Article
Chemistry, Multidisciplinary
Chang-Qiu Guo, Chuan-Jun Lu, Li-Wen Zhan, Peng Zhang, Qi Xu, Jia Feng, Ren-Rong Liu
Summary: This study reports a new catalyst that successfully catalyzes the enantioselective coupling reaction between quinone esters and anilines, resulting in the formation of N-aryl quinone atropisomers with a unique intramolecular hydrogen bond. This method has the potential to be used for the synthesis of structurally diverse secondary amine atropisomers.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Maxim K. Rabchinskii, Svyatoslav D. Saveliev, Dina Yu. Stolyarova, Maria Brzhezinskaya, Demid A. Kirilenko, Marina Baidakova, Sergei A. Ryzhkov, Vladimir V. Shnitov, Victor V. Sysoev, Pavel N. Brunkov
Summary: This study demonstrates the modulation of N species by tailoring the functionalization and atomic structure of graphene derivatives prior to chemical N-doping. Thermal annealing at moderate temperatures was shown to readjust the composition of N-species in graphene derivatives regardless of their chemistry, nanostructure, and the initial distribution of the N-species. The oxidation of the graphene layer governs the manifestation of pi* resonances and configuration of sigma* resonance.
Article
Chemistry, Multidisciplinary
Laura M. E. Wilson, Kari Rissanen, Jas S. Ward
Summary: A series of iodine(i) complexes, both known and new, were synthesized to investigate the influence of Lewis bases and anions on iodination reactivity. The iodination capability of the iodine(i) species was tested and compared using a screening protocol based on the iodination of antipyrine. The results showed that both the identity of Lewis bases and anions affect the iodination capability, and less efficient reagents can still deliver comparable percentage conversions with longer reaction times.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Physics, Multidisciplinary
Can B. Uzundal, Sasawat Jamnuch, Emma Berger, Clarisse Woodahl, Paul Manset, Yasuyuki Hirata, Toshihide Sumi, Angelique Amado, Hisazumi Akai, Yuya Kubota, Shigeki Owada, Kensuke Tono, Makina Yabashi, John W. Freeland, Craig P. Schwartz, Walter S. Drisdell, Iwao Matsuda, Tod A. Pascal, Alfred Zong, Michael Zuerch
Summary: Second harmonic generation (SHG) spectroscopy is commonly used to investigate surface chemistry, interfacial chemistry, and symmetry properties in solids, but the complexity of novel materials makes interpretation of experiments difficult. Polarization-resolved extreme ultraviolet (XUV-SHG) spectroscopy demonstrates element-specific angular anisotropy investigations for the first time, paving the way for future angle and time-resolved XUV-SHG studies with elemental specificity in condensed matter systems.
PHYSICAL REVIEW LETTERS
(2021)
Article
Multidisciplinary Sciences
J. Niskanen, A. Vladyka, J. Niemi, C. J. Sahle
Summary: In this study, we explore the sensitivity of several core-level spectroscopic methods to the atomistic structure using water molecule as a test system. We define a metric to measure the magnitude of spectral change as a function of structure, which enables us to identify structural regions with high spectral sensitivity. By employing machine-learning emulator-based decomposition of structural parameter space, we are able to recover more spectral variance and identify spectroscopically dominant degrees of freedom.
ROYAL SOCIETY OPEN SCIENCE
(2022)
Article
Chemistry, Organic
Jinglan Lei, Min Li, Qingqing Zhang, Shuyang Liu, Haifang Li, Lei Shi, Wen-Feng Jiang, Chunying Duan, Yunhe Jin
Summary: We report a convenient and manipulable synthesis of methylenebisamide derivatives through visible-light-driven radical cascade reactions incorporating C(sp3)-H activation and C-N/ N-O cleavage. Mechanistic studies reveal the involvement of both a traditional Ir-catalyzed photoredox pathway and a novel copper-induced complex-photolysis pathway, enabling the activation of inert N-methoxyamides and the synthesis of valuable bisamides. This approach offers many advantages, including mild reaction conditions, broad scope and functional group tolerance, and competitive step economy. With its mechanistic plenitude and operational simplicity, we believe this method paves a promising way for the synthesis of valuable nitrogen-containing molecules.
