期刊
GREEN CHEMISTRY
卷 19, 期 7, 页码 1642-1646出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc03465a
关键词
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资金
- Ministry of Science and Technology of the People's Republic of China [2016YFA0602900]
- National Natural Science Foundation of China [21572071, 21420102003]
- Fundamental Research Funds for the Central Universities [2015zz038]
A Cu-catalyzed oxidative coupling reaction of arylboronic acids, amines and carbon dioxide is described for the first time in this paper. The reaction tolerates a wide range of functional groups, providing a convenient protocol for the synthesis of various O-aryl carbamates. The successful development of the transformation was enabled by the use of BF3 center dot OEt2 as the promoter and molecular oxygen as the oxidant. Mechanistic studies suggested that the Cu-II carbamato complex is involved in the catalytic transformation.
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