Article
Biochemistry & Molecular Biology
Valentina Stoppa, Edoardo Battistel, Marco Baron, Paolo Sgarbossa, Andrea Biffis, Gregorio Bottaro, Lidia Armelao, Cristina Tubaro
Summary: This article reports the synthesis of three novel dinuclear gold(I) complexes with luminescent properties, which can be used in various research fields such as bioinorganic chemistry, catalysis, and material science. These complexes can be easily synthesized through mechanochemistry by reacting pristine dibromido complexes with phenylacetylene and KOH.
Article
Chemistry, Multidisciplinary
Romane Manguin, Maria Galiana-Cameo, Tanakorn Kittikool, Cecile Barthes, Jompol Thongpaen, Etienne Bancal, Sonia Mallet-Ladeira, Sirilata Yotphan, Ricardo Castarlenas, Marc Mauduit, Jean-Baptiste Sortais, Olivier Basle
Summary: This article discusses the synthesis and characterization of a new series of iridium complexes with NHC-carboxylate ligands, which exhibit efficient catalytic activities in dehydrogenative directed C-H silylation of arenes, with excellent ortho-selectivity control.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Robert Richstein, Constantin Eisen, Lingcong Ge, Monnaya Chalermnon, Florian Mayer, Bernhard K. Keppler, Jia Min Chin, Michael R. Reithofer
Summary: The bottom-up synthesis of plasmonic NHC@CuNPs from common starting reagents, via the formation of the synthetically accessible NHC-Cu(I)-Br complex and its reduction by NH3·BH3 is reported. The resulting NHC@CuNPs have been characterized in detail by XPS, TEM and NMR spectroscopy. The stability of NHC@CuNPs was investigated under both inert and ambient conditions using UV-Vis analysis. While the NHC@CuNPs are stable under inert conditions for an extended period of time, the NPs oxidize under air to form CuxO with concomitant release of the stabilizing NHC ligand.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Ana P. C. Ribeiro, Ines A. S. Matias, Poorya Zargaran, A. Stephen K. Hashmi, Luisa M. D. R. S. Martins
Summary: The study successfully achieves the highly efficient and eco-friendly synthesis of acetic acid directly from ethane by using NHC and NHOC gold(I) catalysts under mild conditions. This method shows selectivity and promising prospects compared to other commonly used methods, with environmental advantages highlighted by green metrics measurements. Comparisons with previous catalysts emphasize the features of this remarkable protocol.
Review
Chemistry, Inorganic & Nuclear
Kevin Magra, Antonio Frances-Monerris, Cristina Cebrian, Antonio Monari, Stefan Haacke, Philippe C. Gros
Summary: Iron complexes show promise as sustainable molecular photoactive materials alternative to precious metals. This review focuses on recent research on bidentate Fe(II) complexes with N-heterocyclic carbene ligands, discussing their potential for energy conversion and photocatalysis applications, design strategies, and current challenges in the field.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Medina Afandiyeva, Abhishek A. Kadam, Xijue Wu, William W. Brennessel, C. Rose Kennedy
Summary: This paper describes a family of anionic, formally nickel(0) complexes supported by bidentate NHC-pyridone ligands. These complexes have an unsymmetric chelating environment and a capping [K(18-crown-6)]+ countercation, allowing for isolation of single-component, monometallic complexes in high yield. The steric and electronic properties are evaluated using experimental (NMR, IR, UV-vis, X-ray diffraction) and computational tools. Catalytic activity for highly branched-selective hydroboration of styrene with HBpin is demonstrated. Control experiments suggest that the pyridone plays an important role in establishing reactivity and regioselectivity, indicating the potential to utilize secondary coordination sphere effects for reagent activation and delivery with these single-component precatalysts.
Article
Chemistry, Multidisciplinary
J. L. S. Milani, A. F. P. Biajoli, F. I. Batista, R. S. Oliboni, O. L. Casagrande
Summary: A series of new Cr(III) complexes were successfully synthesized and showed moderate activity in ethylene oligomerization, with a uniform distribution of oligomers and polymer production ranging from 1.2% to 9.8%. The catalytic activity is mainly controlled by electronic effects at the thioether/imine groups.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Polymer Science
Zhen Dong, Wenjun Huang, Xiaoqing Liu, Feng Yu, Chuanjiang Long, Sitong Feng, Lang Luo, Zhong-Ren Chen
Summary: A poly(norbornene-graft-styrene) (PNB-g-PS) supported mono(phenoxy-imine) metal complex was developed for ethylene polymerization. The catalysts showed improved catalytic activities, with the highest activities of 369 and 461 kg PE mol(-1) h(-1) for Ti and Zr catalysts with cumyl group ligands. The obtained polyethylenes have high crystallinities and tunable molecular weights, while bimodal polyethylenes were successfully prepared by combining two different phenoxy-imine ligands in one pot.
Article
Chemistry, Inorganic & Nuclear
Piermaria Pinter, Johannes Soellner, Thomas Strassner
Summary: Platinum(II) complexes exhibit unique photophysical behavior due to their square-planar geometry. The photophysical properties of monometallic platinum(II) complexes are dependent on concentration, while those of bimetallic complexes are dependent on the distance between metal centers. This study reveals a correlation between the electronic and photophysical properties of monomeric monometallic platinum(II) complexes and their aggregates with corresponding bimetallic complexes.
Article
Optics
Guilherme L. dos Santos, Julia P. O. Silva, Gustavo Galleani, Marcos Colaco, Fabio F. Ferreira, Isadora T. S. Bastos, Monica S. Ferreira, Ricardo O. Freire, Lippy F. Marques
Summary: This study presents the synthesis, solid state characterization, and photoluminescence study of three new photoluminescent Eu3+ hydrocinnamate complexes containing different ancillary ligands. The photoluminescent properties are closely related to the molecular structures, suggesting potential for the development of new spectroscopic probes based on Eu3+ coordination compounds.
JOURNAL OF LUMINESCENCE
(2021)
Article
Chemistry, Multidisciplinary
Jessica R. Lamb, Christopher M. Brown, Jeremiah A. Johnson
Summary: N-Heterocyclic carbenes (NHCs) react with carbodiimides (CDIs) to form betaine adducts with tunable properties, whose stability depends on substituents on CDI nitrogens and configuration is influenced by NHC substituents. Despite being in the early stages, these adducts have been utilized as ligands for transition metals and nanoparticles, as connection points in zwitterionic polymers, and to stabilize distonic radical cations.
Article
Chemistry, Inorganic & Nuclear
Julio Corredoira-Vazquez, Cristina Gonzalez-Barreira, Matilde Fondo, Ana M. Garcia-Deibe, Jesus Sanmartin-Matalobos, Silvia Gomez-Coca, Eliseo Ruiz, Enrique Colacio
Summary: A new synthetic method has been developed to isolate a series of fluoride-bridged complexes, which exhibit interesting magnetic properties and provide theoretical insights into the structure-magnetism relationship for this type of compounds.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Aleksei O. Tolpygin, Anastasia A. Sachkova, Alexander D. Mikhailychev, Anatoly M. Ob'edkov, Tatyana A. Kovylina, Anton Cherkasov, Georgy K. Fukin, Alexander A. Trifonov
Summary: A series of coordination compounds were synthesized and demonstrated high catalytic activity and stability in catalyzing the polymerization of isoprene and 1-heptene.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Julio Corredoira-Vazquez, Cristina Gonzalez-Barreira, Matilde Fondo, Ana M. Garcia-Deibe, Jesus Sanmartin-Matalobos, Silvia Gomez-Coca, Eliseo Ruiz, Enrique Colacio
Summary: A new synthetic method has been developed to isolate dinuclear compounds with fluoride bridging, and the crystal structures and magnetic properties have been studied to explore the relationship between structure and properties.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Sandra Abi Fayssal, Timothee Naret, Vincent Huc, Julien Buendia, Cyril Martini, Emmanuelle Schulz
Summary: The scalable synthesis of Pd-NHC cinnamyl complexes supported on benzyloxycalix[8]arene is reported. These catalysts are highly active for Buchwald-Hartwig cross-coupling reactions, enabling the coupling of aryl chlorides and bromides with alkyl and aryl amines at low catalytic loadings. The supported complexes also produce attractive unsymmetrical triarylamines and can even facilitate the synthesis of unprecedented Pd-catalyzed C-H activation products. Through an easy to implement procedure, these characterized catalysts combine the best features of homogeneous and heterogeneous catalysis, achieving high efficiency and low Pd leaching levels.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Review
Chemistry, Inorganic & Nuclear
Mikhail A. Kinzhalov, Elena V. Grachova, Konstantin V. Luzyanin
Summary: This review examines the use of metal complexes featuring acyclic diaminocarbene ligands as powerful emitters in OLEDs and other electroluminescent technologies. It discusses the photophysical properties of these complexes in relation to the carbene ligand structure and metal characteristics, highlighting the advantages that they provide to transition-metal-based phosphors.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Biochemistry & Molecular Biology
Aleksandra Paderina, Alexey Melnikov, Sofia Slavova, Vladimir Sizov, Vladislav Gurzhiy, Stanislav Petrovskii, Maksim Luginin, Oleg Levin, Igor Koshevoy, Elena Grachova
Summary: This work demonstrates the significant effect of distant substituents on the physicochemical properties of [Cu(Xantphos)(N boolean AND N)](+) complexes. Three hybrid molecular systems with different peripheral ligands were produced, resulting in complex emission behaviors. The results provide insights for designing materials with controlled optoelectronic properties and producing hybrid systems based on Cu(I) complexes.
