A unified strategy for silver-, base-, and oxidant-free direct arylation of C–H bonds

Visible Light Mediated Photoredox Catalytic Arylation Reactions

(2016) Indrajit Ghosh et al.   ACCOUNTS OF CHEMICAL RESEARCH

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Iridium(iii)-catalyzed regioselective direct arylation of sp2 C–H bonds with diaryliodonium salts

(2016) Pan Gao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cross-Coupling of Meyer–Schuster Intermediates under Dual Gold–Photoredox Catalysis

(2016) Jiwon Um et al.   ORGANIC LETTERS

Metal-Free One-Pot Synthesis of N,N′-Diarylamidines and N-Arylbenzimidazoles from Arenediazonium Salts, Nitriles, and Free Anilines

(2016) So Won Youn et al.   ORGANIC LETTERS

Collective Synthesis of Phenanthridinone through C–H Activation Involving a Pd-Catalyzed Aryne Multicomponent Reaction

(2016) Minghao Feng et al.   ORGANIC LETTERS

Visible light-mediated gold-catalysed carbon(sp2)–carbon(sp) cross-coupling

(2016) Suhong Kim et al.   Chemical Science

A Career in Catalysis: Maurice Brookhart

(2016) Olafs Daugulis et al.   ACS Catalysis

Ruthenium(II)-Catalyzed Regioselective C–H Arylation of Cyclic and N,N-Dialkyl Benzamides with Boronic Acids by Weak Coordination

(2016) Pradeep Nareddy et al.   ACS Catalysis

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling

(2016) Mark D. Levin et al.   ACS Central Science

Ruthenium(II)-Catalyzed CH Arylation of Anilides with Boronic Acids, Borinic Acids and Potassium Trifluoroborates

(2015) Jonathan Hubrich et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzedortho-Arylation of Anilides with Aryl Halides

(2015) Radhakrishnan Haridharan et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Stereoselective Synthesis of Imine-Containing Dibenzo[b,d]azepines by a Palladium(II)-Catalyzed [5+2] Oxidative Annulation ofo-Arylanilines with Alkynes

(2015) Zhijun Zuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox-Catalyzed C−H Difluoroalkylation of Hydrazones through an Aminyl Radical/Polar Mechanism

(2015) Pan Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical CH Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red-Shifted Dyes

(2015) Bram Verbelen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzedortho-Arylation of Benzoic Acids with Arenediazonium Salts

(2015) Liangbin Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp*Ir(III)-Catalyzed Mild and Broad C−H Arylation of Arenes and Alkenes with Aryldiazonium Salts Leading to the External Oxidant-Free Approach

(2015) Kwangmin Shin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis

(2015) Hosea M. Nelson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(III)-Catalyzed Direct Arylation of C–H Bonds with Diaryliodonium Salts

(2015) Pan Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Synthesis of N-H Carbazoles via Iridium(III)-Catalyzed Intramolecular C–H Amination

(2015) Chiharu Suzuki et al.   ORGANIC LETTERS

Characterizing chain processes in visible light photoredox catalysis

(2015) Megan A. Cismesia et al.   Chemical Science

Synthesis of Carbazoles by a Merged Visible Light Photoredox and Palladium-Catalyzed Process

(2015) Sungkyu Choi et al.   ACS Catalysis

Ruthenium(II)-Catalyzed C–H Arylation of Azoarenes by Carboxylate Assistance

(2015) Jonathan Hubrich et al.   ACS Catalysis

On the mechanism of photocatalytic reactions with eosin Y

(2014) Michal Majek et al.   Beilstein Journal of Organic Chemistry

Ruthenium-catalyzed ortho-arylation of acetanilides with aromatic boronic acids: an easy route to prepare phenanthridines and carbazoles

(2014) Ravi Kiran Chinnagolla et al.   CHEMICAL COMMUNICATIONS

A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides

(2014) Dengke Li et al.   CHEMICAL COMMUNICATIONS

Synthetic applications of eosin Y in photoredox catalysis

(2014) Durga Prasad Hari et al.   CHEMICAL COMMUNICATIONS

Direct Arylation of N-Heteroarenes with Aryldiazonium Salts by Photoredox Catalysis in Water

