期刊
EUROPEAN POLYMER JOURNAL
卷 93, 期 -, 页码 530-544出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2017.06.026
关键词
Green chemistry; Bio-based; Eugenol; Dual curing; Click reaction; Thermosets
资金
- MINECO [MAT2014-53706-C03-01, MAT2014-53706-C03-02]
- Generalitat de Catalunya [2014-SGR-67]
Novel bio-based and dual-curable thermosets were prepared from eugenol derivatives. The curing sequence combined two click reactions, a photoinduced radical thiol-ene reaction followed by a thermally activated thiol-epoxy reaction. Eugenol was transformed into a triallyl (3A-EU) and a diallyl glycidyl derivative (2AG-EU) with high yields, and they were used as starting monomers in order to study the thiol-ene reaction and the dual-curing process, respectively. Three different thiol crosslinkers were tested, one commercially available tetrathiol derived from pentaerythritol (PETMP) and two other that were also synthesized: a trithiol derived from eugenol (3SH-EU) and a hexathiol derived from squalene (6SH-SQ). FTIR and DSC were used to monitor both curing stages and analyze the obtained materials. The results evidenced the occurrence of side reactions that led to incomplete thiol-ene reaction. The dual-curable materials showed higher To than the materials obtained by a simple thiol-ene process and presented higher mechanical and thermomechanical performance.
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