Enhanced mechanical and thermal properties of anisotropic fibrous porous mullite-zirconia composites produced using sol-gel impregnation

A new lightweight and thermal insulating material was successfully prepared by impregnating Al2O3 SiO2 aerogel into a porous mullite zirconia fiber network with a quasi-layered microstructure. The microstructures, thermal and mechanical properties of the porous mullite zirconia ceramics were investigated before and after the impregnating of Al2O3-SiO2 aerogel. It was observed that the mullite and zirconia fibers combined well with aerogels. Compared with fibrous porous mullite-zirconia ceramics, the Al2O3-SiO2 aerogel/porous mullite zirconia composite exhibited higher compressive strength (i.e. 136 MPa in the z direction) and lower thermal conductivity (i.e. 0.052 Wi(m . K)). The present work provides an efficient way to fabricate highly porous ceramics with high strength and ultra low thermal conductivity, which find potential use in high-temperature thermal insulation materials. (C) 2017 Elsevier B.V. All rights reserved.