ultra-high mechanical properties (ultimate tensile strength of 480.2 MPa, yield strength of 462 MPa) are obtained after extrusion at 200 degrees C with a rate of 0.1 mm/s. Among all strengthening mechanisms for the present composite, the grain refinement contributes the most to the increase in strength. A mixture of cleavage facets and dimples were observed in the fracture surfaces of three as-extruded nanocomposites, which explain a mix of brittle-ductile fracture way of the samples.

INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS (2022)

Article Materials Science, Multidisciplinary

The Effect of Extrusion Parameters on the Microstructure and Mechanical Properties of TiCp/Mg-2.4Al-2.4Ca-0.6Mn Nanocomposites

Hongwei Li, Kaibo Nie, Zhilong Liu, An Yang, Kunkun Deng

Summary: TiCp/Mg-Al-Ca-Mn nanocomposites were produced through extrusion, which resulted in refined grains and changes in the second phase. The composites exhibited specific texture composition and their properties were influenced by the degree of dynamic recrystallization and precipitates. The nanocomposites showed excellent mechanical properties, which were enhanced by various strengthening mechanisms.
Article Materials Science, Multidisciplinary

Effect of Ca/Al Ratio on Microstructure and Mechanical Properties of Slow Extrusion High-Strength Mg-Al-Ca-Mn Alloys

Shilei Wang, Kaibo Nie, An Yang, Kunkun Deng

Summary: The influence of different Ca/Al mass ratios on the microstructure, phase evolution, and mechanical properties of Mg-Al-Ca-Mn alloys was investigated. It was found that increasing the Ca/Al ratio led to the transformation of the secondary phases and refinement of the grain size. The secondary phases not only refined the grains but also hindered dislocation migration, resulting in the strengthening of the alloy.

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE (2023)

Article Nanoscience & Nanotechnology

The work hardening and softening behaviors of Mg-6Zn-1Gd-0.12Y alloy influenced by the VR/VD ratio

Mei-li Hou, Kun-kun Deng, Cui-ju Wang, Kai-bo Nie, Quan-xin Shi

Summary: The effects of the VR/VD ratio on the work hardening and softening behaviors of Mg-6Zn-1Gd-0.12Y alloy were studied. It was found that increasing the VR/VD ratio reduced the work hardening rate in stage III, while increasing it in stage IV. A low VR/VD ratio improved the work hardening rate in stage III, while a high VR/VD ratio improved it in stage IV. With an increased VR/VD ratio, the softening behavior of the alloy increased in stage III and decreased and then increased in stage IV.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2022)

Article Electrochemistry

The corrosion resistance and discharge performance of as-extruded AZ91 alloy synergistically improved by the addition of submicron SiCp

Xin Lv, Kunkun Deng, Cuiju Wang, Kaibo Nie, Quanxin Shi, Haoyi Niu

Summary: Through immersion, electrochemical, and Mg-air battery tests on extruded AZ91 alloy and 0.5 μm SiCp (0.5 vol.%)/AZ91 composite, it is found that the introduction of submicron SiCp can reduce the corrosion rate and improve the discharge performance of the alloy. This improvement is attributed to the refined grains, precipitates, and weakened basal texture resulting from the addition of submicron SiCp. This study provides new ideas for achieving the synergistic improvement of corrosion resistance and discharge performance of magnesium alloy.

ELECTROCHIMICA ACTA (2023)

Article Materials Science, Composites

Achieving strength-thermal conductivity synergy in Mg bulk system via introducing oriented graphite flakes into Mg-Zn-Ca alloy

Li Zhang, Kun-kun Deng, Kai-bo Nie, Cui-ju Wang, Chao Xu, Quan-xin Shi

Summary: GFs/ZX50 (graphite flakes/Mg-5Zn-0.5Ca) composites were successfully fabricated by ultrasonic-assisted semi-solid stirring followed by extrusion process. The microstructure observation shows that hot extrusion effectively regulates the orientation of GFs. The GFs/ZX50 composites exhibit excellent thermal conductive property of -145.6-174.2 W/(m center dot K) and high yield strength of -386.8-407.8 MPa. The excellent strength-thermal conductivity synergy of the composites is mainly attributed to the highly orientated GFs, the clean Mg-graphite interface, the ultrafine grains, and the MgZn2 nano-precipitates.

COMPOSITES COMMUNICATIONS (2023)

Article Chemistry, Physical

Work hardening and softening behaviors of Mg-Zn-Gd-Ca alloy regulated by bimodal microstructure

Quan-xin Shi, Cui-ju Wang, Kun-kun Deng, Yi-dan Fan, Kai-bo Nie, Wei- Wei-Liang

Summary: The present work investigates the impact of bimodal microstructure on the work hardening and softening behaviors of Mg-6Zn-1Gd-0.3Ca alloy. The study also discusses the grain refinement mechanism through EBSD analysis. The results reveal that the work hardening capacity of the alloy increases with the volume fraction of fine recrystallized grains due to increased dislocation storage rate caused by grain coarsening. The stress reduction value in the early stage of deformation is the highest for the alloy with fine recrystallized grains, providing a greater driving force for softening effect. However, the stress reduction values decrease with the increase of fine recrystallized grains in the later stage of deformation. Furthermore, the analysis indicates that dynamic recrystallization plays a significant role in the formation of fine recrystallized grains in the Mg-6Zn-1Gd-0.3Ca alloy.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Materials Science, Multidisciplinary

The corrosion resistance of homogenized AZ91 alloy influenced by submicron SiCp content

Xin Lv, Kunkun Deng, Cuiju Wang, Kaibo Nie, Xiaogang Wang, Quanxin Shi

Summary: The effect of submicron SiCp content on the corrosion resistance of homogenized AZ91 alloy was investigated. The results showed that the addition of 0.5 vol.% submicron SiCp significantly improved the corrosion resistance, reducing the weightless corrosion rate from 4.44 mm/y to 0.68 mm/y. However, the corrosion resistance decreased with increasing submicron SiCp concentration.

MATERIALS TODAY COMMUNICATIONS (2023)

Article Chemistry, Physical

Magnetic/optical assessments of RFeO3 (R=La, Pr, Nd, and Sm) ceramics: An experimental and theoretical discernment

J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia

Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

The effect of Ti-based surface layer on AlSi thin film as a high-performance anode for the lithium-ion battery

Xianxiang Lv, Jing Jin, Weiguang Yang

Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Bifunctional phosphate-modulated Cu2O/CeO2 redox heterojunction: A promising approach for proficient CO2 reduction

Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao

Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Engineering heterogeneous synergistic interface and multifunctional cobalt-iron site enabling high-performance oxygen evolution reaction

Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong

Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Highly efficiency blue emissive from Bi3+ions in zero-dimensional organic bismuth halide for white LED applications

Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang

Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Study on the wear resistance and mechanism of AlCrCuFe2NiTix high-entropy surfacing alloys

Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong

Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Facile synthesis of ternary g-C3N4/polyacrylic acid/CoFe2O4 nanocomposites for solar light irradiated photocatalytic and supercapacitor applications

M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu

Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Investigation on bio-synthesized Ni- and Al-doped cobalt ferrite using lemon juice as eco-fuel

Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad

Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Cu, Ni and Ag ions assisted preparation of nonpolar preferential oriented ZnO films with controlled morphology and optical properties

Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi

Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Characterization of magnetic FeCo particles with controlled bimetallic composition

Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang

Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Micro-alloying effects of Ta and B on nano-oxides and grain boundaries in 13CrWTi-ODS ferritic alloys

Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang

Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Nitrogen-doped reduced graphene oxide/black phosphorus quantum dot composites for electrocatalytic treatment of choroidal melanoma

Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang

Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Significantly enhanced magnetism in cobalt ferrite by manganese and terbium co-doping

Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu

Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

High-performance low-temperature solid oxide fuel cell with nanostructured lanthanum strontium cobaltite/yttria-stabilized zirconia cathode via advanced co-sputtering

Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee

Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Amorphous quaternary alloy nanoplates for efficient catalysis of hydrogen evolution reaction

Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu

Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)