Article
Chemistry, Inorganic & Nuclear
Jaspreet S. Dhau, Avtar Singh, Paula Brandao, Vitor Felix
Summary: A new methodology for synthesizing bis[3-(4-chloro-N,N-diethylpyridine-2-carboxamide)] diselenide has been successfully achieved, characterized by various spectroscopic techniques and X-ray diffraction analysis. The compound showed antibacterial activity, with comparisons made to other pyridylselenium compounds and the standard drug Ampicillin.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Hao Wang, Walther Caminati, Meng Li, Junhua Chen, Xiao Tian, Jens-Uwe Grabow, Qian Gou
Summary: This study uses high-resolution rotational spectroscopy to observe and characterize two isomers of the acrolein dimer. The first isomer is stabilized by hydrogen bonds and has a planar configuration, while the second isomer exhibits unique interactions and tunneling motion.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Physical
Hao Wang, Walther Caminati, Meng Li, Junhua Chen, Xiao Tian, Jens-Uwe Grabow, Qian Gou
Summary: In this study, two isomers of acrolein dimer were observed and characterized using high-resolution rotational spectroscopy in pulsed jets. The first isomer, stabilized by two hydrogen bonds, exhibits a planar configuration and is energetically favored over the second isomer. Surprisingly, the study reveals that the second isomer, with a dominant n -> pi* interaction, enables a concerted tunneling motion along the carbonyl group. This motion leads to the inversion of transient chirality associated with the exchange of donor-acceptor roles.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Astronomy & Astrophysics
Prakash Tripathi, Gulab Chand Dewangan, I. E. Papadakis, K. P. Singh
Summary: The simultaneous UV/X-ray observations of IC 4329A by AstroSat reveal large-amplitude UV variability and provide insights into the X-ray spectral variability, showing a soft X-ray excess component and a steepening power law with increasing X-ray flux. The UV emission acts as primary seed photons for the hot corona, which produces the broadband X-ray continuum, while the X-ray spectral variability is well described by the cooling of the corona with increasing UV flux.
ASTROPHYSICAL JOURNAL
(2021)
Article
Materials Science, Multidisciplinary
Christoph Emeis, Sanjoy Kr Mahatha, Sebastian Rohlf, Kai Rossnagel, Fabio Caruso
Summary: This study combines ab initio calculations and ARPES to investigate the electron-plasmon interaction in highly doped semiconducting 1T-HfS2. Experimental results reveal the emergence of satellite spectral features near quasiparticle excitations, indicating coupling to bosonic excitations. First-principles calculations demonstrate that these features can be attributed to electronic coupling to carrier plasmons. Additionally, reduced screening at the surface enhances the electron-plasmon interaction and leads to the formation of plasmonic polarons.
Article
Chemistry, Physical
Hannah van Dyk, Frederick Jacobus Francois Jacobs, Robin Edward Kroon, Tshepiso Jan Makhafola, Alice Brink
Summary: Seven salicylidene base compounds were synthesized and characterized. They were tested for fluorescence and bioactivity. Compound 2 exhibited anticancer activity against MCF-7 and HepG2 cells, while compound 7 showed anticancer activity against HeLa and A549 cells. Compounds 4 and 5 demonstrated anticancer activity against MCF-7 cells. None of the compounds showed antibacterial activity.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Multidisciplinary
Surendar Karwasara, Leonard R. Maurer, Benjamin Peerless, Gregor Schnakenburg, Ujjal Das, Alexander C. Filippou
Summary: Experimental and theoretical studies were reported for a N-heterocyclic carbene-supported two-coordinated silicon-0-isocyanide compound, synthesized through a Si atom economic two-step method, showcasing unique structural features and dynamics.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
S. Ponnuswamy, P. Chandrika, S. Abdul Basheer, A. Akila, G. Usha
Summary: A new series of N-chloroacetyl-2,6-diphenylpiperidines 13-18 were synthesized from piperidines 7-12. Compound 14 was characterized by multiple techniques, while compounds 13-16 & 18 were characterized using specific spectroscopic techniques. NMR data revealed distinct conformations for the compounds, with compound 17 preferring alternate chair conformation and the others preferring boat conformation. The crystal structure of compound 16 supported its distorted boat conformation. Compounds 15 & 16 showed superior antibacterial activity, while all synthesized compounds displayed promising antioxidant activity compared to a standard antioxidant.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Saadat Hajari, Hassan Keypour, Mohammad Taher Rezaei, Seyed Hamed Moazzami Farida, Robert William Gable
Summary: In this study, 15-membered-ring symmetrical pentaaza macrocyclic Schiff base complexes were prepared using a template approach, and characterized using various techniques. The complexes showed strong antioxidant activity and moderate bactericidal activity, as well as significant cytotoxicity against breast and lung adenocarcinoma cells. Comparatively, [ZnLBr]ClO4 exhibited greater cytotoxic effect against the tested cells.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Engineering, Multidisciplinary
Sayed Zia Mohammadi, Hadi Beitollahi, Massoud Kaykhaii, Nosrat Mohammadizadeh, Somayeh Tajik, Rahman Hosseinzadeh
Article
Chemistry, Organic
Rahman Hosseinzadeh, Mohammad Mavvaji, Mahmood Tajbakhsh, Zahra Lasemi, Nora Aghili
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL
(2020)
Article
Chemistry, Organic
Rahman Hosseinzadeh, Fatemeh Fathalipour, Mahmood Tajbakhsh, Mohammad Mavvaji, Mona Pooryousef
Summary: In this study, a mild and efficient one-pot synthesis of 1,4,5-trisubstituted 1,2,3-triazoles via a three-component reaction under ball-milling conditions was reported. The optimized reaction conditions yielded a wide variety of derivatives in high yields, offering advantages such as high product yields, short reaction time, and simple work-up procedure.
POLYCYCLIC AROMATIC COMPOUNDS
(2022)
Article
Biochemical Research Methods
Mahshid Hamzehloueian, Rahman Hosseinzadeh, Setayesh Ghandiyar
JOURNAL OF MOLECULAR GRAPHICS & MODELLING
(2020)
Article
Spectroscopy
Mohammad Nemati, Rahman Hosseinzadeh, Maryam Mohadjerani
Summary: A new colorimetric and fluorescent chemosensor based on calix[4]arene with sulfonamide-fluorenone subunits shows remarkable color change and fluorescence quenching in the presence of fluoride anion. The binding property with F- was studied using various spectroscopic techniques, and this design with functional group attached to upper rim of calix[4]arene platform offers a new approach for the development of F- chemosensor.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Physical
Hannaneh Rahimi, Rahman Hosseinzadeh, Mahmood Tajbakhsh
Summary: The newly synthesized fluorene/pyridine-2,6-dicarboxamide sensor showed desirable selectivity and significant sensitivity for detecting Cu2+ and Pb2+ ions, with promising application prospects.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Somayeh Tajik, Hadi Beitollahi, Rahman Hosseinzadeh, Abbas Aghaei Afshar, Rajender S. Varma, Ho Won Jang, Mohammadreza Shokouhimehr
Summary: The study successfully demonstrated the electrocatalytic detection of hydrazine by modifying a carbon paste electrode with ferrocene-derivative, ionic liquid, and CoS2-carbon nanotube nanocomposite, resulting in a sensor with excellent sensitivity and a low detection limit. Additionally, the sensor exhibited good reproducibility, stability, and selectivity.
Article
Chemistry, Organic
Rahman Hosseinzadeh, Erfan Narimani, Mohammad Mavvaji
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL
(2021)
Article
Chemistry, Organic
Ghazaleh Zarrinzadeh, Mahmood Tajbakhsh, Rahman Hosseinzadeh, Mohammad A. Khalilzadeh, Masoumeh Hosseinzadeh
Summary: In this study, the binding affinities and interaction modes between Euparin derivatives and N-myristoyltransferase enzyme were evaluated through molecular docking studies. Compounds 1-3 exhibited significant hydrophobic and hydrogen bonding interactions with important residues at the active site of the receptor. Among them, compound 1 showed the highest antifungal activity, compound 2 displayed cytotoxicity against a cancer cell line, and compound 3 exhibited strong growth inhibition against a bacterial strain.
POLYCYCLIC AROMATIC COMPOUNDS
(2023)
Article
Chemistry, Inorganic & Nuclear
Rahman Hosseinzadeh, Nora Aghili, Mohammad Mavvaji
Summary: Functionalized nanocellulose was used to prepare a heterogeneous copper catalyst, which showed remarkable catalytic efficiency in C-O and C-N cross-coupling reactions. The catalyst could be easily recovered and reused multiple times without significant loss of catalytic activity.
Article
Chemistry, Multidisciplinary
Sahar Peiman, Robabeh Baharfar, Rahman Hosseinzadeh
Summary: In this paper, a nanocatalyst (Fe3O4@SiO2@DNHCS-Tr@CuI) containing PAMAM dendrimer and trypsin enzyme supported on magnetic nanosilica with immobilized CuI NPs was prepared. The nanocatalyst was characterized using various techniques and showed highly efficient catalytic activity for the synthesis of propargylamines in green conditions, with high yields, short reaction times and easy separation and recovery of the catalyst for further use.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Correction
Spectroscopy
Mohammad Nemati, Rahman Hosseinzadeh, Maryam Mohadjerani
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Chemistry, Physical
Maryam Abaszadeh, Rahman Hosseinzadeh, Mahmood Tajbakhsh, Shahram Ghasemi
Summary: Magnetic graphene oxide (MGO) was functionalized with 5-amino-1,10-phenanthroline (APhen) to obtain MGO@APhen. The results showed that MGO@APhen acts as an efficient heterogeneous catalyst in the C-N coupling reaction of aryl halides with amides and N-heterocycles in the presence of CuI. Additionally, MGO@APhen demonstrated excellent performance in the adsorption of heavy metal ions.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Inorganic & Nuclear
Ehsan Roustaie, Mahmood Tajbakhsh, Rahman Hosseinzadeh
Summary: Zinc oxide was supported on the surface of ZSM-5 zeolite using the extract of Convolvulus persicus to create a stable nanocatalyst, ZnO/ZSM-5. The catalyst exhibited good catalytic behavior in the Biginelli reaction, producing high yields of products and allowing for easy recovery and reusability.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2023)
Article
Electrochemistry
Sayed Zia Mohammadi, Hadi Beitollahi, Maryam Askari, Rahman Hosseinzadeh
Summary: The study successfully synthesized 2FTNE as a mediator and CMNP as a nanoparticle for constructing a modified CPE, which exhibited high electro-catalytic activity towards NEP oxidation. The 2FTNECMNP-modified CPE showed high selectivity, proper stability and suitable reproducibility in accurately measuring NEP, AC and TRP in various samples.
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
(2021)