Article
Chemistry, Inorganic & Nuclear
Andrey Yu. Baranov, Sofia O. Slavova, Alexey S. Berezin, Stanislav K. Petrovskii, Denis G. Samsonenko, Irina Yu. Bagryanskaya, Vladimir P. Fedin, Elena V. Grachova, Alexander V. Artem
Summary: We report a family of polynuclear complexes with Au-centered Ag4 and Cu4 tetrahedral cores. The structures of the Au@M4 clusters were experimentally determined, revealing very weak intermolecular Au-M metallophilic interactions. These compounds exhibit modest luminescence lifetimes at ambient temperature, with emission type depending on the composition of the cluster core.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Aleksandra Paderina, Ruslan Ramazanov, Rashid Valiev, Christian Mueller, Elena Grachova
Summary: The manipulation of photophysical properties of molecular emitters can be achieved by modifying the close environment of the metal center with a heavier pnictogen atom effect. Replacing a nitrogen atom with a heavier phosphorus atom in isostructural molecular systems results in significant changes in photophysical parameters. Novel Cu(I) complexes based on phosphine and diimine ligands were synthesized, and their peculiar photophysical properties, dependent on the heavier pnictogen atom effect, were investigated.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Analytical
Anastasiia Surkova, Andrey Bogomolov, Aleksandra Paderina, Viktoria Khistiaeva, Ekaterina Boichenko, Elena Grachova, Dmitry Kirsanov
Summary: In this work, an optical multisensor system based on the luminescence of Nd(III) and Yb(III) complexes in the near-infrared (NIR) spectral region is proposed. The system is able to analyze milk samples for fat content determination and adulteration recognition. Samples are prepared by putting a drop of milk upon a thin glass covering powdered lanthanide complexes, which are excited by a UV LED. The acquired diffuse-reflectance spectra are analyzed using chemometric methods, achieving feasible regression and classification model performances.
Article
Chemistry, Inorganic & Nuclear
Mikhail A. A. Kinzhalov, Daniil M. M. Ivanov, Anastasia V. V. Shishkina, Anna A. A. Melekhova, Vitalii V. V. Suslonov, Antonio Frontera, Vadim Yu. Kukushkin, Nadezhda A. A. Bokach
Summary: Crystallization of [CuI(CNXyl)(3)] (1) with I-2 resulted in the formation of a series of (XylNC)Cu-I crystal polyiodides, along with the accumulation of iodine. The compounds [Cu(I-3)(CNXyl)(3)] (2(I) and 2(II)), [Cu(I-3)(CNXyl)(3)]center dot 1/2I(2) (2 center dot 1/2I(2)), and [Cu(CNXyl)(3)](I-5) (3) were studied by X-ray diffractometry. The presence of an I-2?I-3(-) halogen bonded linkage in the structure of 2 center dot 1/2I(2) provides insight into the mechanism for the generation of I-5(-) and I-8(2-) ligands from I-2 and metal-coordinated I-3(-).
