Article
Crystallography
Sabine Bottin-Rousseau, Mehdi Medjkoune, Oriane Senninger, Laurent Carroz, Richard Soucek, Ulrike Hecht, Silvere Akamatsu
Summary: The study investigated the directional solidification dynamics of slightly hypoeutectic Al-Al2Cu alloys in thin films, revealing new crystal orientation relationships and discussing lamellar growth dynamics and eutectic grain structures.
JOURNAL OF CRYSTAL GROWTH
(2021)
Article
Chemistry, Physical
Shulin Dong, Wei Wu, Ruirun Chen, Yingdong Qu, Jingjie Guo, Guanglong Li, Wei Zhang, Hengzhi Fu, Bo Yu
Summary: This study successfully improved the fracture toughness stability of CCDS TiAl-based alloys by adding (B,Y) refinement elements. The addition of (B,Y) compounds can inhibit grain growth, enhance fracture toughness, and provide more barriers against crack propagation.
Article
Crystallography
Satoshi Nakano, Xin Liu, Xue-Feng Han, Koichi Kakimoto
Summary: This study investigated the effect of evaporation flux on phosphorus concentration distribution in silicon crystal by numerical analysis, finding that controlling phosphorus evaporation flux can achieve a homogeneous phosphorus concentration distribution.
Article
Physics, Multidisciplinary
Eugenya V. Makoveeva, Alexander A. Ivanov, Irina V. Alexandrova, Dmitri V. Alexandrov
Summary: In this paper, a nonlinear theory of self-oscillatory solidification mode during directional crystallization in the presence of a quasi-equilibrium two-phase region of constitutional supercooling is developed. The study demonstrates that this mode can be formed due to the oscillatory instability at certain values of physical and operating parameters of the system, based on the linear stability theory. The development of oscillatory instability is explained using a new frontal model of crystallization with a two-phase region, where a discontinuity surface replaces the real two-phase region.
EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS
(2023)
Article
Engineering, Manufacturing
Yichao Zhu, Shangcheng Zhou, Zhiping Xiong, Yao-Jian Liang, Yunfei Xue, Lu Wang
Summary: This study presents a strategy for improving the strength and ductility of EHEAs by introducing directional eutectic cells with ultrafine two-phase lamellae. Experimental results show that compared with traditional alloys, a strength increment of about 60% is achieved without a loss in ductility when tensile loading is applied parallel to the 3D-printed directional lamellae of the EHEAs.
ADDITIVE MANUFACTURING
(2021)
Article
Metallurgy & Metallurgical Engineering
Jie Zhang, Jing Li, Cheng-bin Shi
Summary: The study investigated the impact of melting rate on various parameters during the electroslag remelting process, showing that the proper melting rate can lead to better temperature distribution and liquid metal molten pool morphology. For a mold with a diameter of 160 mm, a melting rate of 98 kg/h may be suitable for the process.
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Shaodong Hu, Long Hou, Kang Wang, Zhongmiao Liao, Wen Zhu, Aihua Yi, Wenfang Li, Yves Fautrelle, Xi Li
Summary: Research indicates that thermoelectric magnetic convection (TEMC) under transverse static magnetic field leads to solute enrichment on one side of the sample, affecting primary dendrite arm spacing and freckle formation. The impact intensifies with an increase in magnetic field strength.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Peng Peng, Li Lu, Wanchao Zheng, Jiatai Wang, Shudong Zhou
Summary: Peritectic alloys have attracted attention for their applications and freckle formation during directional solidification. The dendritic morphology is influenced by the Gibbs-Thomson and temperature gradient zone melting effects, with a proposed Rayleigh number predicting freckle formation. Unsteady growth conditions also affect freckle formation, predicted successfully by the Rayleigh number.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Physics, Multidisciplinary
Eugenya V. Makoveeva, Dmitri V. Alexandrov
Summary: A linear theory of morphological stability of flat crystallization front is proposed, taking into account convective motions in liquid. The effects of slow and intense convection on heat and mass transfer are considered. Dispersion relations are derived that define the perturbation frequency as a function of wavenumber and other process parameters. The neutral stability curve in the case of slow convection depends on the extension rate at the phase interface, dividing the domains of morphological instability and stability. In the case of intense convection, the dispersion relation shows that small morphological perturbations decay with time, indicating absolute stability of the crystallization process.
EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS
(2023)
Article
Materials Science, Multidisciplinary
Paul Martin, Gildas Guillemot, Christopher A. Hareland, Peter W. Voorhees, Charles-Andre Gandin
Summary: A generalized model for the kinetics of a dendrite tip with a non-equilibrium interface is proposed for multicomponent alloys. The model takes into account the full coupling with thermodynamic databases to consider the effects of non-dilute non-ideal solutions, as well as a full diffusion matrix in the liquid phase. The study reveals substantial deviations from existing theories in the dendrite tip kinetics, especially in the absence of solute drag.
Article
Chemistry, Physical
Xuefeng Zhu, Zhu Xiao, Junhong An, Hongyun Jiang, Yanbin Jiang, Zhou Li
Summary: A Phi 40 mu m Cu-4 wt%Ag alloy wire with high strength and high electrical conductivity was prepared by continuously directional solidification and cold drawing. The study investigated the evolution of microstructure and properties, revealing the main deformation mechanisms and strengthening mechanism of the alloy during different stages of the drawing process.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Jinge Yan, Tie Liu, Mengmeng Wang, Jinmei Sun, Shulin Dong, Lijia Zhao, Qiang Wang
Summary: Directional solidification experiments of eutectic Al-Fe alloys were conducted under different high magnetic field gradients. The study found that high magnetic field gradient changed the microstructure selection during solidification process, leading to different solidification structures. A solidification model of eutectic alloy under high magnetic field gradient was proposed, and the microstructure selection map of Al-Fe alloy under gradient magnetic field was qualitatively drawn for the first time. These findings have significant implications for controlling the structure and properties of alloys.
MATERIALS CHARACTERIZATION
(2022)
Article
Materials Science, Multidisciplinary
Lili Tian, Yinli Peng, Xing He, Yang Bai, Xiaowei Lei, Nan Wang
Summary: This study unraveled the onset mechanism of irregular eutectic growth by studying the morphology transitions in a transparent eutectic system. The results showed that a decoupled interface gradually appeared from an original coupled interface after the specimen was exposed in a thermal gradient, leading to the growth of two types of seeds under an exerted pulling rate. The findings provide new insights into the solidification dynamics of irregular eutectic systems.
Article
Environmental Sciences
Fenghui Wu, Bangjin Chen, Guangfei Qu, Shan Liu, Chenyang Zhao, Yuanchaun Ren, Xinxin Liu
Summary: This paper introduces a highly targeted solidification and stabilization technology that effectively solidifies and stabilizes the toxic and hazardous components in phosphogypsum. The experimental results demonstrate excellent solidification and stabilization effect, meeting the requirements of relevant international standards.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2022)
Article
Computer Science, Artificial Intelligence
Jiafeng Xu, Xin Chen, Weihua Cao, Min Wu
Summary: This paper introduces a novel multi-objective optimization algorithm (BCCO) for trajectory planning in the drilling process. By employing a bi-directional constrained co-evolutionary mechanism and a series of optimization measures, BCCO is capable of effectively handling diverse constraints and demonstrates strong convergence and diversity in real-world engineering problems.
EXPERT SYSTEMS WITH APPLICATIONS
(2024)
Article
Mathematics, Applied
Ferran Brosa Planella, Colin P. Please, Robert A. Van Gorder
Summary: The research on the extended Stefan problem identifies distinct spatio-temporal regimes and intricate boundary layer structures in the solidification process, considering all time regimes and accounting for impurities and constitutional supercooling.Comparing asymptotic solutions with numerical simulations and real experimental data highlights the role of supercooling in the solidification of binary alloys in various applications.
