期刊
CRYSTENGCOMM
卷 17, 期 31, 页码 5947-5952出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce00953g
关键词
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资金
- NSFC [21201110]
- Research Award Fund for Outstanding Middle-aged and Young Scientist of Shandong Province [BS2013CL010]
- International Scientific and Technological Cooperation Projects of Shanxi Province [2015081043]
- 131 Leading Talents Project in Colleges and Universities, Science and Technology Innovation Project of Shanxi Province [2014101002]
A novel polyoxometalate (POM) hybrid material based on a Keggin polyanion and silver(I)-organic sheet, namely, [Ag-4(apym)(4)(SiW12O40)](n) (1), where apym = 2-aminopyrimidine, has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, thermal gravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. In the structure of 1, polyanions link 2D 3-connected 4.8(2)-fes Ag-I-organic sheets to generate a 3D complicated framework. Moreover, the catalytic performance of 1 towards the cyanosilylation of carbonyl compounds has been tested under mild conditions, showing a high turnover number and turnover frequency.
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