(2014) Dong Xue et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aniline Carbamates: A Versatile and Removable Motif for Palladium-Catalyzed Directed CH Activation

(2014) Nick Uhlig et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

(2014) Matthew N. Hopkinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion

(2014) Xing-zhong Shu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemo-, Regio- and Stereoselective Heck Arylation of Allylated Malonates: Mechanistic Insights by ESI-MS and Synthetic Application toward 5-Arylmethyl-γ-lactones

(2014) Caio C. Oliveira et al.   ORGANIC LETTERS

The Photocatalyzed Meerwein Arylation: Classic Reaction of Aryl Diazonium Salts in a New Light

(2013) Durga Prasad Hari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Pd(iii)/Pd(i) reductive elimination in palladium sequences

(2013) Giovanni Maestri et al.   CHEMICAL COMMUNICATIONS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Oxidative Palladium(II)-Catalyzed Dehydrogenative CH/CH Cross-Coupling of 2,3-Substituted Indolines with Arenes at the C7 Position

(2013) Lin-Yu Jiao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes

(2013) Basudev Sahoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent applications of arene diazonium salts in organic synthesis

(2013) Fanyang Mo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-catalyzed C–H activation of anilides at room temperature: ortho-arylation and acetoxylation

(2013) Fan Yang et al.   RSC Advances

Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed CH Arylation with Diaryliodonium Salts

(2012) Sharon R. Neufeldt et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III) and Hexabromobenzene-A Catalyst System for the Cross-Dehydrogenative Coupling of Simple Arenes and Heterocycles with Arenes Bearing Directing Groups

(2012) Joanna Wencel-Delord et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Shining Light on Photoredox Catalysis: Theory and Synthetic Applications

(2012) Joseph W. Tucker et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-Free Oxyarylation of Alkenes with Aryl Diazonium Salts and TEMPONa

(2012) Marcel Hartmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts

(2012) Durga Prasad Hari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Intermolecular Aniline Ortho-Arylation via Benzyne Intermediates

(2012) Thanh Truong et al.   ORGANIC LETTERS

Enantioselective Heck Arylations of Acyclic Alkenyl Alcohols Using a Redox-Relay Strategy

(2012) E. W. Werner et al.   SCIENCE

Photocatalytic Arylation of Alkenes, Alkynes and Enones with Diazonium Salts

(2012) Peter Schroll et al.   ChemistryOpen

Evolution and Synthetic Applications of the Heck-Matsuda Reaction: The Return of Arenediazonium Salts to Prominence

(2011) Jason G. Taylor et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Operationally Simple and Highly (E)-Styrenyl-Selective Heck Reactions of Electronically Nonbiased Olefins

(2011) Erik W. Werner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis

(2011) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible Light

(2010) Matthias Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remote amide-directed palladium-catalyzed benzylic C–H amination with N-fluorobenzenesulfonimide

(2010) Tao Xiong et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Cationic Palladium(II) Catalysis: C−H Activation/Suzuki−Miyaura Couplings at Room Temperature

(2010) Takashi Nishikata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Umpolung Direct Arylation Reactions: Facile Process Requiring Only Catalytic Palladium and Substoichiometric Amount of Silver Salts

(2010) James J. Mousseau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-CatalyzedOrtho-Arylation ofO-Phenylcarbamates with Simple Arenes and Sodium Persulfate

(2010) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-catalyzed ortho-arylation of phenylacetamides, benzamides, and anilides with simple arenes using sodium persulfate

(2010) Charles S. Yeung et al.   Chemical Science

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Room Temperature CH Activation and Cross-Coupling of Aryl Ureas in Water

(2009) Takashi Nishikata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Catalytic C–C coupling through C–H arylation of arenes or heteroarenes

(2009) Gian Paolo Chiusoli et al.   COORDINATION CHEMISTRY REVIEWS

Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate

(2009) Nicholas R. Deprez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates

(2009) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

(2009) David C. Powers et al.   Nature Chemistry

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE

Twofold C−H Functionalization: Palladium-CatalyzedOrthoArylation of Anilides

(2008) Gordon Brasche et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART

Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components

(2007) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION