期刊
INORGANIC CHEMISTRY
卷 56, 期 3, 页码 1023-1026出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b02165
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资金
- A*MIDEX (FUNCOPPER) [ANR-11-IDEX-0001-02]
We report here two copper complexes as first functional models for lytic polysaccharide monooxygenases, mononuclear copper-containing enzymes involved in recalcitrant polysaccharide breakdown. These complexes feature structural and spectroscopic properties similar to those of the enzyme. In addition, they catalyze oxidative cleavage of the model substrate p-nitrophenyl-beta-D-glucopyranoside. More importantly, a particularly stable copper(II) hydroperoxide intermediate is detected in the reaction conditions.
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