Article
Chemistry, Physical
Mohammad Bagher Karimi, Fereidoon Mohammadi, Maral Ghahramani, Mehran Javanbakht
Summary: This study evaluates the potential and challenges of electrospun Nafion membranes as gel polymer electrolytes (GPEs) for lithium-ion batteries. By incorporating poly(ethylene oxide) (PEO) and poly(vinyl alcohol) (PVA), the pure Nafion membranes successfully address certain challenges and exhibit enhanced performance. The electrospun Nafion/PVA membranes demonstrate high ionic conductivity, exceptional electrochemical stability, and remarkable long-term cyclic stability.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Electrochemistry
C. Martinez-Cisneros, C. Antonelli, B. Levenfeld, A. Varez, J. C. Perez-Flores, A. Santos-Mendez, A. Kuhn, J-Y Sanchez
Summary: This study systematically investigates non-woven separators based on polyacrylonitrile blended with cellulose and para-aramid fibers, providing a potential alternative for more stable and safer lithium-ion batteries. Although the conductivity values are modest, the electrochemical performance developed when used in Li4Ti5O12/LiCoO2 cells is satisfactory.
ELECTROCHIMICA ACTA
(2021)
Article
Nanoscience & Nanotechnology
Pui Lap Jacob Lee, Vigneshwaran Thangavel, Claude Guery, Christina Trautmann, Maria Eugenia Toimil-Molares, Mathieu Morcrette
Summary: This study explores the use of polymer etched ion-track membranes as separators in Li-S batteries to mitigate the redox shuttle effect. Compared to commercial separators, these membranes offer unique advantages in adjusting and optimizing the density, geometry, and diameter of nanopores, effectively reducing the self-discharge issue of the battery.
Article
Engineering, Chemical
Minggui Zou, Yanmei Luo, Xu Ma, Jinqiang Fan, Yan Niu, Jierui Liang, Guifen Gong
Summary: This study reports on the surface modification of EVO-Li membranes with poly-dopamine to enhance their mechanical properties. The reaction of PDA with EVO-Li forms C-N-O bonds, improving the ultimate tensile strength of the membrane and enhancing its water uptake property and thermostability.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Engineering, Multidisciplinary
Lingli Liu, Tongwei Xu, Xuefeng Gui, Shuxi Gao, Longfeng Sun, Qiong Lin, Xuan Song, Zhongxin Wang, Kai Xu
Summary: A study on a silsesquioxane-modified electrospun hybrid membrane that improves the mechanical, thermal, and electrochemical performance for application in lithium batteries. Research findings show that separators decorated with octa-silsesquioxanes (SQ-T8) offer superior cycling performance, while those with deca-silsesquioxanes (SQ-T10) exhibit higher capacity.
COMPOSITES PART B-ENGINEERING
(2021)
Article
Materials Science, Multidisciplinary
Jianwei Li, Xuanning Zhang, Yuyan Lu, Keliang Linghu, Chen Wang, Zhonglei Ma, Xinhai He
Summary: In this study, composite nanofibrous membranes (CNMs) with enhanced mechanical strength and thermal stability were successfully fabricated by synthesizing fluorinated polyimide (FPI) and blending it with polyvinylidene fluoride (PVDF). The CNMs showed improved tensile strength and almost no dimensional shrinkage after heat treatment. In addition, the CNMs exhibited enhanced electrochemical performances compared to neat PVDF and commercial Celgard membranes, with higher electrolyte uptake and ionic conductivity. The prepared CNMs offer a promising approach for high-performance separator design.
ADVANCED FIBER MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Xiaobao Gong, Chunfeng Jin, Xiao-Yan Liu, Jianyong Yu, Shichao Zhang, Bin Ding
Summary: This study presents a novel strategy to develop true-nanoscale fibers with remarkable nanostructural characteristics and separation performances in areas of protective textiles, air filtration, and water purification. The obtained fibers have true-nanoscale diameters and the resultant membranes exhibit excellent properties.