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Stanislav Petrovskii, Aleksandra Paderina, Anastasia Sizova, Elena Grachova
Summary: A series of compounds P1-P4 with terminal alkynyl sites connected to a phosphonium group via different K-conjugated linkers have been synthesized. These compounds are efficient push-pull emitters and exhibit bright fluorescence in blue and near-UV regions. Using P1-P4 as alkynyl ligands, a series of homoleptic bis-alkynyl Au(I) complexes 1-4 were obtained. The complexes show bright phosphorescence and dual emission, with dominant phosphorescence in most cases.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Aleksandra Paderina, Sofia Slavova, Stanislav Petrovskii, Elena Grachova
Summary: A series of Pt(II) complexes with alkynylphosphonium and di-tert-butyl-2,2'-bipyridine (dtbpy) ligands were prepared and characterized. The complexes showed triplet emission in solution, which was controlled by the nature of the pi-conjugated linker in the alkynylphosphonium ligand. DFT calculations supported this conclusion and also showed that the complexes exhibited enhanced nonlinear optical properties and mechanochromic luminescence.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Stanislav K. K. Petrovskii, Marco Moors, Sebastian Schmitz, Elena V. V. Grachova, Kirill Yu. Monakhov
Summary: The covalent attachment of organogold(i) moieties to the Lindqvist-type polyoxovanadate leads to measurable charge redistribution across the formed Au-{V-6}-Au linkages. Scanning probe microscopy studies on the Au(111) surface demonstrate that the number of switching states increases with a gradual increase in molecular conductance compared to unfunctionalized hexavanadates.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Anastasia Yu. Gitlina, Viktoria Khistiaeva, Alexey Melnikov, Mariia Ivonina, Vladimir Sizov, Dar'ya Spiridonova, Anna Makarova, Denis Vyalikh, Elena Grachova
Summary: Two methods of post-synthetic modification (Suzuki coupling and CuAAC click-reaction) were applied to Ir(iii) complexes to introduce a highly selective donor site. The potential of post-synthetic modification for controlled construction of d-d and d-f binuclear complexes was demonstrated using functionalized complexes. Characterization techniques such as elemental analysis, NMR spectroscopy, mass spectrometry, FTIR spectroscopy, and X-ray diffraction analysis were used to analyze the obtained complexes. The coordination of the diimine donor site to the Ln(iii) center was confirmed through XPS and NEXAFS spectroscopy. The photophysical properties and luminescent characteristics of the complexes were investigated, and TDDFT calculations were used to explain the luminescence mechanism.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
S. A. Katkova, E. V. Sokolova, M. A. Kinzhalov
Summary: A series of platinum(II) cyclometallated complexes with two isocyanide ligands were synthesized and characterized. Their structure was determined by various spectroscopic techniques and their photophysical properties and mechanochromic luminescence behavior were studied in the solid state.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Svetlana A. Katkova, Daria O. Kozina, Kristina S. Kisel, Maria A. Sandzhieva, Dmitriy A. Tarvanen, Sergey V. Makarov, Vitaly V. Porsev, Sergey P. Tunik, Mikhail A. Kinzhalov
Summary: A series of cyclometalated platinum(ii) complexes with acyclic diaminocarbene (ADC) ancillary ligands were designed and synthesized. Their photophysical properties were investigated both experimentally and theoretically. The complexes showed green phosphorescence with high quantum efficiency of up to 45% in 2 wt% doped PMMA film at room temperature. These complexes were further utilized as light-emitting dopants for OLED fabrication. The resulting devices demonstrated green emission with a maximum current efficiency of 2.9 cd A(-1) and a luminance of 2700 cd m(-2), highlighting the potential of these cyclometalated platinum(ii) complexes as efficient green emitters for OLED devices.
DALTON TRANSACTIONS
(2023)
Article
Biochemistry & Molecular Biology
Maria V. Kashina, Andrei A. Karcheuski, Mikhail A. Kinzhalov, Konstantin V. Luzyanin, Svetlana A. Katkova
Summary: A series of platinum complexes with phosphine and isocyanide ligands were synthesized and evaluated as catalysts for photocatalytic hydrosilylation of alkynes. The phosphine-isocyanide complexes showed high yields under violet light irradiation, while the parent phosphine complexes were more efficient under blue light irradiation.
Article
Chemistry, Inorganic & Nuclear
Anastasia Yu. Gitlina, Stanislav Petrovskii, Maksim Luginin, Alexey Melnikov, Elena Rychagova, Sergey Ketkov, Elena Grachova
Summary: This study investigates a new series of luminescent cyclometalated complexes as "building blocks" for constructing a supramolecular network. The complexes exhibit non-covalent interactions in the crystal state, and their emission profiles are mainly determined by the nature of the C ligand, as revealed by DFT calculations.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Physical
Stanislav Petrovskii, Anna Senchukova, Vladimir Sizov, Aleksandra Paderina, Maksim Luginin, Evgenia Abramova, Elena Grachova
Summary: Two families of hetero- and homoleptic mononuclear Au(I) complexes with alkynyl ligands containing an azo or stilbene group have been synthesized and characterized by spectroscopic methods and single crystal XRD. The Au(I) complexes show photoswitching behavior under near-UV irradiation, and the quantum yield of trans->cis photoisomerization is comparable to that of native photoswitches. The alkynyl-carbene complex with a stilbene group exhibits a higher quantum yield and more impressive photochromic behavior. The change in ligand environment configuration due to photoswitching leads to the activation of triplet emission and luminescent visualization of the on-off process.
MOLECULAR SYSTEMS DESIGN & ENGINEERING
(2022)