期刊
CRYSTENGCOMM
卷 17, 期 8, 页码 1800-1804出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce02367f
关键词
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资金
- National Natural Science Foundation of China [21171035, 51302035, 51472049]
- Key Grant Project of Chinese Ministry of Education [313015]
- PhD Programs Foundation of the Ministry of Education of China [20110075110008, 20130075120001]
- National 863 Program of China [2013AA031903]
- Science and Technology Commission of Shanghai Municipality [13ZR1451200]
- Fundamental Research Funds for the Central Universities
- Program Innovative Research Team in University [IRT1221]
- Hong Kong Scholars Program
- Shanghai Leading Academic Discipline Project [B603]
- Program of Introducing Talents of Discipline to Universities [111-2-04]
3D array nanostructures assembled from 0D nanoparticles, 1D nanorods, nanowires, nanotubes, and 2D nanosheets on specific substrates are an important class of architecture in nanomaterials application. SnO2 nanostructure arrays on different types of heterogeneous substrates have been reported. Here, we provide a self-supporting 3D hierarchical SnO2 nanorods array on homogeneous substrate by a one-step solvothermal route with the help of an anionic surfactant. By investigating the morphology of products using different reaction conditions, the formation mechanism of the structure is proposed. The self-supporting SnO2 nanorods array is applied as a gas sensor to a series of harmful gases. It exhibited a high response (S-r = 22.69) to ethanol gas at a low concentration of 50 ppm at 260 degrees C. Its unique structure with a large surface area and interval space accounts for its good performance in gas sensing.
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