Article
Materials Science, Paper & Wood
Xiaobin Zhao, Wenbo Wang, Chenghao Huang, Lei Luo, Zhongmin Deng, Wei Guo, Jie Xu, Zhenghua Meng
Summary: A novel cellulose separator for Li-ion batteries (LIBs) named TOCF was successfully fabricated from cattail fibers, showing good tensile strength, thermal dimensional stability, sufficient porosity, outstanding liquid electrolyte uptake, and large ionic conductivity. The Li/LiFePO4 cell assembled using the TOCF separator demonstrated better discharge capacity and cycling stability compared to a cell with a commercial Celgard separator, making TOCF a promising and low-cost candidate for high-performance LIBs.
Article
Engineering, Chemical
Solmaz Parsaei, Seyed Mojtaba Zebarjad, Mohammad Hadi Moghim
Summary: PI/PVDF-HFP/PI sandwich separators were prepared by electrospinning, pressing, and heat treatment, resulting in improved properties such as air permeability, porosity, and tensile strength. The use of polyimide as the sandwich improved flame retardant properties, while the PVDF-HFP intermediate layer ensured battery safety. Experimental results showed that the sandwich separator had higher discharge capacity.
POLYMER ENGINEERING AND SCIENCE
(2022)
Article
Energy & Fuels
J. P. Serra, J. C. Barbosa, M. M. Silva, R. Goncalves, J. Uranga, C. M. Costa, P. Guerrero, K. de la Caba, S. Lanceros-Mendez
Summary: In this study, wool and soy protein isolate (SPI) were used to develop separator membranes for lithium-ion batteries (LIBs), resulting in improved battery performance.
JOURNAL OF ENERGY STORAGE
(2024)
Article
Materials Science, Composites
Liying Wang, Yuhan Liu, Xinwei Du, Xiaohui Guo, Qi Zhao, Yuliang Wang, Zhangnan Li, Baijun Liu, Zhaoyan Sun, Yongfeng Men, Wei Hu
Summary: To overcome the limitations of polyethylene separator for lithium-ion batteries, a composite solution of poly(ether ketone) and carbon nanoparticles obtained from nanocellulose carbonization in sulfuric acid was used to modify the separator. The resulting Janus composite separator exhibited high thermal stability, excellent electrolyte loading rate, and improved battery performance. The introduction of carbon nanoparticles provided additional oxidation sites and enhanced ion conductivity, reducing charge transfer resistance.
COMPOSITES COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Mehdi Estili, Shoichi Matsuda, Lulu Jia, Nobuyuki Sakai, Renzhi Ma, Tohru S. Suzuki, Kohei Uosaki
Summary: The effectiveness of multiwalled carbon nanotubes (MWCNTs) in enhancing the suitability of MXenes for energy-related applications is explored. The control over the structure of MXene-based macrostructures by individually dispersed MWCNTs is investigated. The results show that the composition and surface structure of MXene films are significantly altered by the presence of MWCNTs. The stacking order of MXenes is preserved up to 30 wt% MWCNTs, but disrupted at 40 wt%. The membranes with MWCNTs exhibit improved Li-ion transport mechanisms and properties. A high rating of 8 is given for the importance of this research.
Article
Engineering, Environmental
Bin Qin, Yifei Cai, Xiaoqing Si, Chun Li, Jian Cao, Weidong Fei, Junlei Qi
Summary: The use of Mo2C@HGr modified separator enhances the rate performance and sulfur utilization of Li-S batteries, demonstrating favorable chemical adsorption capacity and abundant triple-phase interfaces.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Liying Yin, Zenglong Xu, Guangxu Yang, Fuhai Guo, Wenhui Guo, Songfang Zhao, Shuhua Yang
Summary: In this work, electrospun VO2/carbon fibers with a three-dimensional network structure were obtained and used as cathode materials for aqueous zinc-ion batteries. The carbon fiber network significantly improved the conductivity and stability of VO2, resulting in a higher specific capacity compared to pure VO2. Excellent capacity retention at high current density was also achieved.
Article
Chemistry, Multidisciplinary
Lien-Yang Chou, Yusheng Ye, Hiang Kwee Lee, Wenxiao Huang, Rong Xu, Xin Gao, Renjie Chen, Feng Wu, Chia-Kuang Tsung, Yi Cui
Summary: A feasible method has been developed to balance flame retardancy and electrochemical performance on commercial battery separators by coating an electrolyte-insoluble flame retardant. The composite separator showed four times better flame retardancy than conventional polyolefin separators in full pouch cells, and it can be easily fabricated on a large scale for industrial applications. High-energy-density batteries (2 Ah) assembled with the composite separator confirmed its enhanced safety through nail penetration tests.