EUROPEAN JOURNAL OF APPLIED MATHEMATICS
(2021)
Article
Mathematics, Applied
C. M. Rooney, C. P. Please, S. D. Howison
Summary: Heat transport in granular and porous media occurs through conduction in the solid and radiation through the voids. By utilizing the method of multiple scales, effective conductivity can be found for systems with both radiation and conduction. Care must be taken to handle the integral nature of the radiative boundary condition, and modifications to the basic theory of multiple scales are necessary to address the non-local nature of the radiative boundary condition. Multiple scales formulation of the problem is derived and compared numerically with the direct solution, as well as with models derived from Maxwell models and effective medium theory.
EUROPEAN JOURNAL OF APPLIED MATHEMATICS
(2021)
Article
Electrochemistry
Ferran Brosa Planella, Muhammad Sheikh, W. Dhammika Widanage
Summary: This work discusses the concept of SPM-type models, showing that despite multiple formulations found in the literature, these models always follow the same structure, and extends this discussion to models accounting for thermal effects. The proposed Thermal Single Particle Model with electrolyte (TSPMe), derived systematically using asymptotic techniques, shows very high accuracy in validation against a thermal DFN model with significantly lower computational cost. The comparison against experimental data demonstrates that the model can reasonably predict the behavior of a real battery, but requires a very good parameter set for accurate predictions.
ELECTROCHIMICA ACTA
(2021)
Article
Mathematics, Applied
Ellen K. Luckins, James M. Oliver, Colin P. Please, Benjamin M. Sloman, Robert A. Van Gorder
Summary: This paper investigates the silicon production process in submerged arc furnaces. A model is developed that couples electrical current, thermal, material flow, and chemical processes in the furnace. The model is homogenized over the timescale of the alternating current, resulting in averaged equations for the system's slow evolution. Numerical simulations reveal the minimum applied current required for steady-state solutions and the existence of two spatially heterogeneous steady states with distinct crater sizes. The results demonstrate that stoking furnaces increases material consumption rate and improves silicon production efficiency.
EUROPEAN JOURNAL OF APPLIED MATHEMATICS
(2022)
Article
Electrochemistry
Toby L. Kirk, Colin P. Please, S. Jon Chapman
Summary: In this study, a Many-Particle-DFN (MP-DFN) model is used to provide a physical explanation for the slow relaxation phenomenon in lithium-ion batteries. By optimizing size distribution parameters and solid-state diffusivities, the MP-DFN model accurately reproduces the slow relaxation across different C-rates, highlighting the impact of internal heterogeneities on battery behavior. The model allows for a single set of physical parameters to capture voltage after relaxation, marking a departure from previous studies and offering insights into battery performance.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Mathematics, Applied
G. W. Richardson, J. M. Foster, R. Ranom, C. P. Please, A. M. Ramos
Summary: This paper presents the current state of mathematical modelling of the electrochemical behaviour of lithium-ion batteries (LIBs) during charging and discharging processes. Various models developed by Newman and co-workers are reviewed, with attention to modelling assumptions and interface conditions between electrolytes and electrode materials. Different measures of electric potential are considered to reveal the differences between models, and upscaling to cell scale using homogenisation techniques is discussed. Illustrative results for a common device are also computed based on numerical solutions.
