期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 715, 期 -, 页码 170-175出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.04.196
关键词
Rutile TiO2; Atmosphere; Grain growth; Colossal permittivity; Oxygen vacancy; XPS analysis
资金
- Shaanxi Normal outstanding doctoral dissertation [S2012YB05]
- National Natural Science Foundation of China [51572162]
(Yb1/2Nb1/2)(0.05)Ti0.95O2 ceramics are fabricated by the solid state reaction method. The effects of oxygen partial pressure in the sintering atmosphere (10% <= x <= 100%) on crystal structures, microstructure and dielectric properties of (Yb1/2Nb1/2)(0.05)Ti0.95O2 are investigated. All samples have rutile structure, and average grain size rises from 5 mu m to 28 mu m with x increasing from 10% to 100%. All samples show colossal permittivity (above 10(4)). The dielectric properties of x >= 50% samples show well temperature (120 K-370 K) and frequency stability (100 Hz-100 kHz). The grain resistivity of x = 100% sample is three orders of magnitude higher than that of x = 10%. The breakdown voltage improves from 246 to 716 V/cm with increasing oxygen partial pressure. Both the Ti valence and oxygen concentration have been influenced by sintering atmosphere. (C) 2017 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据