Article
Chemistry, Multidisciplinary
Markus R. P. Pielmeier, Tom Nilges
Summary: Phosphorene and SnIP are two-dimensional and one-dimensional semiconductors formed from black phosphorus and SnI2, synthesized through mineralization and short way transport with similar yet different preparation methods. Investigating the formation mechanisms of these two compounds is of crucial importance for energy conversion, storage, and catalysis applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
David N. Purschke, Markus R. P. Pielmeier, Ebru Uezer, Claudia Ott, Charles Jensen, Annabelle Degg, Anna Vogel, Naaman Amer, Tom Nilges, Frank A. Hegmann
Summary: Time-resolved terahertz spectroscopy was used to study the transient photoconductivity of SnIP nanowire films and measure carrier mobility, revealing high electron mobility along the double-helix axis. Additionally, infrared-active THz vibrational modes were measured showing good agreement with first-principles calculations, and ultrafast photoexcitation-induced charge redistribution was observed on picosecond timescales. The findings suggest that SnIP could be well-suited for flexible electronics applications due to its high carrier mobility.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Inorganic & Nuclear
Andre Utrap, Markus R. P. Pielmeier, Tobias Lange, Torben Gaedt, Tom Nilges
Summary: Calcium silicates are the main components in cement clinkers, with Alite as the main phase represented by the island silicate Ca3SiO5. The structure of Alite is influenced by rapid cooling from high temperatures and the presence of impurities, resulting in the formation of various polymorphs.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2021)
Article
Chemistry, Inorganic & Nuclear
Patrick Walke, Anna Kirchberger, Felix Reiter, Daniel Esken, Tom Nilges
Summary: The study found that adding Al2O3 particles can significantly improve the ionic conductivity of polymer electrolyte membranes, while different preparation methods and additives can also affect the thermal and electrochemical properties of the membranes.
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
(2021)
Article
Chemistry, Inorganic & Nuclear
Felix Reiter, Markus Pielmeier, Anna Vogel, Christian Jandl, Milivoj Plodinec, Christian Rohner, Thomas Lunkenbein, Katharina Nisi, Alexander Holleitner, Tom Nilges
Summary: One-dimensional semiconductors are fascinating materials with unique structural features and anisotropy, leading to intriguing optical, dielectric, and mechanical properties. In this study, we report on SnBrP, a new member of the inorganic double helix compound family similar to SnIP. Through a combination of experimental measurements and quantum chemical calculations, we propose a structural model for SnBrP.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2022)
Article
Crystallography
Nataliya L. Gulay, Jutta Koesters, Yaroslav M. Kalychak, Samir F. Matar, Alfred Rabenbauer, Tom Nilges, Rainer Poettgen
Summary: CoIn2 is formed through reaction and annealing, exhibiting two different crystal structures and a structural phase transition caused by Peierls distortion. The compound features cobalt chains and slightly distorted cobalt/indium coordination.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS
(2022)
Article
Chemistry, Physical
Markus R. P. Pielmeier, Annabelle Degg, Kathrin Vosseler, Tom Nilges
Summary: A detailed density functional theory study was conducted on 1D-SnIP@2D-material hybrids. Different two-dimensional materials were tested as potential hosts for the flexible one-dimensional semiconductor SnIP. The study identified less-probable and most-probable hybrids and found a hybrid that allows the separation of the different enantiomeric forms of SnIP.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Anna Vogel, Alfred Rabenbauer, Philipp Deng, Ruben Steib, Thorben Boeger, Wolfgang G. Zeier, Renee Siegel, Juergen Senker, Dominik Daisenberger, Katharina Nisi, Alexander W. Holleitner, Janio Venturini, Tom Nilges
Summary: A diode requires the combination of p- and n-type semiconductors or certain doping levels to function. However, the discovery of pnp-switchable compounds like Ag10Te4Br3 opens up the possibility of fabricating diodes from a single material. Ag18Cu3Te11Cl3, as a room temperature pnp-switching material, is the first single-material position-independent diode.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Philipp Deng, Alfred Rabenbauer, Kathrin Vosseler, Janio Venturini, Tom Nilges
Summary: Pnp-switchable semiconductor materials can change their electronic properties through a temperature-dependent phase transition, enabling the construction of unconventional one-compound diodes. This study utilizes pnp-switchable AgCuS to create a functional one-compound diode, which demonstrates reversibility and flexibility for diode operation. The material's electrical, thermal, and diode properties are fully characterized, and its performance is discussed in relation to Ag18Cu3Te11Cl3, the first one-compound diode operating near room temperature.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Biotechnology & Applied Microbiology
Michael Paper, Max Koch, Patrick Jung, Michael Lakatos, Tom Nilges, Thomas B. Brueck
Summary: This study investigated the potential of 12 cyanobacterial strains for biosorption of rare earth elements, and Nostoc sp. 20.02 showed the highest adsorption capacity. Synechococcus elongatus UTEX 2973, Calothrix brevissima SAG 34.79, Desmonostoc muscorum 90.03, and Komarekiella sp. 89.12 were also promising strains. The adsorption of metals by the strains had fast kinetics and pH value had a significant impact on the process.
FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY
(2023)
Article
Engineering, Electrical & Electronic
Nasrin Sultana, Annabelle Degg, Kangkan Jyoti Goswami, Bedanta Gogoi, Tom Nilges, Neelotpal Sen Sarma
Summary: Among developed 2D materials, phosphorene is highly demanded for its unique electrical performance in biomedical applications. We successfully developed reduced phosphorene quantum dots (rPhQDs) using a hydrothermal technique, which can be used as an electrical bio-sensing platform to detect uric acid in aqueous media, human blood serum, and artificial urine. The composite materials of rPhQDs show selective current-voltage properties and can be used to fabricate electrical devices for specifically detecting uric acid in the linear range of 1-5 mu M. The detection limits for aqueous media, human blood serum, and artificial urine are 0.809, 0.5292, and 1.065 mu M, respectively. The improved ionic movement in the presence of analytes plays a prominent role in this selective electrical sensing.
ACS APPLIED ELECTRONIC MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Alfred Rabenbauer, Anna Vogel, Janio Venturini, Mahboubeh Moslemi, Oliver Oeckler, Dominik Daisenberger, Tom Nilges
Summary: Coinage metal chalcogenides, such as Cu1.5Se y Te1-y, have the potential for high thermoelectric performance and sensor applications due to their low thermal conductivity, high electrical conductivity, and small band gaps. The synthesized materials in this study, Cu1.5Se0.3Te0.7 and Cu1.5Se0.5Te0.5, exhibit a cubic crystal structure and narrow band gaps. They demonstrate positive Seebeck coefficients and low thermal conductivities, making them suitable for moderate temperature applications.
INORGANIC CHEMISTRY
(2023)
Article
Electrochemistry
Patrick Walke, Janio Venturini, Robert J. Spranger, Leo van Wuellen, Tom Nilges
Summary: In this study, a true solid polymer electrolyte system with high conductivity at room temperature and elevated temperatures was developed by electrospinning method. The electrospun polymer electrolyte membrane showed superior performance in magnesium ion transport and solid electrolyte interface formation. This research highlights the potential of electrospinning as a powerful tool to enhance the electrochemical properties of solid state batteries.
BATTERIES & SUPERCAPS
(2022)
Review
Materials Science, Multidisciplinary
Nasrin Sultana, Annabelle Degg, Samiran Upadhyaya, Tom Nilges, Neelotpal Sen Sarma
Summary: In recent years, there has been growing interest in new two-dimensional materials due to the increasing demand for functionalized materials in advanced electrical and biomedical applications. Among them, phosphorene has gained tremendous attention for its unique properties and potential applications, and research on synthesis and modifications has made progress.
MATERIALS ADVANCES
(2022)
Article
Chemistry, Physical
Markus R. P. Pielmeier, Annabelle Degg, Kathrin Vosseler, Tom Nilges
Summary: A detailed DFT study was conducted on 1D-SnIP@2D-material hybrids, exploring the potential of different 2D materials as hosts for the highly flexible semiconductor SnIP. Hybrid materials were classified based on total energy, matrix internal diameter, and bonding interactions, identifying less-probable and most-probable hybrids.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)