EUROPEAN JOURNAL OF APPLIED MATHEMATICS
(2022)
Editorial Material
Chemistry, Physical
Aashutosh Mistry, Ankit Verma, Shashank Sripad, Rebecca Ciez, Valentin Sulzer, Ferran Brosa Planella, Robert Timms, Yumin Zhang, Rachel Kurchin, Philipp Dechent, Weihan Li, Samuel Greenbank, Zeeshan Ahmad, Dilip Krishnamurthy, Alexis M. Fenton, Kevin Tenny, Prehit Patel, Daniel Juarez Robles, Paul Gasper, Andrew Colclasure, Artem Baskin, Corinne D. Scown, Venkat R. Subramanian, Edwin Khoo, Srikanth Allu, David Howey, Steven DeCaluwe, Scott A. Roberts, Venkatasubramanian Viswanathan
ACS ENERGY LETTERS
(2021)
Review
Electrochemistry
Peter M. Attia, Alexander Bills, Ferran Brosa Planella, Philipp Dechent, Goncalo dos Reis, Matthieu Dubarry, Paul Gasper, Richard Gilchrist, Samuel Greenbank, David Howey, Ouyang Liu, Edwin Khoo, Yuliya Preger, Abhishek Soni, Shashank Sripad, Anna G. Stefanopoulou, Valentin Sulzer
Summary: This article reviews the phenomenon of "knees" in the aging trajectories of lithium-ion batteries and discusses their pathways, key design and usage sensitivities, as well as the challenges and opportunities for knee modeling and prediction.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Article
Electrochemistry
Kieran O'Regan, Ferran Brosa Planella, W. Dhammika Widanage, Emma Kendrick
Summary: In order to accurately predict the lifetime of commercial cells, multi-physics models can be used. This study measured the thermal properties and variability of transport and thermodynamic properties in a high energy 21700 cylindrical cell, and used these parameters to test a model against experimental data. The results showed improved model fit when considering the parameter dependency on state-of-charge and temperature.
ELECTROCHIMICA ACTA
(2022)
Article
Engineering, Multidisciplinary
Ferran Brosa Planella, W. Dhammika Widanage
Summary: Battery degradation is a major obstacle to the widespread use of lithium-ion batteries. In this article, a reduced model is introduced that is simple, accurate, and suitable for most practical applications. The model can be extended to account for additional degradation effects.
APPLIED MATHEMATICAL MODELLING
(2023)
Proceedings Paper
Energy & Fuels
Malgorzata E. Wojtala, Ferran Brosa Planella, Alana A. Zulke, Harry E. Hoster, David A. Howey
Summary: This study investigates battery ageing by analyzing voltage differentials and using inverse modeling to estimate changes in electrochemical parameters. The results show that both cycle-aged and calendar-aged batteries experience changes in diffusion time and kinetic overpotential, with cycle-aged batteries also generating 50% more irreversible heat.
2022 IEEE VEHICLE POWER AND PROPULSION CONFERENCE (VPPC)
(2022)
Review
Energy & Fuels
F. Brosa Planella, W. Ai, A. M. Boyce, A. Ghosh, I Korotkin, S. Sahu, V Sulzer, R. Timms, T. G. Tranter, M. Zyskin, S. J. Cooper, J. S. Edge, J. M. Foster, M. Marinescu, B. Wu, G. Richardson
Summary: Physics-based electrochemical battery models are powerful tools for understanding and improving lithium-ion batteries. Different applications require different model complexities. Although simplified models are often independently proposed, they can actually be derived from more complex models. In this review, a reductive framework is showcased and the advantages and shortcomings of each model are discussed. Possible model extensions, particularly thermal models, are also presented.
PROGRESS IN ENERGY
(2022)
Review
Energy & Fuels
A. A. Wang, S. E. J. O'Kane, F. Brosa Planella, J. Le Houx, K. O'Regan, M. Zyskin, J. Edge, C. W. Monroe, S. J. Cooper, D. A. Howey, E. Kendrick, J. M. Foster
Summary: The article critically reviews the methods for measuring or inferring parameters within the isothermal DFN framework for lithium-ion batteries, and provides a searchable database of parameters for the standard DFN model. It discusses the advantages, disadvantages, and limitations of these methods.
PROGRESS IN ENERGY
(2022)
Article
Mathematics, Applied
Robert Timms, Scott G. Marquis, Valentin Sulzer, Colin P. Please, S. Jonathan Chapman
Summary: A three-dimensional model of a single-layer lithium-ion pouch cell was proposed in this study. Asymptotic analysis was used to reveal important characteristics of the model, simplifying computational complexity by coupling one-dimensional models with two-dimensional problems. This approach offers insights into the electrochemical and thermal behavior of lithium-ion pouch cells.
SIAM JOURNAL ON APPLIED MATHEMATICS
(2021)