期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 36, 页码 5357-5369出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700878
关键词
Glycosylation; Carbohydrates; Disaccharides; Glycomimetics; Phosphorus; Glycosides
资金
- Averroes-ERASMUS MUNDUS program
The synthesis of pseudodisaccharides based on an oxaphosphinane heterocycle is described. Disaccharide mimetics 5 and 6 were readily obtained through glycosylation of a hydroxy group with appropriately protected furanosyl or pyranosyl carbohydrates using a trichloroacetamidate coupling strategy. Selective or complete deprotection then produced the chiral pseudodisaccharides in good yields.
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