期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 2, 页码 409-413出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201601362
关键词
Phenols; Palladium; Heterogeneous catalysis; Dehydrogenation; Hydrogen transfer; Hydrogen acceptors
资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- Special Coordination Funds for Promoting Science and Technology, Creation of Innovation Centers for Advanced Interdisciplinary Research Areas (Innovative Bioproduction Kobe), MEXT, Japan
- Grants-in-Aid for Scientific Research [15K13758] Funding Source: KAKEN
The conversion of cyclohexanone and substituted cyclohexanones into alkyl aryl ethers by using a Pd/C-ethylene system is discussed, with ethylene functioning as a hydrogen acceptor. The ether products are easily transformed into the corresponding phenols by treatment with BBr3. The direct conversion of cyclohexenone into phenol in the presence of a catalytic amount of Pd/C under an ethylene atmosphere is also described.
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