期刊
GREEN CHEMISTRY
卷 19, 期 15, 页码 3558-3565出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc01391d
关键词
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资金
- National Natural Science Foundation of China [21373234, 21533011]
- National Key Research and Development Program of China [2017YFA0403102]
- Chinese Academy of Sciences [QYZDY-SSW-SLH013]
Acetic acid is an important bulk chemical and synthesis of acetic acid via methanol hydrocarboxylation with CO2 and H-2 is a very promising route. In this work, we studied the reaction over a number of catalytic systems. It was found that Rh-2(CO)(4)Cl-2 with 4-methylimidazole (4-MI) as the ligand was very efficient in the presence of LiCl and LiI. Acetic acid began to form at 150 degrees C. The TOF was as high as 26.2 h(-1) and the yield of acetic acid could reach 81.8% at 180 degrees C. The catalytic system had obvious advantages, such as simplicity, high activity and selectivity, milder reaction conditions, and less corrosiveness. The excellent cooperation of CO and Cl-in Rh-2(CO)(4)Cl-2, suitable basicity and aromaticity of the ligand 4-MI, and the hydrogen bonding ability of Cl-were crucial for the outstanding performance of the catalytic system. The control experiments showed that the reaction did not proceed via the CO pathway.
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